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Selective Oxidation of Primary Alcohols to Carboxylic Acids Using Lacunary Polyoxometalates Catalysts and Hydrogen Peroxide

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Abstract

The first organic–inorganic lacunary polyoxometalate catalytic oxidation system with H2O2 as an oxidant for the preparation of aliphatic carboxylic acids from primary alcohols has been developed. This new catalytic system not only exhibits good catalytic activity with high selectivity toward acids, but also satisfactorily resolves the separation of the catalyst for reuse.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21878166) and the Shandong Provincial Natural Science Foundation of China (No. ZR2020MB131).

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Authors and Affiliations

  1. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Feng-Li Yu, Min-Xue Liu, Bing Yuan & Cong-Xia Xie

  2. State Key Laboratory Base of Eco-Chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Shi-Tao Yu

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  1. Feng-Li Yu
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  2. Min-Xue Liu
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  3. Bing Yuan
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  4. Cong-Xia Xie
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Correspondence to Feng-Li Yu or Shi-Tao Yu.

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Yu, FL., Liu, MX., Yuan, B. et al. Selective Oxidation of Primary Alcohols to Carboxylic Acids Using Lacunary Polyoxometalates Catalysts and Hydrogen Peroxide. Catal Lett 153, 1738–1742 (2023). https://doi.org/10.1007/s10562-022-04105-0

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  • DOI: https://doi.org/10.1007/s10562-022-04105-0

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