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Efficient Kinetic Resolution of (R,S)-2-Octanol Catalyzed by Magnetite-Immobilized Yarrowia lipolytica Lipase in Mixed Ionic Liquids

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Abstract

The resolution of (R,S)-2-octanol catalyzed by magnetite-immobilized Yarrowia lipolytica lipase in ionic liquids was investigated. The optimal activity and enantioselectivity of the lipase were obtained in a mixture of [EMIM]BF4 and [OMIM]BF4 (v/v = 5:5). Excellent reusability of the enzyme-ionic liquid system was observed in consecutive batch reactions.

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Acknowledgments

The work was financially supported by the National Basic Research Program of China (No. 2013CB733600), the National Natural Science Foundation of China (No. 21176241) and the Key Deployment Program of Chinese Academy of Sciences (KSZD-EW-Z-015). We thank Dr. Amanda Stiles (the Chinese Academy of Sciences Fellowships for Young International Scientists, No. 2011Y1GA01) for helping to edit this manuscript.

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Authors and Affiliations

  1. National Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, People’s Republic of China

    Ying Liu, Chen Guo & Chun-Zhao Liu

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  1. Ying Liu
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  2. Chen Guo
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  3. Chun-Zhao Liu
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Correspondence to Chun-Zhao Liu.

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Liu, Y., Guo, C. & Liu, CZ. Efficient Kinetic Resolution of (R,S)-2-Octanol Catalyzed by Magnetite-Immobilized Yarrowia lipolytica Lipase in Mixed Ionic Liquids. Catal Lett 144, 1552–1556 (2014). https://doi.org/10.1007/s10562-014-1303-8

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  • DOI: https://doi.org/10.1007/s10562-014-1303-8

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