Abstract
The solid complex of guest styrene included inside the channels of host γ-cyclodextrin (styrene/γ-CDchannel-IC) was formed in order to perform polymerization of styrene in a confined environment (γ-CD channels). The experimental molar ratio of styrene to γ-CD in styrene/γ-CDchannel-IC was found to be 2:1, which is consistent with molecular modeling studies, utilizing Quantum Mechanics PM3 parameters that indicate the γ-CD/two styrene molecular complex is the most energetically favorable. Consistent with modeling of the γ-CD/two styrene molecular complex, no experimental indication of intermolecular π–π interactions between the pairs of included styrene molecules inside the γ-CD channels was observed. Once included in the host γ-CD cavities, the thermal stability of normally volatile bulk styrene to elevated temperatures (much above its boiling point) was observed until the γ-CD host molecules themselves began to degrade at ∼ ∼300 °C. In addition, the thermal degradation of host γ-CD from the styrene/γ-CDchannel-IC was observed to be different from that of pure γ-CD due to co-degradation of styrene and γ-CD.
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Acknowledgements
The authors are grateful to the National Textile Center (US Dept. of Commerce) for funding. The authors would also thank North Carolina State University and the Middle East Technical University (Ankara, Turkey) for their support. We also thank Evren Aslan, and Michael D. Capracotta for performing the Direct Insertion Probe Pyrolysis Mass Spectrometry (DIP-MS) and solid-state UV-Vis experiments, respectively.
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Uyar, T., El-Shafei, A., Wang, X. et al. The Solid Channel Structure Inclusion Complex Formed Between Guest Styrene and Host γ-Cyclodextrin. J Incl Phenom Macrocycl Chem 55, 109–121 (2006). https://doi.org/10.1007/s10847-005-9026-5
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DOI: https://doi.org/10.1007/s10847-005-9026-5