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Selective Oxidation of Cyclohexene with H2O2 Catalyzed by Resin Supported Peroxo Phosphotungstic Acid Under Mild Conditions

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Abstract

A series of modified chloromethyl polystyrene resins loaded with peroxo phosphotungstic acid catalysts were synthesized for the selective oxidation of cyclohexene. The surface of resin was enriched with high concentration quaternary ammonium salt, and grafted with a large amount of peroxo PW-anion through ion exchange. The novel resin catalyst showed excellent cyclohexene conversion and epoxide selectivity using 30% H2O2 as oxidant at ambient temperature. Furthermore, the resin catalyst exhibited excellent recycling stability, which can be reused by a simple filtration and the peroxo phosphotungstic acid did not leach into the solvent after reaction.

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Acknowledgements

We gratefully acknowledge the grants from the National Natural Science Foundation of China (Nos. 91634104 and 21776122) and National Key R&D Program of China (No.2018ZX07208010).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Separation Engineering Research Center, Key Laboratory of Mesoscopic Chemistry of MOE, Nanjing University, Nanjing, 210093, People’s Republic of China

    Jia Liu, Guoqiang Yang, Ying Liu, Zheng Zhou, Zhibing Zhang & Xingbang Hu

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  1. Jia Liu
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  2. Guoqiang Yang
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  3. Ying Liu
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  5. Zhibing Zhang
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Correspondence to Zhibing Zhang or Xingbang Hu.

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Liu, J., Yang, G., Liu, Y. et al. Selective Oxidation of Cyclohexene with H2O2 Catalyzed by Resin Supported Peroxo Phosphotungstic Acid Under Mild Conditions. Catal Lett 151, 147–152 (2021). https://doi.org/10.1007/s10562-020-03273-1

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