Skip to main content
SpringerLink
Log in

Acid Functionalized Multiwall Carbon Nanotube/Magnetite (MWCNT)-COOH/Fe3O4 Hybrid: Synthesis, Characterization and Conductivity Evaluation

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

A functionalized multiwall carbon nanotube (MWCNT)–COOH/Fe3O4 hybrid was fabricated by co-precipitation method. Fe3O4 nanoparticles were stably attached to the surface of carboxyl groups (COOH). The presence of Fe3O4 nanoparticles and their surface conjugation to MWCNT have been confirmed by XRD, TEM and FT-IR techniques. Magnetic evaluation revealed a superparamagnetic character of the hybrid and therefore the attached Fe3O4 nanoparticles. The crystallite size (9 ± 3 nm), particle size (9 ± 2 nm) and magnetic domain size estimated for Fe3O4 are consistent with each other, which reveal the single crystalline character of the nanoparticles. Electrical conductivity and dielectric behavior have also been characterized by utilizing impedance spectroscopy up to 3 MHz for an isotherm line varying from 293 to 393 K by 10 K steps. Electrical characteristics and its complex dielectric approaches might be elucidated with the existence of a conventional tunneling conduction mechanism of temperature-independency. The AC conductivity of MWCNT–COOH/Fe3O4 hybrid could also be a consequence of the estimations of the universal dynamic response.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Scheme 1
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. L. Jiang, L. Gao, Chem. Mater. 15, 2848 (2003)

    Article  CAS  Google Scholar 

  2. X.W. Teng, H. Yang, J. Mater. Chem. 14, 774 (2004)

    Article  CAS  Google Scholar 

  3. Y. Chen, X. Wang, Q. Zhang, Y. Li, H. Wang, J. Alloy. Compd. 509, 4053 (2011)

    Article  CAS  Google Scholar 

  4. C. Gao, W. Li, H. Morimoto, Y. Nagaoka, T. Maekawa, J. Phys. Chem. B 110, 7213 (2006)

    Article  CAS  Google Scholar 

  5. H.Q. Cao, M.F. Zhu, Y.G. Li, J. Solid State Chem. 179, 1208 (2006)

    Article  CAS  Google Scholar 

  6. B.P. Jia, L. Gao, J. Sun, Carbon 45, 1476 (2007)

    Article  CAS  Google Scholar 

  7. J.Q. Wan, W. Cai, J.T. Feng, X.X. Meng, E.Z. Liu, J. Mater. Chem. 17, 1188 (2007)

    Article  CAS  Google Scholar 

  8. M.A. Correa-Duarte, M. Grzelczak, V. Salgueirino-Maceira, M. Giersig, L.M. LizMarzan, M. Farle, K. Sierazdki, R. Diaz, J. Phys. Chem. B 109, 19060 (2005)

    Article  CAS  Google Scholar 

  9. P.L. Lee, Y.K. Chiu, Y.C. Sun, Y.C. Ling, Carbon 48, 1397 (2010)

    Article  CAS  Google Scholar 

  10. Y. Liu, W. Jiang, Y. Wang, X.J. Zhang, D. Song, F.S. Li, J. Magn. Magn. Mater. 321, 408 (2009)

    Article  CAS  Google Scholar 

  11. Z. Liu, J. Wang, D.H. Xie, Small 4, 462 (2008)

    Article  CAS  Google Scholar 

  12. P.D. Stevens, J. Fan, H.M.R. Gardimalla, M. Yen, Y. Gao, Org. Lett. 7, 2085 (2005)

    Article  CAS  Google Scholar 

  13. M.A. White, J.A. Johnson, J.T. Koberstein, N.J. Turro, J. Am. Chem. Soc. 128, 11356 (2006)

    Article  CAS  Google Scholar 

  14. Y. Zhu, L.P. Stubbs, F. Ho, R. Liu, C.P. Ship, J.A. Maguire, N.S. Hosmane, Chem. Cat. Chem 2, 365 (2010)

    CAS  Google Scholar 

  15. C. Kumari, Nanomaterials for the Life Sciences, Vol. 9, Chapt. 16 (Wiley, Hoboken, 2010), pp. 403–418

    Google Scholar 

  16. S. Shahrokhian, S. Rastgar, M.K. Amini, M. Adeli, Bioelectrochemistry 86, 78 (2012)

    Article  CAS  Google Scholar 

  17. C. Cunha, S. Panseri, D. Iannazzo, A. Piperno, A. Pistone, M. Fazio, A. Russo, M. Marcacci, S. Galvagno, Nanotechnology 23, 465102 (2012)

    Article  CAS  Google Scholar 

  18. H. Teymourian, A. Salimi, R. Hallaj. Biosens. Bioelectron. 33, 60 (2012)

    Article  CAS  Google Scholar 

  19. H. Wu, G. Liu, Y. Zhuang, D. Wu, H. Zhang, H. Yang, H. Hu, S. Yang, Biomaterials 32, 4867 (2011)

    Article  CAS  Google Scholar 

  20. J.F. Fan, X. Li, New Carbon Mater. 27, 111 (2012)

    Article  CAS  Google Scholar 

  21. L. Kong, X. Lu, W. Zhang, J. Solid State Chem. 181, 628 (2008)

    Article  CAS  Google Scholar 

  22. B. Unal, A. Baykal, M. Senel, H. Sözeri, Synthesis and characterization of multiwall-carbon nanotubes decorated with nickel ferrite hybrid, J Inorg Organomet Polym. doi 10.1007/s10904-012-9803-8

  23. T. Wejrzanowski, R. Pielaszek, A. Opalińska, H. Matysiak, W. Łojkowski, K.J. Kurzydłowski, Appl. Surf. Sci. 253, 204 (2006)

    Article  CAS  Google Scholar 

  24. Y. Liu, L. Gao, Carbon 43, 47 (2005)

    Article  Google Scholar 

  25. J. Jang, J. Bae, S. Yoon, J. Mater. Chem. 13, 676 (2003)

    Article  CAS  Google Scholar 

  26. J. Zhang, H. Zou, Q. Qing, Y. Yang, Q. Li, Z. Liu, X. Guo, Z. Du, J. Phys. Chem. B 107, 3712 (2003)

    Article  CAS  Google Scholar 

  27. B. Unal, Z. Durmus, H. Kavas, A. Baykal, M.S. Toprak, Mater. Chem. Phys. 123, 184 (2010)

    Article  CAS  Google Scholar 

  28. B. Unal, Z. Durmus, A. Baykal, H. Sözeri, M.S. Toprak, L. Alpsoy, J. Alloy. Compd. 505, 172 (2010)

    Article  Google Scholar 

  29. Q. Zhang, M.F. Zhu, Q.H. Zhang, Y.G. Li, H.Z. Wang, Mater. Chem. Phys. 116, 658 (2009)

    Article  CAS  Google Scholar 

  30. D. Eder, Chem. Rev. 110, 1348 (2010)

    Article  CAS  Google Scholar 

  31. Y. Zhang, M. Zhu, Q. Zhang, H. Y, Y. Li, H. Wang, J. Magn. Magn. Mater. 322, 2006 (2010)

    Article  CAS  Google Scholar 

  32. J. Mürbe, A. Rechtenbach, T. Töpfer, Mater. Chem. Phys. 110, 426 (2008)

    Article  Google Scholar 

  33. R.H. Kodama, A.E. Berkowitz, E.J. McNiff Jr, S. Foner, Phys. Rev. Lett. 77, 394 (1996)

    Article  CAS  Google Scholar 

  34. X. Batlle, A. Labarta, J. Phys. D Appl. Phys. 35, R15 (2002)

    Article  CAS  Google Scholar 

  35. Z. Durmus, H. Erdemi, A. Aslan, M.S. Toprak, H. Sozeri, Polyhedron 30, 419 (2011)

    Article  CAS  Google Scholar 

  36. Z. Durmus, H. Sozeri, B. Unal, A. Baykal, R. Topkaya, S. Kazan, M.S. Toprak, Polyhedron 30, 322 (2011)

    Article  CAS  Google Scholar 

  37. A.E. Berkowitz, J.A. Lahut, I.S. Jacobs, L.M. Levinson, D.W. Forester, Phys. Rev. Lett. 34, 594 (1975)

    Article  CAS  Google Scholar 

  38. C. Kittel, Introduction to Solid State Physics (Wiley, New York, 1971)

    Google Scholar 

  39. D.-X. Chen, O. Pascu, A. Roig, A. Sanchez, J. Magn. Magn. Mater. 322, 3834 (2010)

    Article  CAS  Google Scholar 

  40. S. Barrau, P. Demont, A. Peigney, C. Laurent, C. Lacabanne, Macromolecules 36, 5187 (2003)

    Article  CAS  Google Scholar 

  41. E. Laredo, M. Grimau, A. Bello, D.F. Wu, Y.S. Zhang, D.P. Lin, Biomacromolecules 11, 1339 (2010)

    Article  CAS  Google Scholar 

  42. A.K. Jonscher, Nature (London) 267, 673 (1977)

    Article  CAS  Google Scholar 

  43. J.C. Dyre, T.B. Schroder, Rev. Mod. Phys. 72, 873 (2000)

    Article  Google Scholar 

  44. Q. Li, Q.Z. Xue, X.L. Gao, Q.B. Zheng, eXPRESS. Polymer Letters 3, 769 (2009)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Art and Science, Fatih University, B.Cekmece, Istanbul, 34500, Turkey

    A. Baykal, M. Senel & E. Karaoğlu

  2. Department of Electrical and Electronic Engineering, Faculty of Engineering, Fatih University, B.Cekmece, Istanbul, 34500, Turkey

    B. Unal

  3. TUBITAK-UME, National Metrology Institute, 41470, Gebze, Kocaeli, Turkey

    H. Sözeri

  4. Department of Materials and Nanophysics, KTH-Royal Institute of Technology, Kista, 16440, Stockholm, Sweden

    M. S. Toprak

  5. Department of Materials Science and Engineering, Yildirim Beyazit University, Ulus, Ankara, Turkey

    M. S. Toprak

Authors
  1. A. Baykal
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Senel
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. Unal
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. Karaoğlu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. H. Sözeri
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. M. S. Toprak
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to A. Baykal or M. Senel.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Baykal, A., Senel, M., Unal, B. et al. Acid Functionalized Multiwall Carbon Nanotube/Magnetite (MWCNT)-COOH/Fe3O4 Hybrid: Synthesis, Characterization and Conductivity Evaluation. J Inorg Organomet Polym 23, 726–735 (2013). https://doi.org/10.1007/s10904-013-9839-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-013-9839-4

Keywords

Search

Navigation