Skip to main content
Log in

Evaluation of surface ozone measurements during 2000–2005 at a rural area in the upper Spanish plateau

  • Published:
Journal of Atmospheric Chemistry Aims and scope Submit manuscript

Abstract

This paper presents the main experimental results of surface ozone concentrations measured at a rural area in Northern Spain from February 2000 to December 2005. Daily and seasonal variation of ozone has been analysed. The peak concentration levels are obtained in the afternoon, mean value around 88 µg m−3, with extreme average values of 59 µg m−3 in January and 113 µg m−3 in July. Small differences are found in the mean and median of the ozone levels from April to August, when spring and summer maxima are observed. Despite the great inter-annual ozone variability obtained, most air quality indicators showed a positive trend. Further analysis of the monthly mean ozone concentrations of the main percentiles have also been performed using a harmonic model. The upward trend was 6.2 ± 1.7 µg m−3 for the 98th percentile. To interpret the main features of the annual cycle and describe the ozone peaks, the influence of meteorological factors is studied. In summer, ozone production is governed by local processes, air temperature being the major controlling factor. However, the origin of the spring maximum is not so well identified.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  • Arteta, J., Cautenet, S.: Study of ozone distribution over the south-eastern France (ESCOMPTE campaign): discrimination between ozone tendencies due to chemistry and to transport. J. Atmos. Chem 58, 111–130 (2007). doi:10.1007/s10874-007-9081-y

    Article  Google Scholar 

  • Atkinson-Palombo, C.M., Miller, J.A., Balling Jr., R.C.: Quantifying the ozone “weekend effect” at various locations in Phoenix, Arizona. Atmos. Environ 40, 7644–7658 (2006). doi:10.1016/j.atmosenv.2006.05.023

    Article  Google Scholar 

  • Bonasoni, P., Stohl, A., Cristofanelli, P., Calzolari, F., Colombo, T., Evangelisti, F.: Background ozone variations at Mt. Cimone Station. Atmos. Environ 34, 5183–5189 (2000). doi:10.1016/S1352-2310(00)00268-5

    Article  Google Scholar 

  • Brankov, E., Henry, R., Civerolo, K., Hao, W., Rao, S.T., Misra, P., et al.: Assessing the effects of transboundary ozone pollution between Ontario, Canada and New York, USA. Environ. Pollut 123, 403–411 (2003). doi:10.1016/S0269-7491(03)00017-4

    Article  Google Scholar 

  • Brönnimann, S., Buchmann, B., Wanner, H.: Trends in near-surface ozone in Switzerland: the 1990s. Atmos. Environ 36, 2841–2852 (2002). doi:10.1016/S1352-2310(02)00145-0

    Article  Google Scholar 

  • Camalier, L., Cox, W., Dolwick, P.: The effects of meteorology on ozone in urban areas and their use in assessing ozone trends. Atmos. Environ 41, 7127–7137 (2007). doi:10.1016/j.atmosenv.2007.04.061

    Article  Google Scholar 

  • Coyle, M., Fowler, D., Ashmore, M.: New directions: implications of increasing tropospheric background ozone concentrations for vegetation. Atmos. Environ 37, 153–154 (2003). doi:10.1016/S1352-2310(02)00861-0

    Article  Google Scholar 

  • Davies, T.D., Kelly, P.M., Low, P.S., Pierce, C.E.: Surface ozone concentrations in Europe: links with regional-scale atmospheric circulation. J. Geophys. Res 97, 9819–9832 (1992). doi:10.1029/91JB02571

    Article  Google Scholar 

  • Dawson, J.P., Adams, P.J., Pandis, S.N.: Sensitivity of ozone to summertime climate in the eastern USA: A modelling case study. Atmos. Environ 41, 1494–1511 (2007). doi:10.1016/j.atmosenv.2006.10.033

    Article  Google Scholar 

  • De Leeuw, F.: Trends in ground level ozone concentrations in the European Union. Environ. Sci. Policy 3, 189–199 (2000). doi:10.1016/S1462-9011(00)00090-3

    Article  Google Scholar 

  • Derwent, R.G., Simmonds, P.G., Manning, A.J., Spain, T.G.: Trends over a 20-year period from 1987 to 2007 in surface ozone at the atmospheric research station, Mace Head, Ireland. Atmos. Environ 41, 9091–9098 (2007). doi:10.1016/j.atmosenv.2007.08.008

    Article  Google Scholar 

  • Dueñas, C., Fernández, M.C., Cañete, S., Carretero, J., Liger, E.: Assessment of ozone variations and meteorological effects in an urban area in the Mediterranean coast. Sci. Total Environ 299, 97–113 (2002). doi:10.1016/S0048-9697(02)00251-6

    Article  Google Scholar 

  • EC. Directive 2002/3/EC of the European Parliament and of the Council, OJEC, 9.3., L 67/14 (2002)

  • EEA: Air Pollution by ozone across Europe during summer 2007. EEA (European Environment Agency) Technical report Num. 5/2008 (2008)

  • Fiala, J., Cernikovsky, L., de Leeuw, F., Livorova, H.: Air pollution by ozone in Europe 2002. Overview of exceedances of EC ozone threshold values during the summer season April–August 2002. European Environmental Agency, Topic report 6 (2002)

  • García, M.A., Sánchez, M.L., Pérez, I.A., de Torre, B.: Ground level ozone concentrations at a rural location in northern Spain. Sci. Total Environ 138, 135–150 (2005). doi:10.1016/j.scitotenv.2004.12.049

    Google Scholar 

  • Guerra, J.C., Rodríguez, S., Arencibia, M.T., García, M.D.: Study of the formation and transport of ozone in relation to the air quality management and vegetation protection in Tenerife (Canary Islands). Chemosphere 56, 1157–1167 (2004). doi:10.1016/j.chemosphere.2004.03.017

    Article  Google Scholar 

  • Jaffe, D., Ray, J.: Increase in surface ozone at rural sites in the western US. Atmos. Environ 41, 5452–5463 (2007). doi:10.1016/j.atmosenv.2007.02.034

    Article  Google Scholar 

  • Kalabokas, P.D., Repapis, C.C.: A climatological study of rural surface ozone in Central Greece. Atmos. Chem. Phys 4, 1139–1147 (2004)

    Article  Google Scholar 

  • Kalabokas, P.D., Viras, L., Bartzis, J., Repapis, C.C.: Mediterranean rural ozone characteristics around the urban area of Athens. Atmos. Environ 34, 5199–5208 (2000). doi:10.1016/S1352-2310(00)00298-3

    Article  Google Scholar 

  • Kalabokas, P.D., Volz-Thomas, A., Brioude, J., Thouret, V., Cammas, J.-P., Repapis, C.C.: Vertical ozone measurements in the troposphere over Eastern Mediterranean and comparison with Central Europe. Atmos. Chem. Phys 7, 3783–3790 (2007)

    Google Scholar 

  • Lindskog, A., Derwent, D., Friedli, K., Schuepbach, E., Solberg, S., Stevenson, D.: Seasonal cycles across Europe. Proceedings of EUROTRAC-2 Symposium 2002. Midgley P.M., Reuther M. (Eds), Weikersheim, Margraf, (2002)

  • Millán, M., Salvador, R., Mantilla, E.: Methodology and photochemical air pollution in Southern Europe: experimental results from EC research projects. Atmos. Environ 30, 1909–1924 (1996). doi:10.1016/1352-2310(95)00220-0

    Article  Google Scholar 

  • MMA: Medio Ambiente en España 2006. Ministerio de Medio Ambiente. Secretaría General Técnica (2007)

  • Monks, P.S.: A review of the observations and origins of the spring ozone maximum. Atmos. Environ 34, 3545–3561 (2000). doi:10.1016/S1352-2310(00)00129-1

    Article  Google Scholar 

  • Nolle, M., Ellul, R., Heinrich, G., Güsten, H.: A long-term study of concentrations in the central Mediterranean—diurnal and seasonal variations on the island of Gozo. Atmos. Environ 36, 1391–1402 (2002). doi:10.1016/S1352-2310(01)00505-2

    Article  Google Scholar 

  • Peuch, V.H., Dufour, A., Martin, D.: La pollution, le temps et le “temps Chimique”. Pollut. Atmos 179, 361–367 (2003)

    Google Scholar 

  • Reddy, R.R., Gopal, K.R., Reddy, L.S., Narasimhulu, K., Kumar, K.R., Ahammed, Y.N., et al.: Measurements of surface ozone at semi-arid site Anantapur (14.62°N, 77.65°E, 331 m asl) in India. J. Atmos. Chem 59, 47–59 (2008). doi:10.1007/s10874-008-9094-1

    Article  Google Scholar 

  • Ribas, A., Peñuelas, J.: Temporal patterns of surface ozone levels in different habitats of the North Western Mediterranean basin. Atmos. Environ 38, 985–992 (2004). doi:10.1016/j.atmosenv.2003.10.045

    Article  Google Scholar 

  • Sánchez, M.L., Pascual, D., Ramos, C., Pérez, I.: Forecasting particulate pollutant concentrations in a city from meteorological variables and regional weather patterns. Atmos. Environ 24, 1509–1519 (1990)

    Google Scholar 

  • Sánchez, M.L., de Torre, B., García, M.A., Pérez, I.: Ozone concentrations at a high station in the Central Massif (Spain). Chemosphere 60, 576–584 (2005). doi:10.1016/j.chemosphere.2004.12.079

    Article  Google Scholar 

  • Sánchez, M.L., de Torre, B., García, M.A., Pérez, I.: Ground-level ozone and ozone vertical profile measurements close to the foothills of the Guadarrama mountain range (Spain). Atmos. Environ 41, 1302–1314 (2007). doi:10.1016/j.atmosenv.2006.09.047

    Article  Google Scholar 

  • Scheel, H.E., Areskoug, H., Geiss, H., Gomiscek, B., Granby, K., Haszpra, L., et al.: On the spatial distribution and seasonal variation of lower-troposphere ozone over Europe. J. Atmos. Chem 28, 11–28 (1997). doi:10.1023/A:1005882922435

    Article  Google Scholar 

  • Trauth, M.H.: MATLAB Recipes for Earth Sciences; Springer (2007)

  • Vecchi, R., Valli, G.: Ozone assessment in the southern part of the Alps. Atmos. Environ 33, 97–109 (1999). doi:10.1016/S1352-2310(98)00133-2

    Article  Google Scholar 

  • Vingarzan, R.: A review of surface ozone background levels and trends. Atmos. Environ 38, 3431–3442 (2004). doi:10.1016/j.atmosenv.2004.03.030

    Article  Google Scholar 

  • Vinnikov, K.Y., Robock, A., Grody, N.C., Basist, A.: Analysis of diurnal and seasonal cycles and trends in climatic records with arbitrary observation times. Geophys. Res. Lett 31, L06205 (2004). doi:10.1029/2003GL019196

    Article  Google Scholar 

  • Volz-Thomas, A., Beekmann, M., Derwent, D., Law, K., Lindskog, A., Prévôt, A., et al: Tropospheric ozone and its control. Midgley et al. (eds). EUROTRAC-2 Final Report, Part 1, Margraf, Weikersheim (2003)

  • Vukovich, F.M.: Regional-scale boundary layer ozone variations in the eastern United States and their association with meteorological variations. Atmos. Environ 29, 2259–2273 (1995). doi:10.1016/1352-2310(95)00146-P

    Article  Google Scholar 

Download references

Acknowledgements

This paper has been possible thanks to the financial support provided by the Interministerial Commission of Science and Technology and the Regional Government of Castile and Leon, to whom the authors wish to express their gratitude.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. L. Sánchez.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sánchez, M.L., García, M.A., Pérez, I.A. et al. Evaluation of surface ozone measurements during 2000–2005 at a rural area in the upper Spanish plateau. J Atmos Chem 60, 137–152 (2008). https://doi.org/10.1007/s10874-008-9113-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10874-008-9113-2

Keywords

Navigation