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Double clathrate hydrate of propane and hydrogen

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Abstract

Formation of the only cubic structure II double hydrate of propane and hydrogen occurs in the propane–hydrogen–water system. The decomposition curves of the double hydrate at low pressures are situated at 3–4° above the decomposition curve of propane hydrate; at pressures 2000–2500 bar double hydrate decompose at 20° above propane hydrate.

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Acknowledgement

This work was supported by RFBR project 08-03-00191-a and the Integration project of SB RAS No. 43.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry SD RAS, Lavrentieva ave. 3, Novosibirsk, 630090, Russian Federation

    Sergey S. Skiba, Eduard G. Larionov, Andrej Yu Manakov, Boris A. Kolesov & Eugeny Ya Aladko

  2. Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russian Federation

    Andrej Yu Manakov, Boris A. Kolesov & Aleksei I. Ancharov

  3. Institute of Solid State Chemistry SD RAS, Kutateladze str. 18, Novosibirsk, 630128, Russian Federation

    Aleksei I. Ancharov

Authors
  1. Sergey S. Skiba
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  2. Eduard G. Larionov
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  3. Andrej Yu Manakov
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  4. Boris A. Kolesov
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  5. Aleksei I. Ancharov
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  6. Eugeny Ya Aladko
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Correspondence to Andrej Yu Manakov.

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Skiba, S.S., Larionov, E.G., Manakov, A.Y. et al. Double clathrate hydrate of propane and hydrogen. J Incl Phenom Macrocycl Chem 63, 383–386 (2009). https://doi.org/10.1007/s10847-008-9521-6

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  • DOI: https://doi.org/10.1007/s10847-008-9521-6

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