Abstract
The density and viscosity of ternary Cr–Fe–Ni liquid alloys have been investigated over a wide temperature range. The density was measured using electromagnetic levitation as a container-less technique, while viscosity was measured by means of a high-temperature oscillating cup viscometer. Although, the concentration dependence of density shows the influence of the second order (binary) interaction parameter in excess volume, the influence of a third order (ternary) interaction parameter in excess volume can be neglected. The temperature dependences of the viscosities are well described by the Arrhenius law. The viscosity increases monotonically as Fe or Cr concentration increases. For constant temperature, the viscosity as a function of iron molar faction can be described by a thermodynamic model using the enthalpy of mixing as input parameter.
Similar content being viewed by others
References
Wakamatsu T, Ozawa S, Fukuyama H, Kobatake H, Watanabe M, Mizuno A, Hibiya T, (2008) Proceedings 29th Japan Symposium on Thermophysical Properties, Japan Society of Thermophysical Properties, Tokyo, p 179
Hirai M (1993) Iron Steel Inst Jpn Int 33:251
Kapty G (2003) Proceedings of MicroCad 2003, International Conference, Section, Metallurgy, University of Miskolc, Hungary, p 23
Sharan A, Nagasaka T, Cramb AW (1994) Met Mater Trans B 25:939
Brillo J, Egry I (2004) Z Metallkd 95:6911
Tsu Y, Takano K, Watanabe S, Shiraishi Y (1978) Tohoku Daigaku Senko Seiren Kenkyusho Iho 34:131
Kobatake H, Brillo J (2012) J Mater Sci. doi:10.1007/s10853-013-7274-0
Sato Y, Sugisawa K, Aoki D, Yamamura T (2005) Meas Sci Technol 16:363
Kehr M, Hoyer W, Egry I (2007) Int J Thermophys 28:1017
Schick M, Brillo J, Egry I, Hallstedt B (2012) J Mater Sci 47:8145. doi:10.1007/s10853-012-6710-x
Brillo J, Egry I (2004) Z Metallkd 95:6911
Brillo J, Egry I (2003) Int J Thermophys 24:1155
Vegard L (1921) Z. Phys 5:17
Adachi M, Schick M, Brillo J, Egry I, Watanabe M (2010) J Mater Sci 45:2002. doi:10.1007/s10853-009-4149-5
Krishnan S, Hansen GP, Hauge RH, Margrave JL (1990) High Temp Sci 29:17
Krishnan S, Yugawa K, Nordine PC (1997) Phys Rev B 55:8201
Kobatake H, Khosroabadi H, Fukuyama H (2012) Met Mat Trans A 43:2466
Hillert M, Qiu C (1990) Met Mat Trans A 21:1673
Brillo J, Egry I, Ho I (2006) Int J Thermophys 27:494
Ferris D, Quested PN (2002) NPL Report (A) 306
Roscoe R (1958) Proc Phys Soc 72:576
Kinzoku data book 4th edn (2004) The Japan Institute of metals, Maruzen, Tokyo, p 223
Brillo J, Egry I, Matsushita T (2006) Int J Thermophys 27:1778
Schick M, Brillo J, Egry I (2009) Int J Cast Met Res 22:82
Kozlow LY, Romanov LM, Petrov NN, Vuzov Izv (1983) Chernaya Metall 3:7
Brools RF, Dinsdale AT, Quested PN (2005) Meas Sci Technol 16:354
Miettinen J (1999) Calphad 23:231
Kehr M, Schick M, Hoyer W, Egry I (2008) High Temp High Press 37:361
Acknowledgements
Authors are grateful to Professor Dr. Dieter Herlach for a critical review of this study and his valuable suggestions. One of the authors (H. K.) is grateful to the German Academic Exchange Service DAAD for financial support (A/11/94004).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kobatake, H., Brillo, J. Density and viscosity of ternary Cr–Fe–Ni liquid alloys. J Mater Sci 48, 6818–6824 (2013). https://doi.org/10.1007/s10853-013-7487-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-013-7487-2