Abstract
To better understand the corrosion behaviors of CoCrFeNi-based high-entropy alloys (HEAs), the CALculation of PHAse Diagrams (CALPHAD) method was used to simulate the Pourbaix diagrams for CoCrFeNi, CoCrFeNiCu and CoCrFeNiAl HEAs. Although the CALPHAD simulations were performed under equilibrium conditions, assisted by published experimental results on CoCrFeNi, CoCrFeNiCu and CoCrFeNiAl0.5 HEAs, the CALPHAD simulations provide insights into the corrosion behaviors, such as the oxidation layer pitting and forming potential, of the CoCrFeNi-based HEAs.
Similar content being viewed by others
References
Cantor B, Chang I, Knight P, Vincent A (2004) Microstructural development in equiatomic multicomponent alloys. Mater Sci Eng A 375:213–218
Yeh JW, Chen SK, Lin SJ et al (2004) Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv Eng Mater 6:299–303
Zhang Y, Zuo TT, Tang Z et al (2014) Microstructures and properties of high-entropy alloys. Prog Mater Sci 61:1–93. https://doi.org/10.1016/j.pmatsci.2013.10.001
Shun T-T, Chang L-Y, Shiu M-H (2012) Microstructure and mechanical properties of multiprincipal component CoCrFeNiMox alloys. Mater Charact 70:63–67. https://doi.org/10.1016/j.matchar.2012.05.005
Wang W-R, Wang W-L, Wang S-C, Tsai Y-C, Lai C-H, Yeh J-W (2012) Effects of Al addition on the microstructure and mechanical property of AlxCoCrFeNi high-entropy alloys. Intermetallics 26:44–51
He JY, Wang H, Huang HL et al (2016) A precipitation-hardened high-entropy alloy with outstanding tensile properties. Acta Mater 102:187–196. https://doi.org/10.1016/j.actamat.2015.08.076
He F, Wang Z, Cheng P et al (2016) Designing eutectic high entropy alloys of CoCrFeNiNbx. J Alloy Compd 656:284–289. https://doi.org/10.1016/j.jallcom.2015.09.153
He F, Wang Z, Niu S et al (2016) Strengthening the CoCrFeNiNb0.25 high entropy alloy by FCC precipitate. J Alloy Compd 667:53–57. https://doi.org/10.1016/j.jallcom.2016.01.153
Hsu Y-J, Chiang W-C, Wu J-K (2005) Corrosion behavior of FeCoNiCrCux high-entropy alloys in 3.5% sodium chloride solution. Mater Chem Phys 92:112–117. https://doi.org/10.1016/j.matchemphys.2005.01.001
Shi Y, Yang B, Xie X, Brechtl J, Dahmen KA, Liaw PK (2017) Corrosion of Al xCoCrFeNi high-entropy alloys: Al-content and potential scan-rate dependent pitting behavior. Corros Sci 119:33–45
Lin C-M, Tsai H-L (2011) Evolution of microstructure, hardness, and corrosion properties of high-entropy Al0.5CoCrFeNi alloy. Intermetallics 19:288–294
Pourbaix M (1974) Atlas of electrochemical equilibria in aqueous solutions. National Association of Corrosion, Houston
Pourbaix M (1973) Lectures on electrochemical corrosion. Plenum Press, New York
McCafferty E (2010) Introduction to corrosion science. Springer, Berlin
Zhang B, Gao M, Zhang Y, Yang S, Guo S (2015) Senary refractory high entropy alloy MoNbTaTiVW. Mater Sci Technol 31:1207–1213. https://doi.org/10.1179/1743284715Y.0000000031
Gao MC, Zhang B, Yang S, Guo SM (2016) Senary refractory high-entropy alloy HfNbTaTiVZr. Metall Mater Trans A 47(7):3333–3345
Zhang B, Gao M, Zhang Y, Guo S (2015) Senary refractory high-entropy alloy CrxMoNbTaVW. Calphad 51:193–201
Zhang B, Mu Y, Gao M, Meng W, Guo S (2017) On single-phase status and segregation of an as-solidified septenary refractory high entropy alloy. MRS Commun 7:78–83
Plyasunov AV, Shock EL (2001) Correlation strategy for determining the parameters of the revised Helgeson–Kirkham–Flowers model for aqueous nonelectrolytes. Geochim Cosmochim Acta 65:3879–3900
Zhang X (2011) Galvanic corrosion. Uhlig’s Corros Handb 51:123–143
Roberge PR (2008) Corrosion engineering: principles and practice. McGraw-Hill, New York
Talbot DE, Talbot JD (2007) Corrosion science and technology. CRC Press, Boca Raton
Gulliver G (1915) The quantitative effect of rapid cooling upon the constitution of binary alloys. J Inst Met 13:263–291
Chou H-P, Chang Y-S, Chen S-K, Yeh J-W (2009) Microstructure, thermophysical and electrical properties in AlxCoCrFeNi (0 ≤ x ≤ 2) high-entropy alloys. Mater Sci Eng B 163:184–189
Singh AK, Subramaniam A (2014) On the formation of disordered solid solutions in multi-component alloys. J Alloy Compd 587:113–119. https://doi.org/10.1016/j.jallcom.2013.10.133
Wu Z, Bei H, Otto F, Pharr GM, George EP (2014) Recovery, recrystallization, grain growth and phase stability of a family of FCC-structured multi-component equiatomic solid solution alloys. Intermetallics 46:131–140. https://doi.org/10.1016/j.intermet.2013.10.024
Kao Y-F, Chen T-J, Chen S-K, Yeh J-W (2009) Microstructure and mechanical property of as-cast, -homogenized, and-deformed AlxCoCrFeNi (0 ≤ x ≤ 2) high-entropy alloys. J Alloy Compd 488:57–64
He F, Wang Z, Wu Q, Li J, Wang J, Liu CT (2017) Phase separation of metastable CoCrFeNi high entropy alloy at intermediate temperatures. Scr Mater 126:15–19. https://doi.org/10.1016/j.scriptamat.2016.08.008
Kao Y-F, Chen S-K, Chen T-J, Chu P-C, Yeh J-W, Lin S-J (2011) Electrical, magnetic, and Hall properties of AlxCoCrFeNi high-entropy alloys. J Alloy Compd 509:1607–1614
Uhlig HH (2011) Uhlig’s corrosion handbook. Wiley, Hoboken
Castelli R (2009) Nuclear corrosion modeling: the nature of crud. Butterworth-Heinemann, Oxford
Craig BD (2013) Fundamental aspects of corrosion films in corrosion science. Springer, Berlin
Rahman A, Chawla V, Jayaganthan R, Chandra R, Ambardar R (2012) Hot corrosion of nanostructured Cr/Co–Al coatings. Surf Eng 28:285–293
Ratke L, Diefenbach S (1995) Liquid immiscible alloys. Mater Sci Eng R Rep 15:263–347
Wu P, Liu N, Zhou P et al (2016) Microstructures and liquid phase separation in multicomponent CoCrCuFeNi high entropy alloys. Mater Sci Technol 32:576–580
Oldfield JW (1988) Galvanic corrosion. ASTM International, West Conshohocken
Jien-Wei Y (2006) Recent progress in high entropy alloys. Ann Chim Sci Mat 31:633–648
Ervin G (1952) Structural interpretation of the diaspore–corundum and boehmite–γ-Al2O3 transitions. Acta Crystallogr A 5:103–108
Alwitt R, Diggle J (1976) Oxides and oxide films. Marcel Dekker, New York
Davis G, Moshier W, Long G, Black D (1991) Passive film structure of supersaturated Al–Mo Alloys. J Electrochem Soc 138:3194–3199
Junqueira RMR, Loureiro CRDO, Andrade MS, Buono VTL (2008) Characterization of interference thin films grown on stainless steel surface by alternate pulse current in a sulphochromic solution. Mater Res 11:421–426
S Fujimoto (2006) Pits and pores III: formation, properties, and significance for advanced materials. In: Proceedings of the international symposium. The Electrochemical Society
Shifler DA, Aylor DM (2005) CORROSION 2005. NACE International, Houston
Acknowledgements
The current work is funded by the NSF EPSCoR CIMM Project under Award #OIA-1541079.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhang, B., Zhang, Y. & Guo, S.M. A thermodynamic study of corrosion behaviors for CoCrFeNi-based high-entropy alloys. J Mater Sci 53, 14729–14738 (2018). https://doi.org/10.1007/s10853-018-2652-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-018-2652-2