Skip to main content
SpringerLink
Log in

Coordination complexes of 2,6-diarylpyrazines with copper(II) acetate

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The coordination chemistry of a series of 2,6- and 2,3-diarylpyrazines with copper(II) acetate is reported. The 2:2 coordination complexes formed between two 2,6-diarylpyrazines and copper(II) acetate are characterized by X-ray crystallography. The structure (2,6-bis(3′,5′-dimethylphenyl)pyrazine)copper(II) acetate acetonitrile solvate, (C48H52Cu2N4O8) ⋅ (C2H3N) is triclinic, P 1, with a = 7.9685(10), b = 13.1893(16), c = 13.8267(17) Å, α = 107.585(3)°, β = 103.921(3)° and γ = 96.759(3)°. The structure of (2-(2′,6′-dimethylphenyl)-6-(3″,5″-dimethylphenyl)pyrazine)copper(II) acetate, C48H52Cu2N4O8, is monoclinic, P21/c, with a = 8.2196(7), b = 12.5174(11), c = 21.7325(19) Å and β = 96.201(2)°.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Watson, W. H.; Wu, G.; Richmond, M. G. J. Chem. Crystallogr. 2004, 34, 759.

    Google Scholar 

  • Fenske, D.; Becher, H. J. Chem. Ber. 1974, 107, 117; 1975, 108, 2115.

    Google Scholar 

  • Fenske, D. Chem. Ber. 1979, 112, 363.

    Google Scholar 

  • Mao, F.; Philbin, C. E.; Weakley, T. J. R.; Tyler, D. R. Organometallics 1990, 9, 1510.

    Google Scholar 

  • Saint Version 6.02, Bruker Analytical X-ray Systems, Copyright 1997–1999.

  • SHELXTL Version 5.1, Bruker Analytical X-ray Systems, Copyright 1998.

  • PLATON. In A Multipurpose Crystallographic Tool; Speck, A. L. ed.; Utrecht University: Utrecht, The Netherlands, 2001.

  • Hoffmann, R.; Lipscomb, W. N. J. Chem. Phys. 1962, 36, 2179.

    Google Scholar 

  • Hoffmann, R. J. Chem. Phys. 1963, 39, 1397.

    Google Scholar 

  • Mealli, C.; Proserpio, D. M. J. Chem. Educ. 1990, 67 399.

    Google Scholar 

  • Weast, R. C. (Ed.) Handbook of Chemistry and Physics; CRC: Cleveland, OH, 1975; 56th ed.

  • Bard, A. J.; Faulkner, L. R. Electrochemical Methods; Wiley: New York, 1980.

    Google Scholar 

  • March, J. Advanced Organic Chemistry; Wiley-Interscience: New York, 1985; 3rd ed.

    Google Scholar 

  • Dolphin, D.; Wick, A. Tabulation of Infrared Spectral Data; Wiley-Interscience: New York, 1977.

    Google Scholar 

  • Brown, D. W.; Nakashima, T. T.; Rabenstein, D. L. J. Mag. Res. 1981, 45, 302.

    Google Scholar 

  • Levy, G. C.; Nelson, G. L. Carbon-13 Nuclear Magnetic Resonance for Organic Chemists; Wiley-Interscience: New York, 1972.

    Google Scholar 

  • Shen, H.; Bott, S. G.; Richmond, M. G. J. Chem. Crystallogr. 1997, 27, 19.

    Google Scholar 

  • Bodige, S. G.; Mendez-Rojas, M.; Watson, W. H. J. Chem. Crystallogr. 1999, 29, 57.

    Google Scholar 

  • Watson, W. H.; Bodige, S. G.; Liu, J.; Richmond, M. G. Struct. Chem. 2003, 14, 367.

    Google Scholar 

  • Bondi, A. J. Phys. Chem. 1964, 68, 441.

    Google Scholar 

  • Adams, R. N. Electrochemistry at Solid Electrodes; Marcel Dekker: New York, 1969.

    Google Scholar 

  • Rieger, P. H. Electrochemistry; Chapman & Hall: New York, 1994.

    Google Scholar 

  • Watson, W. H.; Wu, G.; Richmond, M. G. J. Chem. Crystallogr. 2004, 34, 709.

    Google Scholar 

  • Nicholson, R. S.; Shain, I. Anal. Chem. 1964, 36, 706.

    Google Scholar 

  • Albright, T. A.; Burdett, J. K.; Whangbo, M. H. Orbital Interactions in Chemistry; Wiley: New York, 1985.

    Google Scholar 

  • Duffy, N. W.; Nelson, R. R.; Richmond, M. G.; Rieger, A. L.; Rieger, P. H.; Robinson, B. H.; Tyler, D. R.; Wang, J. C.; Yang, K. Inorg. Chem. 1998, 37, 4849.

    Google Scholar 

  • Yang, K.; Bott, S. G.; Richmond, M. G. Organometallics 1995, 14, 2387.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Southwest Missouri State University, 901 South National Avenue, Springfield, Missouri

    Nate Schultheiss & Eric Bosch

  2. Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas

    Douglas R. Powell

Authors
  1. Nate Schultheiss
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Douglas R. Powell
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Eric Bosch
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Eric Bosch.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Schultheiss, N., Powell, D.R. & Bosch, E. Coordination complexes of 2,6-diarylpyrazines with copper(II) acetate. J Chem Crystallogr 34, 785–791 (2004). https://doi.org/10.1007/s10870-004-7654-z

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-004-7654-z

Search

Navigation