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Self-Assembled Porphyrin Arrays via Zinc–Nitrogen Coordination

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Abstract

A series of alkene linked multiporphyrin zinc complexes have been synthesized and their ability to self-assemble in the presence of either 4,4-bipyridine or DABCO has been investigated. It was found that the sandwich complexes with 4,4-bipyridine proceeded via an intermediary 1:1 complex, whereas the sandwich complexes with DABCO formed discrete complexes. Further additions of an excess of DABCO lead to exchange from within the complex.

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Authors and Affiliations

  1. Chemistry Division MS J514, Los Alamos National Laboratory, 87544, Los Alamos, New Mexico, USA

    Paul G. Plieger & Anthony K. Burrell

  2. Nanomaterials Research Centre and Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand

    Simon B. Hall & David L. Officer

Authors
  1. Paul G. Plieger
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  2. Anthony K. Burrell
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  3. Simon B. Hall
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  4. David L. Officer
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Correspondence to Anthony K. Burrell.

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Plieger, P.G., Burrell, A.K., Hall, S.B. et al. Self-Assembled Porphyrin Arrays via Zinc–Nitrogen Coordination. J Incl Phenom Macrocycl Chem 53, 143–148 (2005). https://doi.org/10.1007/s10847-005-0992-4

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  • DOI: https://doi.org/10.1007/s10847-005-0992-4

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