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Three New Co-ordination Polymers of Zinc(II) and Cadmium(II) with Dicarboxylate and Bipyridine Ligands: Synthesis, Structure and Luminescence Study

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Abstract

Three coordination polymers of zinc(II) and cadmium(II) of formula {[Zn(bipy)(NIPH)]0.1·5H2O}n (1), {[Cd2(bipy)2(NIPH)2]·2H2O} n (2) and {[Cd2(bipy)4(BDAC)(NO3)](NO3)·6H2O}n (3) (NIPH = 5-nitro-isophthalic acid, H2BDAC = 1,4-benzenediacrylic acid and bipy = 2,2′-bipyridine) have been synthesized and structurally characterized by X-ray single crystal diffraction analysis. All the complexes display 1D coordination polymers where M(bipy) units are connected by dicarboxylate anions(and also by nitrate in 3)acting as bridging ligands. While in 1 and 3 a zig–zag chain is generated, in case of 2 a double linear chain is formed by the two crystallographic distinct Cd atoms. In solid state all the complexes expand the dimensionality to 3D by means of π–π interactions among π rings and H-bonds generated by lattice water molecules. The fluorescence study indicates intraligand π–π* charge transfer is the reason for emission in all the complexes.

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References

  1. X.H. Bu, M.L. Tong, H.C. Chang, S. Kitagawa, S.R. Batten, Angew. Chem. Int. Ed. 43, 192 (2004)

    Article  CAS  Google Scholar 

  2. M. Sorai, M. Nakano, Y. Miyazaki, Chem. Rev. 106, 976 (2006)

    Article  CAS  Google Scholar 

  3. Y.F. Zeng, X. Hu, F.C. Liu, X.H. Bu, Chem. Soc. Rev. 38, 469 (2009)

    Article  CAS  Google Scholar 

  4. L.Q. Ma, C. Abney, W.B. Lin, Chem. Soc. Rev. 38, 1248 (2009)

    Article  CAS  Google Scholar 

  5. Y.B. Men, J.L. Sun, Z.T. Huang, Q.Y. Zheng, Angew. Chem. Int. Ed. 48, 2873 (2009)

    Article  CAS  Google Scholar 

  6. H.W. Roesky, M. Andruh, Coord. Chem. Rev. 236, 91 (2003)

    Article  CAS  Google Scholar 

  7. S. Dalai, P.S. Mukherjee, G. Rogez, T. Mallah, M.G.B. Drew, N.R. Chaudhuri, Eur. J. Inorg. Chem. 2002, 3292 (2002)

    Article  Google Scholar 

  8. B.H. Ye, M.L. Tong, X.M. Chen, Coord. Chem. Rev. 249, 545 (2005)

    Article  CAS  Google Scholar 

  9. S.A. Bourne, A. Mondal, M.J. Zaworotko, Cryst. Eng. Commun. 4, 25 (2001)

    Article  CAS  Google Scholar 

  10. B. Moulton, J. Lu, R. Hajndl, S. Hariharan, M.J. Zaworotko, Angew. Chem. Int. Ed. 41, 2821 (2002)

    Article  CAS  Google Scholar 

  11. S.Y. Yang, L.S. Long, R.B. Huang, L.S. Zheng, Chem. Commun. 5, 472 (2002)

    Article  Google Scholar 

  12. J.W. Ye, J.Y. Zhang, G.L. Ning, G. Tian, Y. Chen, Y. Wang, Cryst. Growth Des. 8, 3098 (2008)

    Article  CAS  Google Scholar 

  13. H. Ren, T.Y. Song, J.N. Xu, S.B. Jing, Y. Yu, P. Zhang, L.R. Zhang, Cryst. Growth Des. 9, 105 (2009)

    Article  CAS  Google Scholar 

  14. M. Du, Z.H. Zhang, Y.P. You, X.J. Zhao, Cryst. Eng. Commun. 10, 306 (2008)

    Article  CAS  Google Scholar 

  15. J. Ye, J. Zhang, L. Ye, D. Xie, T. Xu, G. Li, G. Ning, Dalton Trans. 39, 5342 (2008)

    Article  Google Scholar 

  16. E.G. Bakalbassis, M. Korabik, A. Michailides, J. Mrozinski, C. Raptopoulou, S. Skoulika, A. Terzis, D.J. Tsaousis, Dalton Trans. 6, 850 (2001)

    Article  Google Scholar 

  17. C. Livage, C. Egger, M. Nogues, G.J. Férey, Mater. Chem. 8, 2743 (1998)

    Article  CAS  Google Scholar 

  18. M.F.S. Lo, S.S.Y. Chui, L.Y. Shek, Z. Lin, X.X. Zang, G.H. Wen, I.D. Williams, J. Am. Chem. Soc. 122, 6293 (2000)

    Article  CAS  Google Scholar 

  19. M.J. Zaworotko, Cryst. Growth Des. 7, 4 (2007)

    Article  CAS  Google Scholar 

  20. Q.R. Fang, G.S.M. Xue, S.L. Qiu, Chem. Eur. J. 12, 3754 (2006)

    Article  CAS  Google Scholar 

  21. Q. Sun, Q. Yue, J.Y. Zhang, L. Wang, X. Li, E.Q. Gao, Cryst. Growth Des. 9, 2310 (2009)

    Article  CAS  Google Scholar 

  22. Y.B. Chen, Y. Kang, J. Zhang, Chem. Commun. 46, 3182 (2010)

    Article  CAS  Google Scholar 

  23. J. Chen, C.P. Li, M. Du, Cryst. Eng. Commun. 13, 1885 (2011)

    Article  CAS  Google Scholar 

  24. Q. Wang, M.J. Wu, E.C. Yang, X.G. Wang, X.J. Zhao, J. Coord. Chem. 61, 595 (2008)

    Article  CAS  Google Scholar 

  25. A.-I.I. Bruker-Nonius, SAINT-Plus (Bruker AXS Inc, Madison, Wisconsin, 2004)

    Google Scholar 

  26. Z. Otwinowski, W. Minor, Methods Enzymol. 276, 307 (1997)

    Article  CAS  Google Scholar 

  27. G.M. Sheldrick, Acta Crystallogr. 64, 112 (2008)

    Article  CAS  Google Scholar 

  28. L.J. Farrugia, J. Appl. Crystallogr. 32, 837 (1999)

    Article  CAS  Google Scholar 

  29. L.J. Farrugia, J. Appl. Crystallogr. 30, 565 (1997)

    Article  CAS  Google Scholar 

  30. Brandenburg, K. Diamond, Ver 3.1 Crystal Impact GbR, Bonn, Germany

  31. H. Ren, T. Song, J. Xu, X. He, L. Wang, P. Zhang, J.W. Ye, Trans. Met. Chem. 31, 992 (2006)

    Article  CAS  Google Scholar 

  32. H. Ren, L.-X. Yu, L.-R. Zhang, Y.-L. Chen, J.-H. Jiang, P. Zhang, T.-Y. Song, J. Coord. Chem. 61, 3960 (2008)

    Article  CAS  Google Scholar 

  33. M. Bera, S.K. Jana, A. Rana, D.S. Chowdhuri, D. Hazari, C.-M. Liu, E. Zangrando, S. Dalai, J. Inorg. Organomet. Polym. 23, 736 (2013)

    Article  CAS  Google Scholar 

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Acknowledgments

This work is financially supported by CSIR, New Delhi, India [No. 01(2536)/11/EMR-II]. S. K. Jana is thankful to UGC for providing research fellowship.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Technology, Vidyasagar University, Midnapore, 721 102, West Bengal, India

    Debdoot Hazari, Swapan Kumar Jana & Sudipta Dalai

  2. Department of Chemistry, Durham University, Darham, DH13LE, UK

    Horst Puschmann

  3. Department of Chemical and Pharmaceutical Sciences, University of Trieste, 34127, Trieste, Italy

    Ennio Zangrando

Authors
  1. Debdoot Hazari
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  2. Swapan Kumar Jana
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  3. Horst Puschmann
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  4. Ennio Zangrando
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  5. Sudipta Dalai
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Correspondence to Sudipta Dalai.

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Hazari, D., Jana, S.K., Puschmann, H. et al. Three New Co-ordination Polymers of Zinc(II) and Cadmium(II) with Dicarboxylate and Bipyridine Ligands: Synthesis, Structure and Luminescence Study. J Inorg Organomet Polym 25, 1151–1159 (2015). https://doi.org/10.1007/s10904-015-0223-4

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  • DOI: https://doi.org/10.1007/s10904-015-0223-4

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