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Graphite Oxide as a Novel Host Material of Catalytically Active Pd Nanoparticles

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Abstract

Graphite oxide (GO) was utilized as a novel host material for Pd nanoparticles of controlled crystallite size. Immobilization of the Pd nanoparticles from a stable Pd sol in GO resulted in the formation of organophilic Pd–GO, a layer-structured material, which was characterized by ICP-AES, XRD and TEM. Pd–GO proved to be a highly active and stereoselective catalyst in liquid-phase alkyne hydrogenations under mild conditions.

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References

  1. Brodie BC (1860) Ann Chim Phys 59:466

    Google Scholar 

  2. Hofmann U, Frenzel A (1930) Ber Deut Chem Ges 63:1248

    Article  Google Scholar 

  3. Clauss A, Plass R, Boehm HP, Hofmann U, Anorg Z (1957) Allgem Chem 291:205

    Article  CAS  Google Scholar 

  4. Hummers WS Jr, Offeman RE (1958) J Am Chem Soc 80:1339

    Article  CAS  Google Scholar 

  5. Boehm HP, Hofmann U (1962) Z Naturforscher B17:150

    Google Scholar 

  6. He H, Riedl T, Lerf A, Klinowski J (1996) J Phys Chem 100:19954

    Article  CAS  Google Scholar 

  7. Szabó T, Tombácz E, Illés E, Dékány I (2006) Carbon 44:537

    Article  Google Scholar 

  8. Boehm HP, Clauss A, Fischer G, Hofmann U (1962) In: Proceedings of the Fifth Conference on Carbon. Pergamon Press, Oxford

  9. Liu Z, Wang Z-M, Yang X, Ooi K (2002) Langmuir 18:4926

    Article  CAS  Google Scholar 

  10. Dékány I, Krüger-Grasser R, Weiss A (1998) Colloid Polym Sci 276:570

    Article  Google Scholar 

  11. Beckett RJ, Croft RC (1952) J Phys Chem 56:929

    Article  CAS  Google Scholar 

  12. Stankovich S, Piner RD, Nguyen ST, Ruoff RS (2006) Carbon 44:3342

    Article  CAS  Google Scholar 

  13. Bourlinos AB, Gournis D, Petridis G, Szabó T, Szeri A, Dékány I (2003) Langmuir 19:6050

    Article  CAS  Google Scholar 

  14. Lerf A, He H, Forster M, Klinowski J (1998) J Phys Chem B 102:4477

    Article  CAS  Google Scholar 

  15. Lerf A, Buchsteiner A, Pieper J, Schöttl S, Dékány I, Szabó T, Boehm HP (2006) J Phys Chem Solids 67:1106

    Article  CAS  Google Scholar 

  16. Kotov NA (2006) Nature 442:254

    Article  CAS  Google Scholar 

  17. MatsuoY, Hatase K, Sugie Y. Chem Commun (1999) 43

  18. Kyotani T, Moriyama H, Tomita A (1997) Carbon 35:1185

    Article  CAS  Google Scholar 

  19. Király Z, Veisz B, Mastalir Á, Rázga Z, Dékány I (1999) Chem Commun 1925

  20. Mastalir Á, Király Z, Szöllősi G, Bartók M (2000) J Catal 194:146

    Article  CAS  Google Scholar 

  21. Mastalir Á, Király Z (2003) J Catal 220:372

    Article  CAS  Google Scholar 

  22. Hontoria-Lucas C, López-Peinado AJ, de López-González J, Rojas-Cervantes ML, Martín-Aranda RM (1995) Carbon 33:1585

    Article  CAS  Google Scholar 

  23. Matsuo Y, Niwa T, Sugie Y (1999) Carbon 37:897

    Article  CAS  Google Scholar 

  24. Aben PC (1968) J Catal 10:224

    Article  CAS  Google Scholar 

  25. Carturan G, Facchin G, Cocco GS, Enzo S, Navazio G (1982) J Catal 76:405

    Article  CAS  Google Scholar 

  26. Mastalir Á, Király Z, Berger F (2004) Appl Catal A: Gen 269:161

    Article  CAS  Google Scholar 

Download references

Acknowledgment

This work was supported by the Hungarian Research Fund (OTKA Grants T 047390 and T 068152) and the Bolyai János Foundation.

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Correspondence to Ágnes Mastalir.

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Mastalir, Á., Király, Z., Benkő, M. et al. Graphite Oxide as a Novel Host Material of Catalytically Active Pd Nanoparticles. Catal Lett 124, 34–38 (2008). https://doi.org/10.1007/s10562-008-9503-8

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  • DOI: https://doi.org/10.1007/s10562-008-9503-8

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