Abstract
Heavy metals (HMs) are ubiquitous; they are found in soil, water, air, and all biological matrices. The toxicity, bioaccumulation potential, and deleterious effects of most of these metals on humans and the environment have been widely documented. Consequently, the detection and quantification of HMs in various environmental samples have become a pressing issue. The analysis of the concentrations of HMs is a vital component of environmental monitoring; hence, the selection of the most suitable analytical technique for their determination has become a topic of great interest in food, environment, and human health safety. Analytical techniques for the quantification of these metals have evolved. Presently, a broad range of HM analytical techniques are available with each having its outstanding merits as well as limitations. Most analytical scientists, therefore, adopt complementation of more than one method, with the choice influenced by the specific metal of interest, desired limits of detection and quantification, nature of the interference, level of sensitivity, and precision among others. Sequel to the above, this work comprehensively reviews the most recent advances in instrumental techniques for the determination of HMs. It gives a general overview of the concept of HMs, their sources, and why their accurate quantification is pertinent. It highlights various conventional and more advanced techniques for HM determination, and as one of its kind, it also gives special attention to the specific merits and demerits of the analytical techniques. Finally, it presents the most recent studies in this regard.
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References
Abuseleek, M., Farag, E., Seileek, M., & Alsayyed, M. (2015). Study of Heavy Metals Concentration in Cosmetics Purchased from Jordan Markets by ICP-MS and ICP-OES. https://doi.org/10.13140/RG.2.1.3547.5689
Addis, W., & Abebaw, A. (2017). Determination of heavy metal concentration in soils used for cultivation of Allium sativum L. (garlic) in East Gojjam Zone, Amhara Region, Ethiopia. Cogent Chemistry, 3, 1419422. https://doi.org/10.1080/23312009.2017.1419422
Agoro, M., Adeniji, A., Adefisoye, M., & Okoh, O. (2020). Heavy metals in wastewater and sewage sludge from selected municipal treatment plants in Eastern Cape Province. Water, 12, 2746. https://doi.org/10.3390/w12102746
Ahmed, A., Singh, A., Padha, B., Sundramoorth, A., Tomar, A., & Arya, S. (2022). UV–vis spectroscopic method for detection and removal of heavy metal ions in water using Ag doped ZnO nanoparticles. https://doi.org/10.1016/j.chemosphere.2022.135208
Ahmed, M., & Alatawi, A. (2022). Comparison of the ICP OES viewing modes efficiency in the estimation of cadmium (Cd) and lead (Pb) in whole blood samples. 208–214. https://doi.org/10.1080/25765299.2022.2090148
Ali, H., Khan, E., & Ilahi, I. (2019). Environmental chemistry and ecotoxicology of hazardous heavy metals: Environmental persistence, toxicity, and bioaccumulation. 6730305. https://doi.org/10.1155/2019/6730305Article ID 290593
Bahinting, S., Pollon, A., Segur, S. ( 2021). Bismuth film-coated gold ultramicroelectrode array for simultaneous quantification of Pb(II) and Cd(II) by square wave anodic stripping voltammetry. Sensors, 21(5), 1811. https://doi.org/10.3390/s21051811
Balali-Mood, M., Naseri, K., Tahergorabi, Z., Khazdair, M., & Sadeghi, M. (2021). Toxic mechanisms of five heavy metals:mercury, lead, chromium, cadmium, and arsenic. Frontier Pharmacolog, 12. https://doi.org/10.3389/fphar.2021.64972
Briffa, J., Sinagra, E., & Blundell, R. (2020). Heavy metal pollution in the environment and their toxicological effects on humans. 6, 9:e04691. https://doi.org/10.1016/j.heliyon.2020.e04691
Bulska, E., & Ruszcznska, A. (2017). Analytical techniques for trace element determination. Physical Sciences Reviews: 2(5)14. https://doi.org/10.1515/psr-2017-8002
Cheng F., Yng C., Zhou C., Lan L., Zhu H and Li Y. (2020). Simultaneous determination of metal ions in zinc sulfate solution using UV–vis spectrometry and SPSE-XGBoost Method.mSensors (Basel). 20(17), 4936. https://doi.org/10.3390/s20174936
Collingwood, A., & Adams, F. (2017). Chemical Imaging Analysis of the Brain with X-Ray Methods. https://doi.org/10.1016/j.sab.2017.02.013
Dinbore, W., Dabbo, W., & Washe, A. (2021). Differential pulse voltammetric determination of hexavalent chromium using nickel hexacyanoferrate modified glassy carbon electrode. Environmental Chemistry, Pollution & Waste Management. https://doi.org/10.1080/27658511.2021.1978633
Durai, L., & Badhu, S. (2022). Stripping voltammetry and chemometrics assisted ultra-selective. Sensors and Actuators Reports, 4. https://doi.org/10.1016/j.snr.2022.100097
Echioda, S., Ogunieye, A., Salisu, S., & Kolo, T. (2021). Spectrophotometric determination of selected heavy metals (Pb, Cr, Cd and As) in environmental, water and biological samples with synthesized glutaraldehyde phenyl hydrazone as the chromogenic reagent. European Journal of Advanced Chemistry, 2(3), 456. https://doi.org/10.24018/ejchem.2021.2.3.59
Elgrishi, N., Rountree, K., & MCCarthy, Rountree E, Eisenhart T. and Dempsey A. (2018). Practical beginner’s guide to cyclic voltammetry. Journal of Chemical Education, 95(2), 197–206. https://doi.org/10.1021/acs.jchemed.7b00361
Fang, L., Yan, X., Xiao, W., & Row, K. (2019).Extraction/preconcentration procedures for determination of metal ions in environmental samples. 1948965. https://doi.org/10.1155/2019/1948965
Fernandez, Z., Alvares, J., Alvarez, A., & Junior, O. (2020). Metal contaminants in rice from Cuba analyzed by ICP-MS, ICP-AES and CVAAS. Food Additives and Contaminants: Part B Surveillance, 14(1), 59–65. https://doi.org/10.1080/19393210.2020.1870576
Fernandez, Z., Valcarcel, L., Alvarez, A., & Torres, D. (2014). Application of cold vapor-atomic absorption (CVAAS) spectrophotometry and inductively coupled plasma-atomic emission spectrometry methods for cadmium, mercury and lead analyses of fish samples. Validation of the method of CVAAS. Food Control, 48, 37–42. https://doi.org/10.1016/j.foodcont.2014.05.056
Finsgar, M., Petovar, B., & Vodopivec, K. (2019). Bismuth-tin-film electrodes for Zn(II), Cd(II), and Pb(II) trace analysis. Microchemical Journal, 145, 676–685. https://doi.org/10.1016/j.microc.2018.11.036
Forero-Mendieta, J. R., Varón-Calderón, J. D., Varela-Martínez, D. A., Riaño-Herrera, D. A., Acosta-Velásquez, R. D., Benavides-Piracón, J. A. (2022). Validation of an analytical method for the determination of manganese and lead in human hair and nails using graphite furnace atomic absorption spectrometry. Separations, 9, 158. https://doi.org/10.3390/separations9070158
Gao, L., Di, D., Liu, X., & Teng, F. (2022). Comparative study of heavy metals analysis in mongolian medicines based on high sensitivity X-ray fluorescence spectroscopy and ICP-MS. Spectroscopy, 37(7), 20–27.
Gaur, V., Sharma, P., Gaur, P., Ariani, S., Ngo, H., & Guo, W. (2021). Sustainable mitigation of heavy metals from effluents: Toxicity and fate with recent technological advancements. Bioengineered, 12(1), 7297–7313. https://doi.org/10.1080/21655979.2021.197861
Gende, M., & Schmeling, M. (2022). Development of an Analytical Method for Determination of Lead and Cadmium in Biological Materials by GFAAS Using Escherichia Coli as Model Substance. https://doi.org/10.1371/journal.pone.0267775
Goday, S. (2019). Survey, screening, analysis of heavy metals in selected medicinal plants by UV-visible spectrophotometry method. Journal of Cleaner Production, 362(15), 132476.
Hall, M. (2017). X-ray fluorescence energy dispersive (ED-XRF) and wavelength dispersive (WD-XRF) spectrometry. in book: The Oxford handbook of archaeological ceramic analysis.
Harris, L., ByersLindsay, J., McHenryTimothy, J., Grund, II. (2019). HXRF techniques to quantify heavy metals in vegetables at low detection limits. Food Chemistry X, 1
Huang, F., Peng, S., Yang, H., Cao, H., Ma, N., & Ma, L. (2022). Development of a novel and fast XRF instrument for large area heavy metal detection integrated with UAV. Environmental Research, 214, 2. https://doi.org/10.1016/j.envres.2022.113841
Idris, M., Umaru, D., Aliu, A., & Musa, I. (2021). Atomic absorption spectroscopy analysis of heavy metals in water at Daura Gypsum Mining Site, Yobe, Nigeria. Journal of Foundations and Physics, 8(2), 234.
Infante, H., Warren, J., Chlmers, J., Dent, G., Todoli, J., Collingwood, J., Telling, N., Resano, M., & Crasto, D. (2019). Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019). Pure and Applied Chemistry. https://doi.org/10.1515/pac-2019-0203
Inobeme, A. (2021). Effect of heavy metals on activities of soil microorganism. Microbial Rejuvenation of Polluted Environment, 115–1421.
Inobeme, A., Mathew, J. T., Adetunji, C. O., Ajai, A. I., Okonkwo, S., Inobeme, J., Adekoya, M. A., & Bamigboye, M. O. (2022). Trace elements and rare earth elements in aerosols. atmospheric aerosols: Properties, sources and detection. Environmental Science Engineering and Technology. Nova Science Publishers, Inc. https://doi.org/10.52305/CXUG8701
Ipeaiyeda, A. R., & Ayoade, A. R. (2017). Flame atomic absorption spectrometric determination of heavy metals in aqueous solution and surface water preceded by co-precipitation procedure with copper (II) 8-hydroxyquinoline. Applied Water Science, 7, 4449–4459. https://doi.org/10.1007/s13201-017-0590-9
Jolly, Y. N., Iqbal, S., Rahman, M., Kabir, J., Akter, S., & Ahmad iftekhar, A. (2017). Energy dispersive X-ray fluorescence detection of heavy metals in Bangladesh cows’ milk. Heliyon, 3(9). https://doi.org/10.1016/j.heliyon.2017.e00403
Kaonga, C. C., Kosamu, I. B. M., Utembe, W. R. (2021). A review of metal levels in urban dust. Their Indonesian Journal of Chemistry, 9, 243–246. https://doi.org/10.22146/ijc.21537
Kasozi, K., Otime, E., Ninsiima, H., & Musoke, G. (2021). An analysis of heavy metals contamination and estimating the daily intakes of vegetables from Uganda
Kensova, R., Hynek, D., Kynicky, J., & Kizek r. (2014). Determination of metal ions in the plasma of children with tumour diseases by differential pulse voltammetry. International Journal of Electrochemical Science, 9(8), 4675–4691.
Khalafi, L., & Rafiee, M. (2017). Cyclic voltammetry. Tools and experimental techniques. Encyclopedia of Physical Organic Chemistry. https://doi.org/10.1002/9781118468586.epoc4036
Khalid, R., Helaluddin, A., Alaama, M., Abdualkader, A., Kasmuri, A., & Abbas, S. (2016). Reliability of graphite furnace atomic absorption spectrometry as alternative method for trace analysis of arsenic in natural medicinal products. Tropical Journal of Pharmaceutical Research, 15(9), 1967. https://doi.org/10.4314/tjpr.v15i9.22
Khan, A., Khan, M., & Saddiq, G. ( 2021)Energy-dispersive X-ray (EDX) fluorescence based analysis of heavy metals in marble powder, paddy soil and rice (Oryza sativa L.) with potential health risks in District Malakand, Khyber Pakhtunkhwa, Pakistan. 301–316.
Kim, Y., Rudasingwa, G., Cho, S., McWilliams, A., Kan, C., Kim, S., & Kimm, S. (2022) Comparison of the concentrations of heavy metals in PM2.5 analysed in three different global research institutions using X-ray fluorescence. Applied Science, 12(9), 4572. https://doi.org/10.3390/app12094572
Knihnicki, P., Skrzypek, A., Jakubowska, M., Porada, R., Rokici ́nska, A., Ku ́strowski, P., Ko ́scielniak, P., Kochana, J. (2022). Electrochemical sensing of Pb2+ and Cd2+ ions with the use of electrode modified with carbon-covered halloysite and carbon nanotubes. Molecules, 27, 4608. https://doi.org/10.3390/molecules271446
Kodom, K., Preko, K., & Boamah, D. (2012). X-ray fluorescence (XRF) analysis of soil heavy metal pollution from an industrial area in Kumasi, Ghana. 1006–1021 https://doi.org/10.1080/15320383.2012.712073
Koleleni, Y., & Hajj, O. (2014). Determination of concentration of heavy metals in fish from sea port of Zanzibar by energy dispersive X-ray fluorescence (Edxrf)Tanz. Journal Science, 40.
Kumar, M., Mouli, P., Reddy, S., & Mohn, S. (2004). Differential pulse anodic stripping voltammetric determination of Pb, Cd, Cu, and Zn in air, diet, and blood samples: Exposure assessment. Pages 463–475 2007. https://doi.org/10.1081/AL-200047792
Liu, N., Ye, W., Liu, G., & Zhao, G. (2022). Improving the accuracy of stripping voltammetry detection of Cd2+ and Pb2+ in the presence of Cu2+ and Zn2+ by machine learning: Understanding and inhibiting the interactive interference among multiple heavy metals. Analytica Chimica Acta, 1213, 339956. https://doi.org/10.1016/j.aca.2022.339956
Liu, N., Zhao, G., & Liu, G. (2020). Coupling square wave anodic stripping voltammetry with support vector regression to detect the concentration of lead in soil under the interference of copper accurately. Sensors, 20(23), 6792. https://doi.org/10.3390/s20236792
Ma, L., Li, Z., Yabo, S., Sun, S., & Oji, H. (2022). Insight into the interaction between heavy metals and water-soluble organic compounds in PM2.5 affected by heavy haze using ultraviolet–visible and fluorescence spectra combined with two-dimensional correlation spectroscopy. Journal of Cleaner Production, 363(15), 1332476. https://doi.org/10.1016/j.jclepro.2022.132476
Maciel, J., Souza, M., Silva, L., & Dias. D. (2019). Direct determination of Zn, Cd, Pb and Cu in wine by differential pulse anodic stripping voltammetry.
Malik, L., Bashir, A., Qureashi, A., & Pandit, A. (2019). Detection and removal of heavy metal ions: A review. Environmental Chemistry Letters, 17(46). https://doi.org/10.1007/s10311-019-00891-z
Manousi, N., Isaakidou, E., & Zachariadis, G. A. (2022). An inductively coupled plasma optical emission spectrometric method for the determination of toxic and nutrient metals in spices after pressure-assisted digestion. Applied Sciences, 12, 534. https://doi.org/10.3390/app12020534
Masindi, V., & Muedi, K. (2018). Environmental Contamination by Heavy Metals. https://doi.org/10.5772/intechopen.76082
Mathew, J. T., Mamman, A., Musah, M., Azeh, Y., Inobeme, A., Umar, M. T., & Otori, A. A. (2022). assessment of selected heavy metal content on dumpsites soil and vegetables grown in Muwo Metropolis, Niger State, Nigeria. Journal of Applied Sciences and Environmental Management, 26(9), 1473–1478.
Meddings, N., Heinrich, M., Overney, F., & Lee, J. (2020). Application of electrochemical impedance spectroscopy to commercial Li-ion cells: A review. Journal of Power Sources, 480, 228742. https://doi.org/10.1016/j.jpowsour.2020.228742
Mei, C., & Ahmad, S. (2021), A review on the determination heavy metals ions using calixarene-based electrochemical sensors. Arabian Journal of Chemistry, 14(9) 103303. https://doi.org/10.1016/j.arabjc.2021.103303
Mejias, E., & Garrido, T. (2016). Analytical Procedures for Determining Heavy Metal Contents in Honey: A Bioindicator of Environmental Pollution. https://doi.org/10.5772/66328
Miedico, O., Lammarino, M., Tarallo, M., & Chiaravalle, E. (2016). Application of inductively coupled plasma–mass spectrometry for trace element characterisation of equine meats. 2888–2900. https://doi.org/10.1080/10942912.2016.1256304
Mohammed, E., Mohammed, T., & Mohammed, A. (2018). Optimization of instrument conditions for the analysis for mercury, arsenic, antimony and selenium by atomic absorption spectroscopy. MethodsX, 5, 824–833. https://doi.org/10.1016/j.mex.2018.07.016
Mohammed, R., Fahad, O., Homoda, A., & Gamal, A. (2016). Evaluation of some toxic metals in blood samples of smokers in Saudi Arabia by inductive coupled plasma mass spectrometry. Tropical Journal of Pharmaceutical Research, 15,(12) 2669–2673.
Munteanu, I. G., & Apetrei, C. (2021). Analytical methods used in determining antioxidant activity: A review. International Journal of Molecular Sciences, 22, 3380. https://doi.org/10.3390/ijms22073380
Okonkwo, S. O., Jacob, J. O., Iyaka, Y. A., & Inobeme, A. (2021). Assessment of selected heavy metal concentrations in soils from a mining area in Minna. Niger State. Environmental Monitoring and Assessment, 193(3), 1–8.
Okpara, E., Fayemi, O., Wojuola, O., Onwudiwe, D., & Ebenso,. (2022). Electrochemical detection of selected heavy metals in water: A case study of African experiences. RSC Advances, 12(40), 26319–26361.
Onakpa, M. M., Njan, A. A., & Kalu, O. C. (2018). A review of heavy metal contamination of food crops in Nigeria. Annals of Global Health, 84(3), 488–494. https://doi.org/10.29024/aogh.2314
Oti, W. (2016). Review of principles and applications of AAS, PIXE and XRF and their usefulness in environmental analysis of heavy metals. Journal of Applied Chemistry, 9(6), 15–17.
Palisoc, S., Bentulan, J., & Natividad, M. (2019). Determination of trace heavy metals in canned food using Graphene/AuNPs/[Ru(NH3)6]3+/Nafion modified glassy carbon electrodes. Journal of Food Measurement and Characterization, 13(1). https://doi.org/10.1007/s11694-018-9930-1
Palisoc, S. T., Vitto, R. I. M., & Noel, M. G. (2021). Highly sensitive determination of heavy metals in water prior to and after remediation using Citrofortunella Microcarpa. Science and Reports, 11, 1394. https://doi.org/10.1038/s41598-020-80672-9
Pandey, S., Sachan, S., & Singh, S. (2019). Ultra-trace sensing of cadmium and lead by square wave anodic stripping voltammetry using ionic liquid modified graphene oxide. Materials Science for Energy Technologies, 2(3), 667–675. https://doi.org/10.1016/j.mset.2019.09.004Get
Petovar, B., Xhanari, K., & Finsgar m. (2017). A detailed electrochemical impedance spectroscopy study of a bismuth film glassy carbon electrode for trace metal analysis. Analytica Chimica Acta. https://doi.org/10.1016/j.aca.2017.12.020
Phadke, R. K., & Gaitonde, V. D. (2016). Analytical method validation for determination of heavy metal in capsule shell by using inductively coupled plasma mass spectrometry (ICP-MS). International Journal of Advanced Research, 4, 447–456(ISSN 2320–5407). www.journalijar.com
Pingarron, J., Labuda, J., Barek, J., & brett C., Camoes M., and Hibbert B. (2019). Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019). Pure and Applied Chemistry. https://doi.org/10.1515/pac-2018-0109
Popovic, S., Pantelic, A., Milovanovic, Z., Milinkov, J., & Vidovic, M. (2017). Analysis of tea for metals by flame and graphite furnace atomic absorption spectrometry with multivariate analysis. Atomic Spectroscopy, 2619–2633. https://doi.org/10.1080/00032719.2017.1307849
Povarov, V., Kopylova, T., Sinyakova, M., & Rudko, V. (2021). Quantitative determination of trace heavy metals and selected rock-forming elements in porous carbon materials by the X-ray fluorescence method. ACS Omega, 6(38), 24595–24601. https://doi.org/10.1021/acsomega.1c03217
Profrock D. and Prange A. (2019). Inductively coupled plasma–mass spectrometry (ICP-MS) for quantitative analysis in environmental and life sciences: A review of challenges, solutions, and trends. 66, 8. https://doi.org/10.1366/12-06681
Pushie, M., Pickering, I., Korbas, M., & George, G. (2014). Elemental and chemically specific X-ray fluorescence imaging of biological systems. Chemical Reviews, 114(17), 8499–8541.
RadaMendoza, M., Arciniegas-herrera, J., & Chito-Trujillo, D. (2019). Atomic absorption spectrometry for the quantification of cadmium in thermoformed and biodegradable flexible films made from cassava (Manihot esculenta crantz). Journal of thermoplastic composite materials, 34(5). https://doi.org/10.1177/0892705719850612
Rahman, M., Ahmed, Z., Seefat, S., Alam, R., & Idris, A. (2021). Assessment of heavy metal contamination in sediment at the newly established tannery industrial Estate in Bangladesh: A case study. Environmental Chemistry and Ecotoxicology., 4, 1–12. https://doi.org/10.1016/j.enceco.2021.10.001
Raimi, M. O., Sawyerr, H., Ezekwe, C., & Gabriel, S. (2022). Toxicants in water: Hydrochemical appraisal of toxic metals concentration and seasonal variation in drinking water quality in oil and gas field area of River State. Nigeria. https://doi.org/10.5772/intechopen.102656
Rhodes, C. J. (2019). Endangered elements, critical raw materials and conflict minerals. Chemosphere, 303(3), 135208. https://doi.org/10.1177/0036850419884
Ribeiro, B., Godinho, S., Silva, E., & Guilherme, R. (2017). Portable X-ray fluorescence (pXRF) applications in tropical Soil Science Ciênc. Agrotec, 41, 3. https://doi.org/10.1590/1413-70542017413000117
Sagagi, B., Bello, A., & Danyaya, H. (2022). Assessment of accumulation of heavy metals in soil, irrigation water, and vegetative parts of lettuce and cabbage grown along Wawan Rafi, Jigawa State. Nigeria. Environ Monit Assess., 194(10), 699. https://doi.org/10.1007/s10661-022-10360-w
Sandford, C., Edwards, M., Klunder, K., Hickey, D., Min, L., Koushik, B., Matthew, S., Sigman, White, H., & Minteer, D. (2019). A synthetic chemist’s guide to electroanalytical tools for studying reaction mechanisms. (Perspective) Chemistry Science, 10, 6404–6422. https://doi.org/10.1039/C9SC01545K
Sarojam, P., Hoult, D., & Chen, J. (2011). Heavy metal characterization of Chinese spices and herbs using GFAAS and CVAAS. Conference: Sustainability Today. https://doi.org/10.2495/ST110201
Saryati, S. (2009). Differential pulse anodic stripping voltammetry for determination of some heavy metals in uranium. Indonesian Journal of Chemistry, 145–154. https://doi.org/10.5599/jese.2014.0051
Scaeteanu, G., Maria, M., & Mot, A. (2021). An overview of methods used for quantification of heavy metal contents in vegetal samples. Romanian Journal of Ecology and Environmental Chemistry, 3, 2. https://doi.org/10.21698/rjeec.2021.201
Scandurra, A., & Mirabella, S. (2021). Square wave anodic stripping voltammetry applied to a nano-electrode for trace analysis of Pb(II) and Cd(II) ions in solution. IEEE Sensors Journal PP (99), 1–1. https://doi.org/10.1109/JSEN.2021.3051762
Senila, M., Neag, E., Cadar, O., Kovacs, E. D., Aschilean, I., & Kovacs, M. H. (2022). Simultaneous removal of heavy metals (Cu, Cd, Cr, Ni, Zn and Pb) from aqueous solutions using thermally treated romanian zeolitic volcanic tuff. Molecules, 27, 3938. https://doi.org/10.3390/molecules2712393
Shaheen, M., Tawfik, W., Mankola, A., & El-Mekawy, F. (2022). Assessment of contamination levels of heavy metals in the agricultural soils using ICP-OE. Soil and Sediment Contamination (formerly Journal of Soil Contamination), 16. https://doi.org/10.1080/15320383.2022.2123448
Sharma, I. (2010). ICP-OES: An advance tool in biological research. Open Journal of Environmental Biology. https://doi.org/10.17352/ojeb.000018
Silva, J., Queiroz, A., Oliveira, A., & Kartnaller, V. (2017). Advances in the application of spectroscopic techniques in the biofuel are over the last few decades. Frontiers in Bioenergy and Biofuels. https://doi.org/10.5772/65552
Simiao, D., Andrade, F., Lima, W., Jesus, M., Dorim, P., & Paiva, M. (2022). Determination of mercury concentration by a new spectrophotometric method and evaluation of bacterial diversity in river water samples from Brazil. Water supply, 22(5), 5535–5548. https://doi.org/10.2166/ws.2022.173
Sisay, B., Debebe, E., & Meresa, A. (2019). Analysis of cadmium and lead using atomic absorption spectrophotometer in roadside soils of jimma town. Journal of Analytical and Pharmaceutical Research, 8(4), 144-147. https://doi.org/10.15406/japlr.2019.08.00329
Somogyi, A., & Mocuta, C. (2015). Possibilities and challenges of scanning hard X-ray Spectro-microscopy techniques in material sciences. AIMS Materials Science, 2(2), 122–162. https://doi.org/10.3934/matersci.2015.2.122
Srogi, K., & Baranowska, I. (2000). Determination of heavy metals in samples of moss by DPV. Polish Journal of Environmental Studies, 9(4), 329–333.
Stortini, A., Baldo, M., Moro, G., & Moretto, L. (2020). Bio- and biomimetic receptors for electrochemical sensing of heavy metal ions. Sensors (basel)., 20(23), 6800. https://doi.org/10.3390/s20236800
Tamayo A., Gua A., Vidal J. and Maccini M. (2014)Analytical method for heavy metal determination in algae and turtle eggs from Guanahacabibes Protected Sea Park . 4, no. 4
Tesfaaye, E., Chandravanshi, B., & Tessema, M. (2021). Square wave anodic stripping voltammetric determination of Hg(II) with N1-Hydroxy-N1,N2-diphenylbenzamidine modified carbon paste electrode. Electroanalysis, 34,(5) 892–903. https://doi.org/10.1002/elan.202100468
Tholkappian M., Ravisankar R., Chandrasekaran A., Jebakumar, P., & Satapathy, K. (2018). Assessing heavy metal toxicity in sediments of Chennai Coast of Tamil Nadu using energy dispersive X-ray fluorescence spectroscopy (EDXRF) with statistical approach. Toxicology Reports, 5, 173–182. https://doi.org/10.1016/j.toxrep.2017.12.020
Tibebe, D., Hussen, M., Mulugeta, M., & Kassa, Y. (2022). Assessment of selected heavy metals in honey samples using atomic absorption spectroscopy (AAS), Ethiopia. BMC Chemistry, 16, 87. https://doi.org/10.21203/rs.3.rs-1682495/v
Tytla, M., Widziewicz-Rzoca, K., & Bernas, Z. (2022). A comparison of conventional and ultrasound-assisted BCR sequential extraction methods for the fractionation of heavy metals in sewage sludge of different characteristics. Molecule, 27(15), 4947. https://doi.org/10.3390/molecules27154947
Uddin, A. H., Khalid, R. S., & Alaama, M. (2016). Comparative study of three digestion methods for elemental analysis in traditional medicine products using atomic absorption spectrometry. Journal of Analytical Science and Technology, 7, 6. https://doi.org/10.1186/s40543-016-0085-6
Ullah, A. K. M. A., Maksud, M. A., & Khan, S. R. (2017). Development and validation of a GF-AAS method and its application for the trace level determination of Pb, Cd, and Cr in fish feed samples commonly used in the hatcheries of Bangladesh. Journal of Analytical Science and Technology, 8, 15. https://doi.org/10.1186/s40543-017-0124-y
Vito-Francesco, E., Alessandro, F., Qiuyue, Y., Bhawna, N., Ruslan, Á., Arben, M., Thorsten, K., Alexander, H., Wolfgang, Stach, Falko, Z., & Roza, A. (2022) An innovative autonomous robotic system for on-site detection of heavy metal pollution plumes in surface water. Environmental Monitoring and Assessment, 194(2), 122. https://doi.org/10.1007/s10661-021-09738-z
Voica, C., Dehelean, A., & Kovacs, M. H. (2012). The use of inductively coupled plasma mass spectrometry (ICP-MS) for the determination of toxic and essential elements in different types of food samples. AIP Conference Proceedings, 1425, 110. https://doi.org/10.1063/1.3681979\
Wilschefski, S., & Baxter, A. (2019). Inductively coupled plasma mass spectrometry: Introduction to analytical aspects. Clinical Biochemist Reviews, 40(3), 115–133. https://doi.org/10.33176/AACB-19-00024
Wobrauschek, P. (2007). X-ray fluorescence-energy dispersive (ED-XRF) and wavelength dispersive (WD-XRF) spectrometry. https://doi.org/10.1093/oxfordhb/9780199681532.013.21
Xie, R., Zhou, L., Lan, C., Fan, F., Xie, R., Tan, H., Xie, T., & Zhao, L. (2018). Nanostructured Carbon Black for Simultaneous Electrochemical Determination of Trace Lead and Cadmium by Differential Pulse Stripping Voltammetry. https://doi.org/10.1098/rsos.180282
Yao, M., Wang, D., & Zhao, M. (2015). Element analysis based on energy-dispersive X-ray fluorescence. Advances in Materials Science and Engineering, 1, 7. https://doi.org/10.1155/2015/290593
Yuan, Y., Liu, B., & Liu, H. (2022). Spatial distribution and source identification for heavy metals in surface sediments of East Dongting Lake, China. Scientific Reports, 12, 7940. https://doi.org/10.1038/s41598-022-12148-x
Zhao, G., Tran, T., Modha, S., & Mulchandani, A. (2022). Multiplexed anodic stripping voltammetry detection of heavy metals in water using nanocomposites modified screen-printed electrodes integrated with a 3D-printed flow cell. Frontier Chemistry, 17, 10:815805. https://doi.org/10.3389/fchem.2022.815805. eCollection 2022.
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All the authors are grateful to the various authors whose works were used as the source of information in writing this review work. They are also thankful to their respective institutions for the enabling research environment.
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Abel Inobeme, Tsado John Mathew, Ejeomo Jatto, Jonathan Inobeme, and Charles Adetunji contributed through conceptualization, investigation, resources, data curation, and writing. Maliki Muniratu, Benedict Onyeachu, Adekoya Mathew, Alexander Ajai, Mann Abdullahi, Eric Olori, Eziukwu Chinenye, Kelani Tawakalit, and Omali Iheanyichukwu Paul made their input by resources, writing – original draft preparation. Akhor Sadiq and all the authors revised the manuscript.
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Inobeme, A., Mathew, J.T., Jatto, E. et al. Recent advances in instrumental techniques for heavy metal quantification. Environ Monit Assess 195, 452 (2023). https://doi.org/10.1007/s10661-023-11058-3
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DOI: https://doi.org/10.1007/s10661-023-11058-3