Abstract
Epoxy/zirconia hybrid materials were synthesized from a bisphenol-A type epoxy resin, zirconium-tetra-n-propoxide and acetic acid via in situ polymerization. Acetic acid was used to control the hydrolysis and condensation reaction of the zirconium-tetra-n-propoxide. As a result, the zirconia produced by the in situ polymerization was uniformly dispersed into the epoxy matrix on a nano scale or less, and the hybrid materials exhibited an excellent optical transparency. With the increasing zirconia contents, the storage modulus in the rubbery region increased and the peak area of tanδ in the glass transition temperature region decreased. These results indicate that their heat resistance of the hybrid materials could be improved by hybridization with zirconia. Furthermore, the refractive indices of the hybrid materials were significantly improved with the increasing zirconia contents.
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Li GZ, Wang L, Toghiani H, Daulton TL, Koyama K, Pittman CU Jr (2001) Macromolecules 34:8686
Li GZ, Wang L, Toghiani H, Daulton TL, Pittman CU Jr (2002) Polymer 43:4167
Habsuda J, Simon GP, Cheng YB, Hewitt DG, Tou H, Diggins DR (2001) J Polym Sci 26:1342
Ochi M, Takahashi R, Terauchi A (2001) Polymer 42:5151
Ochi M, Takahashi R (2001) J Polym Sci Part B 39:1071
Guan C, Lü C, Liu Y, Yang B (2006) J Appl Polym Sci 102:1631
Ching C, Chen W (2001) J Polym Sci Part A 39:3419
Chen W, Liu W, Wu P, Chen P (2004) Mater Chem Phys 83:71
Xiong M, Zhou S, You B, Wu L (2005) J Polym Sci Part B 43:637
Lee L, Chen W (2001) Chem Mater 13:1137
Luo K, Zhou S (2009) Thin Solid Films 517:5974
Hayashi H, Suzuki H, Kaneko S (1998) J Sol-Gel Sci Technol 12:87
Hayashi H, Suzuki H, Saito H (1992) J Ceram Soc Japan 100:122
Yi G, Sayer M (1996) J Sol-Gel Sci Technol 6:65
Yi G, Sayer M (1996) J Sol-Gel Sci Technol 6:75
Sayilkan H, Sener S, Arpac E (1995) J Inorg Organomet Polym 5:409
Nakamoto K (1963) Infrared and Raman spectra of inorganic and coordination compounds. John Wiley & Sons, New York
Ochi M, Okazaki M, shimbo M (1982) J Polym Sci Part B 20:689
Kukil B, Ritala M, Leskelä M (2000) Chem Vap Deposition 6:297
Wang Y, Zhang D, Shi L, Li L, Zhang J (2008) Mater Chem Phys 110:463
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Ochi, M., Nii, D., Suzuki, Y. et al. Thermal and optical properties of epoxy/zirconia hybrid materials synthesized via in situ polymerization. J Mater Sci 45, 2655–2661 (2010). https://doi.org/10.1007/s10853-010-4244-7
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DOI: https://doi.org/10.1007/s10853-010-4244-7