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Ni/NaX: A Bifunctional Efficient Catalyst for Selective Hydrogenolysis of Glycerol

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Abstract

Non-noble metal Ni/NaX catalyst was prepared and used in the hydrogenolysis of aqueous glycerol. Characterization by XRD, SAED, H2 chemisorption, ICP and NH3-TPD techniques disclosed that the proper strong acid sites were responsible for the high activity and selectivity. Over Ni/NaX catalyst, conversion of glycerol reached 86.6% with 94.6% selectivity to glycols including 1,2-proplyene glycol and ethylene glycol under 6.0 MPa H2 pressure at 200 °C after 10 h reaction. Additionally, the effects of time, temperature, and H2 pressure were investigated in detail.

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Acknowledgments

We thank the Knowledge Innovation Program of the Chinese Academy of Sciences (K2006D1) support for our research.

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Authors and Affiliations

  1. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, 116023, Dalian, People’s Republic of China

    Jing Zhao, Weiqiang Yu, Chen Chen, Hong Miao, Hong Ma & Jie Xu

  2. Graduate University of Chinese Academy of Sciences, 100049, Beijing, People’s Republic of China

    Jing Zhao & Weiqiang Yu

Authors
  1. Jing Zhao
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  2. Weiqiang Yu
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  3. Chen Chen
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  4. Hong Miao
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  5. Hong Ma
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  6. Jie Xu
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Corresponding author

Correspondence to Jie Xu.

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Zhao, J., Yu, W., Chen, C. et al. Ni/NaX: A Bifunctional Efficient Catalyst for Selective Hydrogenolysis of Glycerol. Catal Lett 134, 184–189 (2010). https://doi.org/10.1007/s10562-009-0208-4

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  • DOI: https://doi.org/10.1007/s10562-009-0208-4

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