Abstract
In order to provide antimicrobial activity to cotton, cotton fabrics were treated by montmorillonite (KSF), montmorillonite–dihydroxy ethylene urea (KSF–MDEU), KSF–chitosan (CS) and KSF–CS–MDEU solutions containing 12.5, 25 and 50 ppm silver ion. The effect of modification on the antibacterial activity of cotton fabrics was also evaluated after 10 cycles of washings. MDEU exhibited better antimicrobial activities after washing process. By using 25 ppm silver, KSF and CS modification solution, good performance in terms of antibacterial activity was obtained. The addition of CS and MDEU increased the whiteness index values of cotton fabrics treated with KSF containing different silver concentrations. The characterization of modified cotton samples was done by Fourier transform infrared spectroscopy, X-ray diffraction analysis, inductively coupled plasma-mass spectroscopy, scanning electron microscopy and thermogravimetric analysis.
Similar content being viewed by others
References
AATCC Technical Manual (1998) American Association of Textile Chemists and Colorists. vol. 73, Research Triangle Park, NC, pp. 186–188, 206–207, and 253–254
Ahmad MB, Shameli K, Darroudi M, Yunus WMZW, Ibrahim NA (2009) Synthesis and characterization of silver/clay nanocomposites by chemical reduction method. Am J Appl Sci 6(11):1909–1914. doi:10.3844/ajassp.2009 1909.1914
Altinisik A, Yurdakoc K (2011) Synthesis, characterization, and enzymatic degradation of chitosan/PEG hydrogel films. J Appl Polym Sci 3(122):1556–1563. doi:10.1002/app.34278
Altinisik A, Seki Y, Yurdakoc K (2009) Preparation and characterization of chitosan/KSF biocomposite film. Polym Compos 30(8):1035–1042. doi:10.1002/pc.20651
An J, Luo Q, Yuan X, Wang D, Li X (2011) Preparation and characterization of silver-chitosan nanocomposite particles with antimicrobial activity. J Appl Polym Sci 120(6):3180–3189. doi:10.1002/app.33532
Aranaz I, Mengíbar M, Harris R, Panos I, Miralles B, Acosta NG, Heras A (2009) Functional characterization of chitin and chitosan. Curr Chem Biol 3(2):203–230. doi:10.2174/187231309788166415
Bakar MA, Ismail J, Teoh CH, Tan WL, Bakar NHHA (2008) Modified natural rubber induced aqueous to toluene phase transfer of gold and platinum colloid. J Nanomater 6:1–8. doi:10.1155/2008/130295
Bordes P, Pollet E, Bourbigot S, Ave’rous L (2008) Structure and properties of PHA/clay nanobiocomposites prepared by melt intercalation. Macromol Chem Phys 209:1473–1484. doi:10.1002/macp.200800022
Carja G, Kameshima Y, Nakajima A, Dranca C, Okada K (2000) Nanosized silver-anionic clay matrix as nanostructured ensembles with antimicrobial activity. Int J Antimicrob Ag 2:56–64. doi:10.1016/j.ijantimicag.2009.08.008
Carja G, Kameshima Y, Nakajima A, Dranca C, Okada K (2009) Nanosized silver-anionic clay matrix as nanostructured ensembles with antimicrobial activity. Int J Antimicrob Ag 34(6):534–539. doi:10.1016/j.ijantimicag.2009.08.008
Cho J, Cho G (1997) Effect of a dual function finish containing an antibiotic and a fluorochemical on the antimicrobial properties and blood repellency of surgical gown materials. Text Res J 67:875–880. doi:10.1177/004051759706701203
Darder M, Colilla M, Ruiz-Hitzky E (2003) Biopolymer–clay nanocomposites based on chitosan intercalated in montmorillonite. Chem Mater 15(20):3774–3780. doi:10.1021%2fcm0343047
Dastjerdi R, Montazer M (2010) A review on the application of inorganic nano-structured materials in the modification of textiles: focus on anti-microbial properties. Colloid Surface B 79(1):5–18. doi:10.1016/j.colsurfb.2010.03.029
Dolgaev SI, Simakin AV, Voronov VV, Shafeev GA, Bozon-Verduraz F (2002) Nanoparticles produced by laser ablation of solids in liquid environment. Appl Surf Sci 186:546–551. doi:10.1016/S0169-4332(01)00634-1
Duarte ML, Ferreira MC, Marvao MR, Rocha J (2002) An optimised method to determine the degree of acetylation of chitin and chitosan by FTIR spectroscopy. Int J Biol Macromol 31(1–3):1–8. doi:10.1016/S0141-8130(02)00039-9
Dutta PK, Tripathi S, Mehrotra GK, Dutta J (2009) Perspectives for chitosan based antimicrobial films in food applications. Food Chem 114(4):1173–1182. doi:10.1016/j.colsurfa.2012.12.029
Forough M, Farhadi K (2010) Biological and green synthesis of silver nanoparticles. Turk J Eng Environ Sci 34:281–287. doi:10.3906/muh-1005-30
Gao Y, Cranston R (2008) Recent advances in antimicrobial treatments of textiles. Text Res J 78:60–72. doi:10.1177/0040517507082332
Gao Y, Yunzhao Y (2002) Deposition of silver nanoparticles on montmorillonite platelets by chemical plating. J Mater Sci 37:5083–5087. doi:10.1023/A:1021099918952
Gopakumar TG, Lee JA, Kontopoulou MJS (2002) Influence of clay exfoliation on the physical properties of montmorillonite/polyethylene composites. Parent Polym 43(20):5483–5490. doi:10.1016/S0032-3861(02)00403-2
Guo L, Yuan W, Lu Z, Li CM (2013) Polymer/nanosilver composite coatings for antibacterial applications. Colloid Surf A. doi:10.1016/j.colsurfa.2012.12.029
Gupta P, Bajpai MSK (2008) Investigation of antibacterial properties of silver nanoparticle-loaded poly (acrylamide-co-itaconic acid)-grafted cotton fabric. J Cotton Sci 12:280–286
Hema R, Ng PN, Amirul AA (2013) Green nanobiocomposite: reinforcement effect of montmorillonite clays on physical and biological advancement of various polyhydroxyalkanoates. Polym Bull 70:755–771. doi:10.1007/s00289-012-0822-y
Ingraham J, Ingraham C (1995) Introduction to Microbiology. Wadsworth, Belmont, pp 220–223
Kang HY, Jung MJ, Jeong YK (2000) Antimicrobial activity and the stability of an Ag+ solution made using metallic silver. Korean J Biotechnol Bioeng 15:521–524
Ki HY, Kim JH, Kwon SC, Jeong SH (2007) A study on multifunctional wool textiles treated with nano-sized silver. J Mater Sci 42:8020–8024. doi:10.1007/s10853-007-1572-3
Kim TH, Kim ParkHS, Shin US, Gong MS, Kim HW (2012) Size-dependent cellular toxicity of silver nanoparticles. J Biomed Mater Res A 100(4):1033–1043. doi:10.1016/j.colsurfa.2012.12.029
Kimiran Erdem A, Sanli Yurudu NO (2008) The evaluation of antibacterial activity of fabrics impregnated with dimethyltetradecyl (3-(trimethoxysilyl) propyl) ammonium chloride. IUFS J Biol 67(2):115–122
Kreibig U, Vollmer M,(1995) Optical properties of metal clusters. Springer series in material science. 25, Springer, Berlin; pp 26–76. ISBN: 978-3-540-57836-9
Lewin M, Sello SB (1984) Handbook of fiber science and technology: chemical processing of fibers and fabrics, functional finishes, vol. II, Part B, Marcel Decker, NY, pp 144–210 ISBN: 0824771184, 9780824771188
Link S, El-Sayed MA (2003) Optical properties and ultrafast dynamics of metallic nanocrystals. Annu Rev Phys Chem 54:331–366. doi:10.1146/annurev.physchem.54.011002.103759
Montazera M, Alimohammadi F, Shamei A, Rahimi MK (2012) Durable antibacterial and cross-linking cotton with colloidal silver nanoparticles and butane tetracarboxylic acid without yellowing. Colloid Surface B 89:196–202. doi:10.1016/j.colsurfb.2011.09.015
Nath SS, Chakdar D, Gope G (2007) Synthesis of CdS and ZnS quantum dots and their applications in electronics. Nanotrends 2:1–5
Nath SS, Chakdar D, Gope G, Avasthi DK (2008) Effect of 100 Mev nickel ions on silica coated ZnS quantum dot. J Nanoelectron Opt 3(2):180–183. doi:10.1166/jno.2008.212
Noginov MA, Zhu G, Bahoura M, Adegoke J, Small C, Ritzo BA, Drachev VP, Shalaev VM (2007) The effect of gain and absorption on surface plasmas in metal nanoparticles. Appl Phys B 86(3):455–460. doi:10.1007/s00340-006-2401-0
Olderman J (1997) Surgical nonwovens: where do we go from here. Nonwoven Ind 10:38–43
Padalkar S, Capadona JR, Rowan J, Weder C, Won Y-H, Stanciu LA, Moon RJ (2010) Natural biopolymers: novel templates for the synthesis of nanostructures. Langmuir 26(11):8497–8502. doi:10.1021/la904439p
Panacek A, Kvitek L, Prucek R, Kolar M, Vecerova R, Pizurova N, Sharma VK, Nevecna T (2006) Silver colloid nanoparticles: synthesis, characterization, and their antibacterial activity. J Phys Chem B 110:16248–16253. doi:10.1021/jp063826h
Pavlidou S, Papaspyrides CD (2008) A review on polymer-layered silicate nanocomposites. Prog Polym Sci 33:1119–1198. doi:10.1016/j.progpolymsci.2008.07.008
Potiyaraj P, Kumlangdudsana P, Dubas ST (2007) Synthesis of silver chloride nanocrystal on silk fibers. Mater Lett 61:2464–2466. doi:10.1016/j.matlet.2006.09.039
Raveendran P, Fu J, Wallen SL (2003) Completely “Green” synthesis and stabilization of metal nanoparticles”. J Am Chem Soc 125(46):13940–13941. doi:10.1021/ja029267j
Rhim JW, Hong SI, Park HM, Ng PKW (2006) Preparation and characterization of chitosan-based nanocomposite films with antimicrobial activity. J Agric Food Chem 54:5814–5822. doi:10.1021/jf060658h
Seki Y, Sarikanat M, Sever K, Durmuşkahya C (2012) Extraction and properties of Ferula communis (chakshir) fibers as novel reinforcement for composites materials. Compos Part B Eng 44(1):517–523. doi:10.1016/j.compositesb.2012.03.013
Shameli K, Ahmad MB, Yunus WMZW, Rustaiyan A, Ibrahim NA, Zargar M, Abdollahi Y (2010) Green synthesis of silver/montmorillonite/chitosan bionanocomposites using the UV irradiation method and evaluation of antibacterial activity. Int J Nanomed 5:875–887. doi:10.2147/IJN.S13632
Shameli K, Ahmad MB, Zargar M, Yunus WMZW, Ibrahim NA, Shabanzadeh P, Moghaddam MG (2011) Synthesis and characterization of silver/montmorillonite/chitosan bionanocomposites by chemical reduction method and their antibacterial activity. Int J Nanomed 6:271–284. doi:10.2147%2FIJN.S16043
Taleb A, Petit C, Pileni MP (1998) Optical properties of self assembled 2D and 3D superlattices of silver nanoparticles. J Phys Chem B 102:2214–2220. doi:10.1021/jp972807s
Treguer M, Rocco F, Lelong G, Nestour AL, Cardinal T, Maali A, Lounis B (2005) Flourescence silver oligomeric cluster and colloidal particles. Solid State Sci 7:812–818. doi:10.1016/j.solidstatesciences.2005.01.017
Tripathi S, Mehrotra GK, Dutta PK (2011) Chitosan–silver oxide nanocomposite film: preparation and antimicrobial activity. Bull Mater Sci 34(1):29–35. doi:10.1007/s12034-011-0032-5
Turker M (2004) Effect of production parameters on the structure and morphology of Ag nanopowders produced by inert gas condensation. Mater Sci Eng A 367:74–81. doi:10.1016/j.msea.2003.10.290
Wang S, Hou W, Wei L, Jia H, Liu X, Xu B (2007) Antibacterial activity of nano-SiO2 antibacterial agent grafted on wool surface. Surf Coat Tech 202:460–465. doi:10.1016/j.surfcoat.2007.06.012
Wasif AI, Laga SK (2009) Use of nano silver as an antimicrobial agent for cotton. AUTEX Res J 9(1):5–13
Webber D, Rutul W (2001) Use of metals as microbicides. In: Block S (ed) Preventing infections in healthcare. Disinfection, sterilization and preservation, 5th edn. Lippincott, Willams & Wilkins, New York, pp 415–430. ISBN: 0-683-30740-I
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Altınışık, A., Bozacı, E., Akar, E. et al. Development of antimicrobial cotton fabric using bionanocomposites. Cellulose 20, 3111–3121 (2013). https://doi.org/10.1007/s10570-013-0057-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10570-013-0057-6