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Hydrogenation of Phenol to Cyclohexanone over Bifunctional Pd/C-Heteropoly Acid Catalyst in the Liquid Phase

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Abstract

Cyclohexanone is an important intermediate in the manufacture of polyamides in chemical industry, but direct selective hydrogenation of phenol to cyclohexanone under mild conditions is a challenge. Hydrogenation of phenol to cyclohexanone has been investigated in the presence of the composite catalytic system of Pd/C-heteropoly acid. 100% conversion of phenol and 93.6% selectivity of cyclohexanone were achieved within 3 h under 80 °C and 1.0 MPa hydrogen pressure. It has been found that a synergetic effect of Pd/C and heteropoly acid enhanced the catalytic performance of the composite catalytic system which suppressed the hydrogenation of cyclohexanone to cyclohexanol.

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Acknowledgements

This work was financially supported by the Natural Science Foundation of China (31370570), the Taishan Scholars Projects of Shandong (ts201511033), the Key R&D Project of Shandong (2017GGX40106), and the People’s Livelihood Science and Technology Project of Qingdao (173383NSH). The authors are also grateful for the experimental conditions which the Polyphase Fluid Reaction and Separation Engineering Key Laboratory of the Shandong gives.

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Authors and Affiliations

  1. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Shiwei Liu, Jing Han, Qiong Wu, Lu Li, Shitao Yu & Cong Zhang

  2. College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266510, China

    Bing Bian

  3. Department of Chemistry and Biochemistry, University of Michigan, Flint, 48503, MI, USA

    Jie Song

  4. Department of Chemical & Biomolecular Engineering, University of Tennessee Knoxville, 419 Dougherty Engineering Bldg, Knoxville, 37996, TN, USA

    Arthur J. Ragauskas

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  1. Shiwei Liu
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  2. Jing Han
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  3. Qiong Wu
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  4. Bing Bian
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  5. Lu Li
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Correspondence to Shiwei Liu.

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Liu, S., Han, J., Wu, Q. et al. Hydrogenation of Phenol to Cyclohexanone over Bifunctional Pd/C-Heteropoly Acid Catalyst in the Liquid Phase. Catal Lett 149, 2383–2389 (2019). https://doi.org/10.1007/s10562-019-02852-1

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  • DOI: https://doi.org/10.1007/s10562-019-02852-1

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