Abstract
Titanium containing mesoporous silicoaluminophosphate (MESO-TSAPO-37) molecular sieves were assembled from microporous titanium silicoaluminophosphate-37 (TSAPO-37) precursor possessing structural building units of SAPO-37. FT-IR studies and N2 sorption analysis supported the presence of microporosity on the walls of the mesoporous surface. The composite MESO-TSAPO-37 material showed promising catalytic activity in oxidation of cyclohexene. The catalyst showed complete conversion (100 %) of olefin with selective formation of allylic products (80 %). The catalytic activity persisted for several runs.
Graphical Abstract
Titanium substituted MESO-TSAPO-37 materials was assembled in presence of surfactant from microporous precursors of TSAPO-37 by a two step procedure. Thoroughly characterized MESO-TSAPO-37 was used for allylic oxidation of cyclohexene which resulted in 100 % conversion and 80 % selectivity towards allylic product.
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Acknowledgments
Authors express their sincere thanks to UGC (No. 41-237/2012/(SR)) India for the financial support. Authors are also thankful to USIC, University of Delhi, for the support on instrumentation facility and Dr. R. Nagarajan, University of Delhi for his support on use of powder XRD facility under DST. RY and AKS are grateful to UGC and CSIR, India for their senior research fellowship.
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Yadav, R., Singh, A.K. & Sakthivel, A. Synthesis and Catalytic Application of Mesoporous Titanium Silicoaluminophosphate-37 (MESO-TSAPO-37) Molecular Sieves Assembled from Microporous TSAPO-37 Precursor. Catal Lett 146, 800–810 (2016). https://doi.org/10.1007/s10562-015-1688-z
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DOI: https://doi.org/10.1007/s10562-015-1688-z