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Synthesis and Characterization of the New Nano Flowers Lead(II) Coordination Polymer with Hemidirected Coordination Sphere

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Abstract

Nano flowers of a new polymeric lead(II) complex containing the azide anions, [Pb(baea)(N3)·(N3)] n (“baea” is the abbreviation of bis(2-aminoethyl)amine), has been synthesized by a sonochemical method. The new nano-structure was characterized by transmission electron microscopy, scanning electron microscopy, X-ray powder diffraction, elemental analyses, and IR spectroscopy. Single crystalline material was obtained using a heat gradient applied to a solution of the reagents. Single-crystal X-ray diffraction analyses show that the coordination number for PbII ions is five, PbN5 and hold hemidirected coordination geometry. To the best of our knowledge, the 1D coordination polymer interact with each other via supramolecular and weak Pb···N interactions to create 2D supramolecular frameworks.

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Acknowledgments

The authors acknowledge financial support by University of Tabriz and University of Lisbon is gratefully acknowledged. HKF would like to thank the Malaysian Government and Universiti Sains Malaysia for the Research University Golden Goose Grant 1001/PFIZIK/811012.

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Author notes

  1. Mohammad Safi Shalamzari & Shabnam Behrouzi

    Present address: Department of Pharmaceutical Science, University of Antwerp, 2020, Antwerp, Belgium

Authors and Affiliations

  1. Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Babak Mirtamizdoust

  2. Department of Quimica & Bioquimica, University of Lisbon, 1749016, Lisbon, Portugal

    Mohammad Safi Shalamzari, Shabnam Behrouzi & Maria Helena Florencio

  3. X-ray Crystallography Unit, School of Physics, University of Sains Malaysia, 11800 USM, Penang, Malaysia

    Hoong-Kun Fun

Authors
  1. Babak Mirtamizdoust
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  2. Mohammad Safi Shalamzari
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  3. Shabnam Behrouzi
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  4. Maria Helena Florencio
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  5. Hoong-Kun Fun
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Correspondence to Babak Mirtamizdoust.

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Mirtamizdoust, B., Shalamzari, M.S., Behrouzi, S. et al. Synthesis and Characterization of the New Nano Flowers Lead(II) Coordination Polymer with Hemidirected Coordination Sphere. J Inorg Organomet Polym 22, 1358–1364 (2012). https://doi.org/10.1007/s10904-012-9719-3

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