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A Novel Photocatalytic System Constructed Using Eosin Y, Titanium Dioxide, and Keggin-Type Platinum(II)- and Aluminum(III)-Coordinated Polyoxotungstates for Hydrogen Production from Water Under Visible Light Irradiation

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Abstract

A novel photocatalytic system constructed using Eosin Y, α-Keggin-type diplatinum(II)-coordinated tungstophosphate Cs3[α-PW11O39{cis-Pt(NH3)2}2]·8H2O (Cs-Pt-1), α-Keggin-type mono-aluminum(III)-coordinated tungstosilicate K5[α-SiW11{Al(OH2)}O39]·7H2O (K-Al-1), and titanium dioxide achieved a steady rate of hydrogen evolution with highly effective utilization of platinum sites from aqueous triethanolamine solution during a long-term visible light irradiation.

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Acknowledgments

This work was supported by the Ministry of Education, Culture, Sports, Science and Technology of Japan. We also acknowledge Mr. Wataru Unno (Shizuoka University) for the synthesis and characterization of K-Al-1 and TMA-Al-4, and Mr. Daisuke Miyamae (Shizuoka University) for the UV–Vis and NMR measurements.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka, 422-8529, Japan

    Shota Hattori, Yuki Ihara & Chika Nozaki Kato

  2. Green Chemistry Research Division, Research Institute of Green Science and Technology, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka, 422-8529, Japan

    Chika Nozaki Kato

Authors
  1. Shota Hattori
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  2. Yuki Ihara
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  3. Chika Nozaki Kato
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Corresponding author

Correspondence to Chika Nozaki Kato.

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Hattori, S., Ihara, Y. & Kato, C.N. A Novel Photocatalytic System Constructed Using Eosin Y, Titanium Dioxide, and Keggin-Type Platinum(II)- and Aluminum(III)-Coordinated Polyoxotungstates for Hydrogen Production from Water Under Visible Light Irradiation. Catal Lett 145, 1703–1709 (2015). https://doi.org/10.1007/s10562-015-1574-8

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  • DOI: https://doi.org/10.1007/s10562-015-1574-8

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