Abstract
Silica-supported titanium dioxide (TiO2/SiO2) and Ti-MCM 41 catalysts have been used for transesterification of dimethylcarbonate (DMC) and phenol to methylphenylcarbonate (MPC). The structure and the chemical state of titanium species in TiO2/SiO2 and Ti-MCM 41 have been investigated by means of X-ray diffraction (XRD), X-ray absorption near edge structure (XANES) for Ti K-edge and X-ray photoelectron spectroscopy (XPS). To understand the role of pore size on the activity of catalysts, different pore size silica supports (Q-series) were utilized in TiO2/SiO2 catalysts. Similarly, to understand the effect of Ti symmetry on the activity of catalysts, Ti-MCM 41 was used with different Ti-loadings. It was observed that the Ti surface area was an only important factor to achieve highest activity. In case of Ti-MCM 41 catalysts, as the Ti-loading increased octahedral symmetry increased and tetrahedral symmetry decreased. But, turnover rates based on the surface Ti atoms were independent of the Ti symmetry. They are also similar to those obtained for TiO2/SiO2 catalysts. Showing that transesterification of DMC and phenol over Ti-based catalysts is a structure insensitive reaction.
Similar content being viewed by others
References
Komiya K, Fukuoka S, Aminaka M, Hasegawa K, Hachiya H, Okamoto H, Watanabe T, Yoneda H, Fukawa I, Dozon T (1996) Green chemistry: designing chemistry for the environment. American Chemical Society, Washington DC. p 20
Chemistry in Britain (1994) 30:970
Gong J, Ma X, Wang S (2007) Appl Catal A 316:1
Kim WB, Joshi UA, Lee JS (2004) Ind Eng Chem Res 43:1897
Shaikh AG, Sivaram S (1996) Chem Rev 96:951
Song HY, Park ED, Lee JS (2000) J Mol Catal A 154:243
Fu Z-H, Ono Y (1997) J Mol Catal A 118:293
Cao M, Meng Y, Lu Y (2005) Catal Commun 6:802
Zhou WQ, Zhao XQ, Wang YJ, Zhang JY (2004) Appl Catal A 260:19
Mei FM, Pei Z, Li GX (2004) Org Process Res Dev 8:372
Fukuoka S, Deguchi R, Tojo M (1992) US Patent 5166393
Shaikh AG, Sivaram S (1992) Ind Eng Chem Res 31:1167
Lee H, Kim SJ, Ahn BS, Lee WK, Kim HS (2003) Catal Today 87:139
Kim WB, Lee JS (1999) Catal Lett 59:83
Kim WB, Lee JS (1999) J Catal 185:307
Kim WB, Kim YG, Lee JS (2000) Appl Catal A 194–195:403
Rhee CH, Lee JS (1997) Catal Today 38:213
Newville MJ (2001) J Synchrotron Rad 8:322
Bordiga S, Coluccia S, Lamberti C, Marchese L, Zecchina A, Boscherini F, Buffa F, Genoni F, Leofanti G, Petrini G, Vlaic G (1994) J Phys Chem 98:4125
Kim WB, Choi SH, Lee JS (2000) J Phys Chem B 104:8670
Kim WB, Choi SH, Lee JS (2001) J Phys Chem B 105:6274
Lee JS, Kim WB, Choi SH (2001) J Synchrotron Rad 8:163
Greegor RB, Lytle FW, Sandstrom DR, Wong J, Schultz P (1983) J Non-Cryst Sol 55:27
Sandstrom DR, Lytle FW, Wei PSP, Greegor RB, Wong J, Schultz P (1980) J Non-Cryst Sol 41:201
Acknowledgments
We appreciate the support of the Korea Ministry of Education and Human Resources Development through the BK 21 program. Experiments at PAL were supported in part by MOST and POSTECH. UAJ thanks to Dr. Nark Eon Sung for helpful discussion.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Joshi, U.A., Choi, S.H., Jang, J.S. et al. Transesterification of Dimethylcarbonate and Phenol Over Silica Supported TiO2 and Ti-MCM 41 Catalysts: Structure Insensitivity. Catal Lett 123, 115–122 (2008). https://doi.org/10.1007/s10562-008-9403-y
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-008-9403-y