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Synthesis of 1-Thia-5,7-Diazacyclopenta[cd]- Phenalenes from 6(7)-Derivatives of Perimidine

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Chemistry of Heterocyclic Compounds Aims and scope

Electrochemical oxidation of 6(7)-benzoylperimidines was shown to involve two stages of single electron transfer. Based on cyclic voltammetry and microelectrolysis data, a synthetic method was developed for the peri annelation of thiophene ring to benzoyl derivatives of perimidine. A new method was proposed for the preparation of 1-thia-5,7-diazacyclopenta[cd]phenalenes by fusing 6(7)-carbonyl derivatives of perimidine with elemental sulfur.

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This study was performed within the framework of Federal Targeted Program (state contract 16.740.11.0441) and with financial support from the Russian Foundation for Basic Research (grants 09-03-00677a, 14-03-31327 mol_a).

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Authors and Affiliations

  1. North Caucasus Federal University, 1a Pushkin St., Stavropol, 355009, Russia

    A. V. Aksenov, S. V. Shcherbakov & D. A. Lobach

  2. Astrakhan State Technical University, 16 Tamishchev St., Astrakhan, 414056, Russia

    N. N. Letichevskaya & E. A. Vasil’eva

Authors
  1. A. V. Aksenov
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  2. S. V. Shcherbakov
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  3. D. A. Lobach
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  4. N. N. Letichevskaya
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  5. E. A. Vasil’eva
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Correspondence to A. V. Aksenov.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 737-745, May, 2014.

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Aksenov, A.V., Shcherbakov, S.V., Lobach, D.A. et al. Synthesis of 1-Thia-5,7-Diazacyclopenta[cd]- Phenalenes from 6(7)-Derivatives of Perimidine. Chem Heterocycl Comp 50, 677–684 (2014). https://doi.org/10.1007/s10593-014-1520-5

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  • DOI: https://doi.org/10.1007/s10593-014-1520-5

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