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Catalytic applications of hydrotalcite-like materials and their derived forms

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Abstract

Hydrotalcite-like (HT-like) materials have been studied extensively in the last three decades. Although these materials initially perceived as potential anion exchangers, unrelenting efforts have also been attempted to use them as catalytic materials or as catalytic supports. There are varied ways by which one can use them for catalysis viz.; 1. Use them in as-synthesized form 2. Use them after calcining where the structural integrity of layered lattice is lost 3. Use the interlayer as functional spaces with moieties of catalytic interest 4. Use them after destruction or delamination and restructuring and 5. Use them as support or matrix. In this review, we are reporting the catalytic applications of HT-like materials and their derived forms carried out in our research group for the last 15 years in these various ways, covering reactions such as nitrous oxide decomposition, selective oxidation of organic compounds of industrial relevance and base-catalyzed isomerization of chemicals of perfumery interest. Although this review primarily focuses on our work, wherever applicable, related or relevant works from other groups are also presented to bestow comprehensiveness.

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Acknowledgments

The author would like to thank all his coworkers for their invaluable research contributions disclosed in this review. The author would also like acknowledge financial support/ fellowship from Department of Science and Technology, Council of Scientific & Industrial Research, Indian National Science Academy, all from India, Air Products & Chemicals Inc., USA, Alexander von Humboldt Foundation, Germany and Japan Society for Promotion of Science, Japan.

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  1. Silicates and Catalysis Discipline, Central Salt and Marine Chemicals Research Institute, GB Marg, Bhavnagar, 364002, India

    S. Kannan

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Kannan, S. Catalytic applications of hydrotalcite-like materials and their derived forms. Catal Surv Asia 10, 117–137 (2006). https://doi.org/10.1007/s10563-006-9012-y

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