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Green-synthesized Zn-BTC metal–organic frameworks as a highly efficient material to improving electrochemical pseudocapacitance performance of P-type conductive polymer

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Abstract

In the present study, we introduce a simple chemical method to synthesize Zn-based MOF (Zn-BTC). The structural morphology and microstructure analysis of the synthesized materials were performed by Fourier transform infrared spectroscopy and powder X-ray diffraction (XRD), followed by scanning electron microscopy. The obtained Zn-BTC was decorated with poly orthoaminophenol film (POAP/Zn-BTC) through electropolymerization. The electrochemical behavior of composite electrode was studied using an acidic solution in three-electrode cyclic voltammetry and charge/discharge system. The POAP/ Zn-BTC composite electrode showed a specific capacitance of 580 F/g in a current density of 1 A/g. Our results provide an improved conductive polymer composite film with high active surface area, easy synthesis method, and high cycling stability for supercapacitors in aqueous electrolytes.

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References

  1. S.S. Patil, T.S. Bhat, A.M. Teli, S.A. Beknalkar, S.B. Dhavale, M.M. Faras, M.M. Karanjkar, P.S. Patil, Hybrid solid state supercapacitors (HSSC’s) for High energy & power density: an overview, engineered. Science 12, 38–51 (2020)

    CAS  Google Scholar 

  2. C. Hou, B. Wang, V. Murugadoss, S. Vupputuri, Y. Chao, Z. Guo, C. Wang, Du. Wei, recent advances in Co3O4 as anode materials for high- performance lithium-ion batteries, Engineered. Science 11, 19–30 (2020)

    CAS  Google Scholar 

  3. J. Cai, Xu. Wei, Y. Liu, Z. Zhu, G. Liu, W. Ding, G. Wang, H. Wang, Y. Luo, Robust construction of flexible bacterial cellulose@Ni(OH) Paper: toward 2 high capacitance and sensitive H2O2 detection, engineered. Science 5, 21–29 (2019)

    Article  Google Scholar 

  4. S.G. Sayyed, M.A. Mahadik, A.V. Shaikh, J.S. Jang, H.M. Pathan, Nano-metal oxide based supercapacitor via electrochemical deposition. ES Energy Environ. 3, 25–44 (2019).

  5. X. Wang, X. Zeng, D. Cao, Biomass-derived nitrogen-doped porous carbons (NPC) and NPC/polyaniline composites as high performance supercapacitor materials. Engineered Sci. 1, 55–63 (2018).

  6. A. Burke, Ultracapacitors: why, how, and where is the technology. J. Power Sources 91, 37–50 (2000)

    Article  CAS  Google Scholar 

  7. C. Yu, C. Masarapu, J. Rong, B. Wei, H. Jiang, Stretchable supercapacitors based on buckled single-walled carbon-nanotube macrofilms. Adv. Mater. 21(2009), 4793–4797 (2009)

    Article  CAS  Google Scholar 

  8. Y.J. Kang, H. Chung, C.H. Han, W. Kim. All-solid-state flexible supercapacitors based on papers coated with carbon nanotubes and ionic-liquid-based gel electrolytes. Nanotechnology. 23, 065401 (2012).

  9. A. Eftekhari, L. Li, Y. Yang, Polyaniline supercapacitors. J. Power Sources 347, 86–107 (2017)

    Article  CAS  Google Scholar 

  10. D.M. Mohilner, R.N. Adams, W.J. Argersinger, Investigation of the kinetics and mechanism of the anodic oxidation of aniline in aqueous sulfuric acid solution at a platinum electrode. J. Am. Chem. Soc. 84, 3618–3622 (1962)

    Article  CAS  Google Scholar 

  11. I. Shakir, Z. Almutairi, S.S. Shar, A. Nafady. Synthesis of Co(OH)2/CNTs nanocomposite with superior rate capability and cyclic stability for energy storage applications. Mater Res Express 7, 125501 (2020).

  12. Y. Meng, K. Wang, Y. Zhang, Z. Wei, Hierarchical porous graphene/polyaniline composite film with superior rate performance for flexible supercapacitors. Adv. Mater. 25, 6985–6990 (2013)

    Article  CAS  Google Scholar 

  13. P. Kahriz, H. Mahdavi, A. Ehsani, A. Heidari, M. Bigdeloo. Influence of synthesized functionalized reduced graphene oxide aerogel with 4,4′-methylenedianiline as reducing agent on electrochemical and pseudocapacitance performance of poly orthoaminophenol electroactive film. Electrochim. Acta.354, 136736 (2020).

  14. M. Naseri, L. Fotouhi, A. Ehsani, H. Shiri, Novel electroactive nanocomposite of POAP for highly efficient energy storage and electrocatalyst: Electrosynthesis and electrochemical performance. J. Colloid Interface Sci. 484, 308–313 (2016)

    Article  CAS  Google Scholar 

  15. A. Ehsani, H. Parsimehr, H. Nourmohammadi, R. Safari, S. Doostikhah, Environment-friendly electrodes using biopolymer chitosan/poly ortho aminophenol with enhanced electrochemical behavior for use in energy storage devices. Polym. Compos. 40(12), 4629–4637 (2019)

    Article  CAS  Google Scholar 

  16. H. Zhang, J. Nai, L. Yu, X.W. Lou, Metal-organic-framework-based materials as platforms for renewable energy and environmental applications. Joule 1, 77–107 (2017)

    Article  CAS  Google Scholar 

  17. A. Deep, S.K. Bhardwaj, A.K. Paul, K.-H. Kim, P. Kumar, Surface assembly of nano-metal organic framework on amine functionalized indium tin oxide substrate for impedimetric sensing of parathion. Biosens. Bioelectron. 65, 226–231 (2015)

    Article  CAS  Google Scholar 

  18. S. Sundriyal, H. Kaur, S.K. Bhardwaj, S. Mishra, K.-H. Kim, A. Deep. Metal-organic frameworks and their composites as efficient electrodes for supercapacitor applications. Coordination Chem. Rev. 369, 15–38 (2018)

  19. B. Liu, H. Shioyama, T. Akita, Q. Xu, Metal-organic framework as a template for porous carbon synthesis. J. Am. Chem. Soc. 130, 5390–5391 (2008)

    Article  CAS  Google Scholar 

  20. Xinran Li, Xinchun Yang, Huaiguo Xue, Huan Pang, and Qiang Xu. Metal–organic frameworks as a platform for clean energy applications. Energy Chem. 2, 100027 (2020).

  21. WQK Kuai-Bing, Z. Qichun. Recent progress in metal-organic frameworks as active materials for supercapacitors. Energy Chem. 2, 100025 (2020).

  22. Y. Tan, W. Zhang, Y. Gao, J. Wu, B. Tang, Facile synthesis and supercapacitive properties of Zr-metal organic frameworks (UiO-66). RSC Adv. 5, 17601–17605 (2015)

    Article  CAS  Google Scholar 

  23. C. Nicolò, R.V. Ricardo, D. Willem, S. Linda, B. Koen, D.V.D. E.F. Jan. A hybrid supercapacitor based on porous carbon and the metal‐organic framework MIL‐100(Fe), ChemElectroChem. 1, 1182–1188 (2014).

  24. P. Srimuk, S. Luanwuthi, A. Krittayavathananon, M. Sawangphruk, Solid-type supercapacitor of reduced graphene oxide-metal organic framework composite coated on carbon fiber paper. Electrochim. Acta 157, 69–77 (2015)

    Article  CAS  Google Scholar 

  25. L. Wang, X. Feng, L. Ren, Q. Piao, J. Zhong, Y. Wang, H. Li, Y. Chen, B. Wang, Flexible solid-state supercapacitor based on a metal–organic framework interwoven by electrochemically-deposited PANI. J. Am. Chem. Soc. 137, 4920–4923 (2015)

    Article  CAS  Google Scholar 

  26. Z. Yi-Zhou, C. Tao, W. Yang, L. Wen-Yong, P. Huan, H. Wei, A simple approach to boost capacitance: flexible supercapacitors based on Manganese Oxides@MOFs via chemically induced in situ self-transformation. Adv. Mater. 28, 5242–5248 (2016)

    Article  Google Scholar 

  27. R.R. Salunkhe, Y. Kamachi, N.L. Torad, S.M. Hwang, Z. Sun, S.X. Dou, J.H. Kim, Y. Yamauchi, Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons. J Mater Chem A 2, 19848–19854 (2014)

    Article  CAS  Google Scholar 

  28. F.-S. Ke, Y.-S. Wu, H. Deng, Metal-organic frameworks for lithium ion batteries and supercapacitors. J. Solid State Chem. 223, 109–121 (2015)

    Article  CAS  Google Scholar 

  29. F. Meng, Z. Fang, Z. Li, W. Xu, M. Wang, Y. Liu, J. Zhang, W. Wang, D. Zhao, X. Guo, Porous Co3O4 materials prepared by solid-state thermolysis of a novel Co-MOF crystal and their superior energy storage performances for supercapacitors. J Mater Chem A 1, 7235 (2013)

    Article  CAS  Google Scholar 

  30. Y.-Z. Zhang, Y. Wang, Y.-L. Xie, T. Cheng, W.-Y. Lai, H. Pang, W. Huang, Porous hollow Co 3 O 4 with rhombic dodecahedral structures for high-performance supercapacitors. Nanoscale 6, 14354–14359 (2014)

    Article  CAS  Google Scholar 

  31. S. Ullah, I.A. Khan, M. Choucair, A. Badshah, I. Khan, M.A. Nadeem, A novel Cr2O3-carbon composite as a high performance pseudo-capacitor electrode material. Electrochim. Acta 171, 142–149 (2015)

    Article  CAS  Google Scholar 

  32. W. Meng, W. Chen, L. Zhao, Y. Huang, M. Zhu, Y. Huang, Y. Fu, F. Geng, J. Yu, X. Chen, Porous Fe3O4/carbon composite electrode material prepared from metal-organic framework template and effect of temperature on its capacitance. Nano Energy 8, 133–140 (2014)

    Article  CAS  Google Scholar 

  33. X. Wang, Xiaomin M, Huan Wang, Pengfei Huang, Xinzhen Du, Xiaoquan Lu, A zinc(II) benzenetricarboxylate metal organic framework with unusual adsorption properties, and its application to the preconcentration of pesticides. Microchim Acta 184, 3681–3687 (2017)

    Article  CAS  Google Scholar 

  34. S.H. Khan, B. Pathak, M.H. Fulekar. A study on the influence of metal (Fe, Bi, and Ag) doping on structural, optical, and antimicrobial activity of ZnO nanostructures. Adv Compos Hybrid Mater. 3, 551–569 (2020).

  35. Gu. Yongwan, Z.P.H. Zhang, J. Zhu, B. Yuan, D. Pan, Wu. Chunhua, B. Dong, Z. Guo, Synthesis of high performance diesel oxidation catalyst using novel mesoporous AlLaZrTiOx mixed oxides by a modified sol-gel method. Adv Compos Hybrid Mater 3, 583–593 (2020)

    Article  Google Scholar 

  36. C. Houa, W. Yanga, X. Xiea, X. Sun, J. Wang, N. Naike, D. Pan, X. Mai, Z. Guo, F. Dang, W. Du. Agaric-like anodes of porous carbon decorated with MoO2 nanoparticles for stable ultralong cycling lifespan and high-rate lithium/sodium storage. J Colloid Interf Sci 596, 396–407 (2021).

  37. C. Hou, G. Jun, W. Du, J. Wang, Y. Du, C. Liu, J. Zhang, H. Hou, F. Dang, L. Zhao, Z. Guo. One-pot synthesized molybdenum dioxide–molybdenum carbide hetero structures coupled with 3D holey carbon nano sheets for highly efficient and ultrastable cycling lithium-ion storage. J Mater Chem A 7, 13460−13472 (2019).

  38. Qu. Keqi, Z. Sun, C. Shi, W. Wang, L. Xiao, J. Tian, Z. Huang, Z. Guo, Dual-acting cellulose nanocomposites filled with carbon nanotubes and zeolitic imidazolate framework-67 (ZIF-67)–derived polyhedral porous Co3O4 for symmetric supercapacitors. Adv Compos Hybrid Mater 4, 392–400 (2021)

    Article  Google Scholar 

  39. Y. Tian, X. Yang, A. Nautiyal, Y. Zheng, Q. Guo, J. Luo, X. Zhang, One-step microwave synthesis of MoS2/MoO3@graphite nano composite as an excellent electrode material for supercapacitors. Adv Compos Hybrid Mater 2, 151–161 (2019)

    Article  CAS  Google Scholar 

  40. A. Ehsani, M. Mahjani, M. Jafarian, Electrochemical impedance spectroscopy study on intercalation and anomalous diffusion of AlCl-4 ions into graphite in basic molten salt. Turkish J. Chem. 35(5), 735–743 (2011)

    CAS  Google Scholar 

  41. M.G. Mahjani, A. Ehsani, M. Jafarian, Synth. Met. 160, 1252–1258 (2010)

    Article  CAS  Google Scholar 

  42. A. Ehsani, M. Bigdeloo, A. Lorparizangene, M. Hadi, R. Safari, H. Mohammad Shiri, A.A. Heidari. J Chin Chem Soc. 66, 396–401 (2019).

  43. A. Ehsani, B. Mirtamizdoust, M. Yousefi, R. Safari, M. Hadi, A.K. Heidari, Bull. Chem. Soc. Jpn. 91, 617–622 (2018)

    Article  CAS  Google Scholar 

  44. J. Shabani-Shayeh, A. Ehsani, A. Nikkar, P. Norouzi, M.R. Ganjali, M. Wojdyla, New. J. Chem 39, 9454 (2015)

    Article  Google Scholar 

  45. A. Ehsani, Z. Rezaei, A. Agah, H. Mohammad Shiri, A.A. Heidari, Electrochemical and theoretical investigation of functionalized reduced graphene aerogel modified electrode for lead ions sensing. Microchem J 165, 106074 (2021).

  46. Ali Ehsani, M. Esfahaniha, P. Khodaei kahriz, R. safari, H.R. Parsimehr. Functionalized graphene oxide aerogel as a high efficient material for electrochemical sensing of organic pollutant. Surf Interface, 22, 100817 (2021).

  47. A. Ehsani, M. Moftakhar, F. karimi. Lignin-derived carbon as a high efficient active material for enhancing pseudocapacitance performance of p-type conductive polymer. J Energ Storage 35, 102291 (2021).

  48. A. Ehsani, B. Mirtamizdoust, F. karimi, M. Bigdeloo, H. Parsimehr, Influence of nanostructured VO-acetylacetonate coordination system with 2-(pyridin-4-ylmethylene) hydrazine-1-carbothioamide in pseudocapacitance performance of p-type conductive polymer composite film. Plastics Rubber Compos Macromol Eng 50(4), 172–179 (2021).

  49. Ehsani A, Bigdeloo M, Assefi F, Kiamehr M, Alizadeh R. Ternary nanocomposite of conductive polymer/chitosan biopolymer/metal organic framework: synthesis, characterization and electrochemical performance as effective electrode materials in pseudocapacitors. Inorg. Chem. Commun. 115, 107885 (2020).

  50. H. Shiri, A. Ehsani, M. Khales, Electrochemical synthesis of Sm2O3 nanoparticles: application in conductive polymer composite films for supercapacitors. J. Colloid Interface Sci. 505, 940–946 (2017)

    Article  Google Scholar 

  51. H.M. Shiri, A. Ehsani, M.J. Khales. Electrochemical synthesis of Sm2O3 nanoparticles: application in conductive polymer composite films for supercapacitors. J Colloid Interf 505, 40–946 (2017) 9

  52. S. Sadeghi, H. Mohammad Shiri, A. Ehsani, M. Oftadeh Electrosynthesis of high-purity TbMn2O5 nanoparticles and its nanocomposite with conjugated polymer: surface, density of state and electrochemical investigation. Solid State Sci 105, 106227 (2020).

  53. H. Mohammad Shiri, A. Ehsani, R. Behjatmanesh-Ardakani. Electrochemical deposition and plane-wave periodic DFT study on Dy2O3 nanoparticles and pseudocapacitance performance of Dy2O3 /conductive polymer nanocomposite film. J Taiwan Inst Chem Eng 93, 632–643 (2018).

  54. H. Shiri, A. Ehsani, R. Behjatmanesh-Ardakani, S. Hajghani, Electrosynthesis of Y2O3 nanoparticles and its nanocomposite with POAP as high efficient electrode materials in energy storage device: surface, density of state and electrochemical investigation. Solid State Ionics 338, 87–95 (2019)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Qom, Qom, Iran

    Hossein Mostaanzadeh, Mohammad Shahmohammadi, Ali Ehsani, Mojtaba Moharramnejad & Ebrahim Honarmand

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  1. Hossein Mostaanzadeh
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  2. Mohammad Shahmohammadi
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  3. Ali Ehsani
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Mostaanzadeh, H., Shahmohammadi, M., Ehsani, A. et al. Green-synthesized Zn-BTC metal–organic frameworks as a highly efficient material to improving electrochemical pseudocapacitance performance of P-type conductive polymer. J Mater Sci: Mater Electron 32, 26539–26547 (2021). https://doi.org/10.1007/s10854-021-07030-x

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