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Synthesis of Mn3O4 Nanorods by Solid-State Thermal Decomposition of Manganese(III) Schiff Base Complex [Mn(Brsal-mepn)(μ1,3-N3)]n

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Abstract

Hausmannite Mn3O4 nanorods were successfully prepared via solid-state thermal decomposition route with manganese(III) Schiff base complex [Mn(Brsal-mepn)(μ1,3-N3)]n as manganese source in air at 400 °C for 4 h. Powder X-ray diffraction, Fourier transform infrared spectrometry and scanning electron microscopy were used to characterize Mn3O4 nanoparticles. These results confirm that the resulting manganese oxide was pure single-phase Mn3O4 nanoparticles. Using the present method, Mn3O4 nanorods can be product without expensive organic solvent and complicated equipment.

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Acknowledgments

A. D. Khalaji and F. Malekan are grateful to the Golestan University for partial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran

    Aliakbar Dehno Khalaji & Fatemeh Malekan

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  1. Aliakbar Dehno Khalaji
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  2. Fatemeh Malekan
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Correspondence to Aliakbar Dehno Khalaji.

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Khalaji, A.D., Malekan, F. Synthesis of Mn3O4 Nanorods by Solid-State Thermal Decomposition of Manganese(III) Schiff Base Complex [Mn(Brsal-mepn)(μ1,3-N3)]n . J Clust Sci 25, 517–521 (2014). https://doi.org/10.1007/s10876-013-0631-y

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