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[Re6(μ3-Se)8]2+ Core-Containing Cluster Complexes with Isonicotinic Acid: Synthesis, Structural Characterization, and Hydrogen-Bonded Assemblies

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Abstract

Three new complexes of the [Re6(μ3-Se)8]2+ core-containing cluster with isonicotinic acid (INA) were synthesized and characterized by multinuclear NMR (1H and 31P) and high-resolution mass spectrometry. Their molecular and crystal structures were determined by single-crystal X-ray diffraction studies. Unusual degrees of deprotonation of the INA ligand(s) are observed in the crystal structure, possibly due to the activation by the Lewis acidic cluster core. Extensive hydrogen bonding interactions occurring between carboxylate groups of neighboring cluster units as revealed by crystallographic studies lead to the assembly of both linear and zigzag multi-cluster chains in the solid state.

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Acknowledgments

This research was supported in part by US NSF grants CHE-0750530 and CHE-1152609. We thank the University of Arizona Mass Spec facility for its help with the analysis of spectra.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, The University of Arizona, Tucson, AZ, 85721, USA

    William C. Corbin & Zhiping Zheng

  2. School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ, Scotland, UK

    Gary S. Nichol

Authors
  1. William C. Corbin
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  2. Gary S. Nichol
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  3. Zhiping Zheng
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Correspondence to Zhiping Zheng.

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Corbin, W.C., Nichol, G.S. & Zheng, Z. [Re6(μ3-Se)8]2+ Core-Containing Cluster Complexes with Isonicotinic Acid: Synthesis, Structural Characterization, and Hydrogen-Bonded Assemblies. J Clust Sci 26, 279–290 (2015). https://doi.org/10.1007/s10876-014-0769-2

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