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Detection of persistent OCPs and PCBs congeners in the near-shore coastal waters of Alexandria, Egypt

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Abstract

The residues of 19 EPA-organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) were determined in water samples collected from the near-shore surface water of Alexandria coast, Egypt, using gas chomatograph-electron capture detector (GC-ECD) and gas chromatograph-mass spectometer (GC-MS). Higher concentrations of hexachlorocyclohexane (HCH)s, TC, and 2,2-bis (p-chlorophenyl)-1,1,1-trichloroethane (DDT)s with 1.36, 0.556, and 36.97 ngl−1 were recorded, respectively, with a maximum of 165.46 ngl−1 of PCBs during June 2014, which was clearly affected by higher sewage activities during summer season. Among DDTs metabolites, p,p-DDT was the most dominant with a maximum of 36.31ngl−1 recorded at El-Montazah station during June 2014.

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References

  • Abdallah, A. M. A. (1994). Low density particulate role in pollution at Alexandria, Egypt. Toxicological and Environmental Chemistry, 41, 233–238.

    Article  Google Scholar 

  • Abdel Ghani, S. A., El Zokm, G., Shobier, A. H., Said, T. O., & Shreadah, M. A. (2013). Metal pollution in surface sediments of Abu-Qir Bay and the Eastern Harbour of Alexandria, Egypt. Egyptian Journal of Aquatic Research, 39, 1–12.

    Article  Google Scholar 

  • Barakat, A. O. (2004). Assessment of persistent toxic substances in the environment of Egypt. Environment International, 30, 309–322.

    Article  CAS  Google Scholar 

  • Berrojalbiz, N., Dachs, J., Del Vento, S., Ojeda, M. J., Valle, M. C., Castro-Jiménez, J., Mariani, G., Wollgast, J., & Hanke, G. (2011). Persistent organic pollutants in Mediterranean seawater and processes affecting their accumulation in plankton. Environmental Science and Technology, 45, 4315–4322.

    Article  CAS  Google Scholar 

  • Bidleman, T. F., Walla, M., Roura, R., Carr, E., & Schmidt, S. (1993). Organochlorine pesticides in the atmosphere of the southern ocean and Antarctica, January–March, 1990. Marine Pollution Bulletin, 26(5), 258–262.

    Article  CAS  Google Scholar 

  • Binelli, A., & Provini, A. (2003). DDT is still a problem in developed countries: the heavy pollution of Lake Maggiore. Chemosphere, 52, 717–723.

    Article  CAS  Google Scholar 

  • Binelli, A., Sarkar, S. K., & Chatterjee, M. (2008). A comparison of sediments quality guidelines for toxicity assessment in the Sunderban wetlands (Bay of Bengal, India). Chemosphere, 73, 1129–1137.

    Article  CAS  Google Scholar 

  • El Deeb, M. K., Said, T. O., El Naggar, M. H., & Shreadah, M. A. (2007). An assessment of pollution status of Abu-Qir Bay with PAHs and their possible origins. MEDCOAST Proceedings of the 8th International Conference on the Mediterranean Coastal Environment, Alexandria-Egypt, pp 895–906.

  • EL-Sabae, A., & Abo EL-Amayem, M. (1979). A survey to determine potential pollution of the Mediterranean by pesticides from the Egyptian region. Journee Etudee Pollution CIESM, 5, 149–153.

    Google Scholar 

  • Emara, H. I., & Shreadah, M. A. (2009). Distribution and composition of aliphatic aromatic petroleum hydrocarbons at some Hot Spots of Alexandria Coastal Water, Egypt. International Workshop on Integrated Coastal Zone Management (Izmir-Turkey 20–22 October),pp 201–217.

  • Emara, H. I., Said, T. O., El Naggar, N. A., & Shreadah, M. A. (2008). Aliphatic and polycyclic hydrocarbon compounds as chemical markers for pollution sources in relation to physico-chemical characteristics of the Eastern Harbour (Egyptian Mediterranean Sea). Egyptian Journal of Aquatic Research, 4, 1–19.

    Google Scholar 

  • European Commission (2000). Directive of the European Parliament and of the council 2000/60/EC establishing a framework for community action in the field of water policy, Off. European Commission C513.

  • Fytianos, K., Vasilikiotis, G., & Weil, L. (1985). Identification and determination of some trace organic compounds in coastal seawater of northern Greece. Bulletin Environmental Contamination Toxicology, 34, 390–395.

    Article  CAS  Google Scholar 

  • GESAMP, (1993). Impact of oil and related chemicals and wastes on the marine environment. Report Studies 50, 1–180.

  • Guitierrez, A. G., Garnacho, E., Bayona, J. M., & Albaiges, J. (2007). Screening ecological risk assessment of persistent organic pollutants in Mediterranean Sea sediments. Environment International, 33, 867–876.

    Article  Google Scholar 

  • Leoni, V., & Arca, S. U. D. (1976). Experimental data and critical review of the occurrence of hexachlorobenzene in the Italian environment. Science of the Total Environment, 5, 235.

    Article  Google Scholar 

  • Picer, M., Picer, N., & Nazansky, B. (1981). Persistent chlorinated hydrocarbons in the Rijeka Bay. Thalassia Jugoslavica, 17, 225–236.

    Google Scholar 

  • Risebrough, R. W., Hugget, R. J., Griffin, J. J., & Goldberg, E. D. (2000). Pesticide trans-Atlantic movements in the northeast trades. Science, 159, 1233–1236.

    Article  Google Scholar 

  • Said, T. O., & Hamed, M. A. (2001). Determination of organochlorine compounds in coastal water of the Gulf of Suez and river Nile, Egypt. Journal of Egyptian Academy Society Environmental Development, (DEnvironmental studies), 2(2), 125–139.

    Google Scholar 

  • Said, T. O., & Hamed, M. A. (2005). Distribution of chlorinated pesticides in surface water and fish of El Temsah and bitter lakes, Suez Canal. Egyptian Aquatic Research, 31(1).

  • Said, M. A., El-Deek, M. S., Mahmoud, T. H., & Shreadah, M. A. (1994). Effect of pollution on the hydrochemical characteristics of different water types in El-Max Bay area west of Alexandria, Egypt. Acta Adriatica, 34(P), 9–19.

    Google Scholar 

  • Shobier, A. H., Abdel Ghani, S. A., & Shreadah, M. A. (2011). Distribution of total mercury in sediments of four semi-enclosed Basins along the Mediterranean Coast of Alexandria. Egyptian Journal Aquatic Research, 37, 1–11.

    CAS  Google Scholar 

  • Shreadah, M. A., Said, T. O., Younis, A. M., & Farag, R. S. (2006). Physico-chemical characteristics of the semi closed areas along the Mediterranean Coast of Alexandria, Egypt. Egyptian Journal of Aquatic Research, 32, 38–48.

    CAS  Google Scholar 

  • Shreadah, M. A., Said, T. O., Abdel Moniem, M. I., Fathallah, E. M., & Mahmoud, M. E. (2011). PAHs in sediments along the semi-closed areas of Alexandria, Egypt. Journal of Environmental Protection, 2, 700–709.

    Article  CAS  Google Scholar 

  • Shreadah, M. A., Said, T. O., Othman, I. M., Fathallah, E. M., & Mahmoud, M. E. (2012). Polychlorinated biphenyls and chlorinated pesticides in sediments along the semi-closed areas of Alexandria, Egypt. Journal of Environmental Protection, 3, 141–149.

    Article  CAS  Google Scholar 

  • Shreadah, M. A., Said, T. O., Othman, I. M., Fathallah, E. I., & Mahmoud, M. E. (2014). OCPs and PCBs in seawater from Egyptian Mediterranean coast of Alexandria. Development in Analytical Chemistry, 1, 19–24.

    Google Scholar 

  • SPSS 15.0 Command Syntax (2006). SPSS base 15.0 User’s guide. http://www.spss.com

  • Tanabe, S. (2000). Asian developing regions: persistent organic pollutants in the seas. In C. C. Sheppard (Ed.), Seas at the millennium: an environmental evaluation. Amsterdam: Pergamon.

    Google Scholar 

  • UNEP/IOC/IAEA, (1991). Sampling of selected marine organisms and sample preparation for analysis of chlorinated hydrocarbons. References methods for marine pollution studies 12, Nairobi, United Nations Environment Program 17.

  • USEPA, (1996). Method 8082. Polychlorinated biphenyls (PCBs) by gas chromatography. US Environmental Protection Agency.

  • USEPA (United States Environmental Protection Agency) (1980). In: Watts RR, editor Analysis of pesticide residues in human and environmental samples—a compilation of methods selected for use in pesticide monitoring programs. EPA-600/80-038.

  • WHO/UNEP Working Group. (1990). Public health impact of pesticides used in agriculture. Geneva: World Health Organization.

    Google Scholar 

  • Younes, A.E.M. (2005). Speciation of organotin compounds in semi-closed areas along the Mediterranean Coast of Alexandria. M. Sc. in Chemistry, Faculty of science; Al-Azhar University, Egypt.

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Correspondence to Tarek O. Said.

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Said, T.O., Okbah, M.A., Mohamed, L.A. et al. Detection of persistent OCPs and PCBs congeners in the near-shore coastal waters of Alexandria, Egypt. Environ Monit Assess 187, 353 (2015). https://doi.org/10.1007/s10661-015-4537-z

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