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Dielectric properties of sandwich-structured BaTiO3/polyimide hybrid films

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Abstract

In this paper, sandwich structured polyimide hybrid films were prepared by layered coating, in which middle layer is different volume fraction BT/PI monolayer film and both the bottom and the top layers are pure PI. Compared with monolayer hybrid films, sandwich structured hybrid films exert much lower dielectric loss and conductivity, which owe to pure PI layers as insulation layers effective block off conductive paths of middle layer. Besides, the SEM images show hybrid film has obvious layering and without defects. This sandwich structure can redistribute electric field between three layers to optimize breakdown performance, which correspond to data processed by Weibull breakdown distribution. When the intermediary volume fraction is 3 vol%, the breakdown strength of sandwich structured hybrid films is 344.26 kV/mm, which is 1.26 times enhancement than pure PI film. In addition, based on the improvement of the breakdown strength, the energy storage density of hybrid films is improved significantly. When the electric field is 344.26 kV/mm, its energy storage density reached 1.94 J/cm3, which is 1.72 times enhancement of pure PI film.

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References

  1. B.J. Chu, X. Zhou, K.L. Ren, N. Bret, M.R. Lin, Q. Wang, F. Bauer, Q.M. Zhang, Science 313, 5785 (2006)

    Article  Google Scholar 

  2. Prateek, V.K. Thakur, R.K. Gupta, Chem. Rev. 116, 7 (2016)

    Article  Google Scholar 

  3. Q.G. Chi, T. Mao, J.F. Dong, Y. Cui, Y. Zhang, C.H. Zhang, S.C. Xu, X. Wang, Q.Q. Lei, Sci. Rep. (2017). doi:10.1038/s41598-017-03273-z

    Google Scholar 

  4. C.H. Zhang, Q.G. Chi, J.F. Dong, Y. Cui, X. Wang, L.Z. Liu, Q.Q. Lei, Sci. Rep. 6, 33508 (2016)

    Article  Google Scholar 

  5. G. Sui, S. Jana, W.H. Zhong, M.A. Fuqua, C.A. Ulven, Acta Mater. 56, 10 (2008)

    Article  Google Scholar 

  6. Z.M. Dang, M.S. Zheng, J.W. Zha, Small 12, 1688 (2016)

    Article  Google Scholar 

  7. K. Yang, X.Y. Huang, L.J. Fang, J.L. He, P.K. Jiang, Nanoscale 6, 24 (2014)

    Article  Google Scholar 

  8. Y. Yang, B.P. Zhu, Z.H. Lu, Z.Y. Wang, C.L. Fei, D. Yin, R. Xiong, J. Shi, Q.G. Chi, Q.Q. Lei, Appl. Phys. Lett. 102, 4 (2013)

    Google Scholar 

  9. B.H. Fan, J.W. Zha, D. Wang, J. Zhao, Z.M. Dang, Appl. Phys. Lett. 100, 1 (2012)

    Google Scholar 

  10. C.H. Zhang, Q.G. Chi, J.F. Dong, Y. Cui, X. Wang, Q.Q. Lei, Sci. Rep 6, 33508 (2016)

    Article  Google Scholar 

  11. Q. Li, L. Chen, M.R. Gadinski, S. Zhang, G. Zhang, U. Li, A. Iagodkine, Haque, L.Q. Chen, N. Jackson, Q. Wang, Nature 523, 7562 (2015)

    Google Scholar 

  12. X. Zhang, Y. Shen, Q.H. Zhang, L. Gu, Y.H. Hu, J.W. Du, Y.H. Lin, C.W. Nan, Adv. Mater 27, 5 (2015)

    Google Scholar 

  13. K. Yu, Y. Niu, Y. Bai, Y. Zhou, H. Wang, Appl. Phys. Lett. 102, 10 (2013)

    Google Scholar 

  14. Z.B. Pan, L.M. Yao, J.W. Zhai, B. Shen, S.H. Liu, H.T. Wang, J.H. Liu, J. Mater. Chem. A 4, 34 (2016)

    Google Scholar 

  15. F.H. Liu, Q. Li, J. Cui, Z.Y. Li, G. Yang, Y. Liu, L.J. Dong, C.X. Xiong, H. Wang, Q. Wang, Adv. Funct. Mater. 27, 20 (2017)

    Google Scholar 

  16. Q.G. Chi, J.F. Dong, C.H. Zhang, X.W. Wang, Q.Q. Lei, J. Mater. Chem. C 4, 4442 (2016)

    Article  Google Scholar 

  17. P.H. Hu, J.J. Wang, Y. Shen, Y.H. Guan, Y.H. Lin, C.W. Nan, J. Mater. Chem 1, 39 (2013)

    Article  Google Scholar 

  18. H. Luo, D. Zhang, L. Wang, C. Chen, J. Zhou, K.C. Zhou, RSC Adv. 5, 65 (2015)

    Google Scholar 

  19. Q.G. Chi, J.F. Dong, C.H. Zhang, C.P. Wong, X. Wang, Q.Q. Lei, J. Mater. Chem. C 4, 8179 (2016)

    Article  Google Scholar 

  20. J.W. Zha, Z.M. Dang, H.T. Song, Y. Yin, G. Chen, J. Appl. Phys. 108, 9 (2010)

    Article  Google Scholar 

  21. Q.G. Chi, J. Sun, C.H. Zhang, G. Liu, J.Q. Lin, Y.N. Wang, X. Wang, Q.Q. Lei, J. Mater. Chem. C 2, 172 (2014)

    Article  Google Scholar 

  22. B.C. Luo, X.H. Wang, Y.P. Wang, L.T. Li, J. Mater. Chem. A 2, 2 (2013)

    Google Scholar 

  23. Y. Yang, H.L. Sun, D. Yin, Z.H. Lu, J.H. Wei, R. Xiong, J. Shi, Z.Y. Wang, Z.Y. Liu, Q.Q. Lei, J. Mater. Chem. A 3, 9 (2015)

    Google Scholar 

  24. C.H. Zhang, Q.G. Chi, L.Z. Liu, Y. Chen, J.F. Dong, T. Ma, X. Wang, Q.Q. Lei, J. Mater. Sci. 28, 3 (2017)

    Google Scholar 

  25. G.R. Chen, X. Wang, J.Q. Lin, W.L. Yang, H.D. Li, Y.N. Wen, J. Phys. Chem. C 120, 50 (2016)

    Google Scholar 

  26. Y.F. Wang, J. Cui, Q.B. Yuan, Y.J. Niu, Y.Y. Bai, H. Wang, Adv. Mater. 27, 42 (2015)

    Google Scholar 

  27. R. Ma, A.F. Baldwin, C.C. Wang, I. Offenbach, M. Cakmak, R. Ramprasad, G.A. Sotzing, ACS Appl. Mater. Interfaces 6, 13 (2014)

    Google Scholar 

  28. Y.H. Wu, J.W. Zha, Z.Q. Yao, F. Sun, R.K. Li, Z.M. Dang, RSC. Adv. 5, 56 (2015)

    Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge the support of the National Science Foundation of China (61640019), the Open Foundation of State Key Laboratory of Electronic Thin Films and Integrated Devices (KFJJ201601), Science Funds for the Young Innovative Talents of HUST (201102).

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Authors and Affiliations

  1. Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin, 150080, People’s Republic of China

    Qingguo Chi, Zhiyou Gao, Changhai Zhang, Yang Cui, Jiufeng Dong, Xuan Wang & Qingquan Lei

  2. School of Electrical and Electronic Engineering, Harbin University of Science and Technology, Harbin, 150080, People’s Republic of China

    Qingguo Chi, Zhiyou Gao, Yang Cui & Xuan Wang

  3. State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, 610054, People’s Republic of China

    Qingguo Chi

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  1. Qingguo Chi
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Correspondence to Qingguo Chi.

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Chi, Q., Gao, Z., Zhang, C. et al. Dielectric properties of sandwich-structured BaTiO3/polyimide hybrid films. J Mater Sci: Mater Electron 28, 15142–15148 (2017). https://doi.org/10.1007/s10854-017-7390-8

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  • DOI: https://doi.org/10.1007/s10854-017-7390-8

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