Abstract
Anisotropic MnAlCuC and MnAlCuC/Fe polycrystalline flakes have been produced by surfactant-assisted ball milling. The [001] textured MnAlCuC flakes were formed via continuous basal cleavage along the (110) planes of the microparticles during the surfactant-assisted high-energy ball milling. The c-axes of most the grains are parallel to the flake surface. The remanent magnetization (Mr) of annealed MnAlCuC/Fe has an enhancement of around 62.4% compared with uncoated powders. A high coercivity up to 207.4 kA/m of as-milled MnAlCuC flakes was obtained due to the domain wall pinning effect of the defects and the associated strained areas.
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Zhu L, Nie S, Meng K, Pan D, Zhao J, Zheng H (2012) Multifunctional L10–Mn1.5 Ga films with ultrahigh coercivity, giant perpendicular magnetocrystalline anisotropy and large magnetic energy product. Adv Mater 24:4547–4551
Coey JM (2014) New permanent magnets; manganese compounds. J Phys Condens Matter 2:064211-1–064211-6
Le Breton JM, Bran J, Folcke E, Lucis M, Lardé R, Jean M, Shield JE (2013) Structural modifications in a Mn54Al43C3 melt-spun alloy induced by mechanical milling and subsequent annealing investigated by atom probe tomography. J Alloys Compd 581:86–90
Zeng Q, Baker I, Cui JB, Yan ZC (2007) Structural and magnetic properties of nanostructured Mn–Al–C magnetic materials. J Magn Magn Mater 308:214–226
Mican S, Benea D, Hirian R, Gavrea R, Isnard O, Pop V, Coldea M (2016) Structural, electronic and magnetic properties of the Mn50Al46Ni4 alloy. J Magn Magn Mater 401:841–847
Bance S, Bittner F, Woodcock TG, Schultz L, Schrefl T (2017) Role of twin and anti-phase defects in MnAl permanent magnets. Acta Mater 131:48–56
Singh N, Mudgil V, Anand K, Srivastava AK, Kotnala RK, Dhar A (2015) Influence of processing on structure property correlations in τ-MnAl rare-earth free permanent magnet material. J Alloys Compd 633:401–407
Liu ZW, Chen C, Zheng ZG, Tan BH, Ramanujan RV (2012) Phase transitions and hard magnetic properties for rapidly solidified MnAl alloys doped with C, B, and rare earth elements. J Mater Sci 47:2333–2338. https://doi.org/10.1007/s10853-011-6049-8
Zeng Q, Baker I, Z-c Yan (2006) Nanostructured Mn–Al permanent magnets produced by mechanical milling. J Appl Phys 99:08E902–08E903
Zuo WL, Xin Z, Zhao TY, Hu FX, Sun JR, Shen BG (2016) Ultrathin SmCo5 nanoflakes with high-coercivity prepared by solid particle (NaCl) and surfactant co-assisted ball milling. Sci Rep 6:25805-1–25805-6
Cui BZ, Zheng LY, Li WF, Liu JF, Hadjipanayis GC (2012) Single-crystal and textured polycrystalline Nd2Fe14B flakes with a submicron or nanosize thickness. Acta Mater 60:1721–1730
Su KP, Chen XX, Wang HO, Huo DX, Liu ZW (2016) Effect of milling on the structure and magnetic properties in Mn54Al46 flakes prepared by surfactant-assisted ball milling. Mater Charact 114:263–266
Saravanan P, Hsu JH, Vinod VTP, Černík M, Kamat SV (2015) Coercivity enhancement in Mn–Al–Cu flakes produced by surfactant-assisted milling. Appl Phys Lett 107:192407-1–192407-5
Madugundo R, Koylualkan O, Hadjipanayis GC (2016) Bulk Mn–Al–C permanent magnets prepared by various techniques. AIP Adv 6:056009-1–056009-6
Marshall LG, McDonald IJ, Lewis LH (2016) Quantification of the strain-induced promotion of τ-MnAl via cryogenic milling. J Magn Magn Mater 404:215–220
Park JH, Hong YK, Bae S, Lee JJ, Jalli J, Abo GS, Neveu N, Kim SG, Choi CJ, Lee JG (2010) Saturation magnetization and crystalline anisotropy calculations for MnAl permanent magnet. J Appl Phys 107:09A731-1–09A731-3
Fang H, Cedervall J, Casado FJM, Matej Z, Bednarcik J, Ångström J, Berastegui P, Sahlberg M (2016) Insights into formation and stability of τ-MnAlZx (Z = C and B). J Alloys Compd 692:198–203
Alleg S, Hamouda A, Azzaza S, Bensalem R, Sunol JJ, Greneche JM (2010) Solid state amorphization transformation in the mechanically alloyed Fe27.9Nb2.2B69.9 powders. Mater Chem Phys 122:35–40
Cui BZ, Li WF, Hadjipanayis GC (2011) Formation of SmCo5 single-crystal submicron flakes and textured polycrystalline nanoflakes. Acta Mater 59:563–571
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant Numbers 51601049, 11574066, 11604067); the Zhejiang Provincial Natural Science Foundation of China (Grant Number LQ14E010005); the Guangxi Key Laboratory of Information Materials (Grant Number 151007-K); and the Science and Technology Project of Zhejiang Province (Grant Number 2015C37041).
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Su, K.P., Wang, H.O., Huang, S. et al. Magnetic anisotropy and enhanced remanence in textured polycrystalline MnAlCuC-based flakes. J Mater Sci 53, 9823–9829 (2018). https://doi.org/10.1007/s10853-018-2274-8
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DOI: https://doi.org/10.1007/s10853-018-2274-8