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Investigation of 12-Tungstophosphoric Acid Supported on Ce0.5Zr0.5O2 Solid Solution

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Abstract

The nature of the Keggin ions of tungstophosphoric acid interacting with Ce0.5Zr0.5O2 solid solution has been investigated. The vibrational study shows additional IR features at 1051 and 957 cm−1 which are correlated to the primary Keggin anions interacting with Lewis sites involving Ce4+ and Zr4+ ions, and thus affecting the P–O and W=Oterminal bonds. The IR study indicates the formation of interfacial Ce4+–O–W and Zr4+–O–W bonds. The chemisorbed Keggin molecular layers on Ce0.5Zr0.5O2 show activity towards conversion of acetophenone to styrene by Meerwein–Ponndorf–Verley reduction followed by dehydration. The activity is correlated with the relative intensities of IR peaks at 1051 and 957 cm−1 of the perturbed Keggin molecular layers.

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References

  1. DiMonte R, Kašpar J (2005) J Mater Chem 15:633

    Article  CAS  Google Scholar 

  2. Ranga Rao G, Sahu HR (2001) Proc Indian Acad Sci Chem Sci 113:651

    Google Scholar 

  3. Tomishige K, Kunimori K (2002) Appl Catal A Gen 237:103

    Article  CAS  Google Scholar 

  4. Tomishige K, Furusawa Y, Ikeda Y, Asadullah M, Fujimoto K (2001) Catal Lett 76:71

    Article  CAS  Google Scholar 

  5. Sato S, Takahashi R, Sodesawa T, Yamamoto N (2004) Catal Commun 5:397

    Article  CAS  Google Scholar 

  6. Mishra BG, Ranga Rao G (2006) J Mol Catal A Chem 243:204

    Article  CAS  Google Scholar 

  7. Solinas V, Rombi E, Ferino I, Cutrufello MG, Colón G, Navío JA (2003) J Mol Catal A Chem 204–205:629

    Article  CAS  Google Scholar 

  8. Hamoudi S, Sayari A, Belkacemi K, Bonneviot L, Larachi F (2000) Catal Today 62:379

    Article  CAS  Google Scholar 

  9. Ranga Rao G, Sahu HR, Mishra BG (2003) React Kinet Catal Lett 78:151

    Article  CAS  Google Scholar 

  10. Cutrufello MG, Ferino I, Solinas V, Primavera A, Trovarelli A, Auroux A, Picciau C (1999) Phys Chem Chem Phys 1:3369

    Article  CAS  Google Scholar 

  11. Kuang W, Rives A, Fournier M, Hubaut R (2003) Appl Catal A Gen 250:221

    Article  CAS  Google Scholar 

  12. Dias JA, Caliman E, Dias SCL, Paulo M, de Souza ATCP (2003) Catal Today 85:39

    Article  CAS  Google Scholar 

  13. Izumi Y, Hasebe R, Urabe K (1983) J Catal 84:402

    Article  CAS  Google Scholar 

  14. Sulikowski B, Haber J, Kubacka A, Pamin K, Olejniczaka Z, Ptaszyński J (1996) Catal Lett 39:27

  15. Olejniczak Z, Sulikowski B, Kubacka A, Gąsior M (2000) Topics Catal 11/12:391

    Article  CAS  Google Scholar 

  16. Sulikowski B, Rachwalik R (2003) Appl Catal A 256:173

    Article  CAS  Google Scholar 

  17. Watanabe Y, Yamamoto K, Tatsumi T (1999) J Mol Catal A Gen 145:281

    Article  CAS  Google Scholar 

  18. Misono M (2001) Chem Comm 1141

  19. Nowińska K, Fiedorow R, Adamiec J (1991) J Chem Soc Faraday Trans 87:749

    Article  Google Scholar 

  20. Misono M (1988) Catal Rev Sci Eng 30:339

    Article  Google Scholar 

  21. Gomez-Garcia MA, Pitchon V, Kiennemann A (2005) Environ. Sci Technol 39:638

    Article  CAS  Google Scholar 

  22. Newman AD, Lee AF, Wilson K, Young NA (2005) Catal Lett 102:45

    Article  CAS  Google Scholar 

  23. Kozhevnikov IV, Kloetstra KR, Sinnema A, Zandbergen HW, van Bekkum H (1996) J Mol Catal A Chem 114:287

    Article  CAS  Google Scholar 

  24. Klemperer WG, Wall CG (1998) Chem Rev 98:297

    Article  CAS  Google Scholar 

  25. Pierre AC (1991) Ceram Bull 70:1281

    CAS  Google Scholar 

  26. Muthuraman M, Patil KC (1998) Mater Res Bull 33:655

    Article  CAS  Google Scholar 

  27. Kaspar J, Fornasiero P, Balducci G, Di Monte R, Hickey N, Sergo V (2003) Inorg Chim Acta 349:217

    Article  CAS  Google Scholar 

  28. Kishimoto H, Omata T, Otsuka-Yao-Matsuo S, Ueda K, Hosono H, Kawazoe H (2000) J Alloys Compd 312:94

    Article  CAS  Google Scholar 

  29. Okuhara T, Mizuno N, Misono M (1996) Adv Catal 41:113

    Article  CAS  Google Scholar 

  30. Rocchiccioli-Deltcheff C, Fournier M, Franck R (1983) Inorg Chem 22:207

    Article  CAS  Google Scholar 

  31. Escribano VS, López EF, Panizza M, Resini C, Amores JMG, Busca G (2003) Solid State Sci 5:1369

    Article  CAS  Google Scholar 

  32. Kanakaraju S, Mohan S, Sood AK (1997) Thin Solid Films 305:191

    Article  CAS  Google Scholar 

  33. Dutta G, Waghmare UV, Baidya T, Hegde MS, Priolkar KR, Sarode PR (2006) Catal Lett 108:165

    Article  CAS  Google Scholar 

  34. Fernández-García M, Martínez-Arias A, Iglesias-Juez A, Belver C, Hungría AB, Conesa JC, Soria J (2000) J Catal 194:385

    Article  CAS  Google Scholar 

  35. Devassy BM, Halligudi SB (2005) J Catal 236:313

    Article  CAS  Google Scholar 

  36. Loridant S, Feche C, Essayem N, Figueras F (2005) J Phys Chem B 109:5631

    Article  CAS  Google Scholar 

  37. Scheithauer M, Grasselli RK, Knözinger H (1998) Langmuir 14:3019

    Article  CAS  Google Scholar 

  38. López-Salinas E, Hernández-Cortéz JG, Schifter I, Torres-Garćia E, Navarrete J, Gutiérrez-Carrillo A, López T, Lottici PP, Bersani D (2000) Appl Catal A Gen 193:215

    Article  Google Scholar 

  39. Dias JA, Osegovic JP, Drago RS (1999) J Catal 183:83

    Article  CAS  Google Scholar 

  40. Dias AS, Pillinger M, Valente AA (2006) Micropor Mesopor Mater 94:214

    Article  CAS  Google Scholar 

  41. Angelis A, Amarilli S, Berti D, Montanari L, Perego C (1999) J Mol Catal A Chem 146:37

    Article  Google Scholar 

  42. Devassy BM, Halligudi SB, Hegde SG, Halgeri AB, Lefebvre F (2002) Chem Commun 1074

  43. Devassy BM, Lefebvre F, Halligudi SB (2005) J Catal 231:1

    Article  CAS  Google Scholar 

  44. Klemperer WG, Wall CG (1998) Chem Rev 98:297

    Article  CAS  Google Scholar 

  45. Fonasiero P, Di Monte R, Ranga Rao G, Kaspar J, Meriani S, Trovarelli A, Graziani M (1995) J Catal 151:168

    Article  Google Scholar 

  46. Ranga Rao G (1999) Bull Mater Sci 22:89

    Article  Google Scholar 

  47. Hodnett BK, Moffat JB (1985) J Catal 91:93

    Article  CAS  Google Scholar 

  48. Ortiz JIG, de Rivas B, Fonseca RL, Velasco JRG (2006) Appl Catal B Environ 65:191

    Article  CAS  Google Scholar 

  49. Hodnett BK, Moffat JB (1984) J Catal 88:253

    Article  CAS  Google Scholar 

  50. He T, Yao J (2006) Prog Mater Sci 51:810

    Article  CAS  Google Scholar 

  51. Bernal S, Calvino JJ, Gatica JM, Cartes CL, Pintado JM (2002) In: Trovarelli A (ed) Catalysis by ceria and related materials, vol. 2, Ch. 4. Imperial College Press, London

  52. Kumbhar PS, Sanchez-Valente J, Lopez J, Figueras F (1998) Chem Commun 535

  53. Zhu Y, Jaenicke S, Chuah GK (2003) J Catal 218:396

    Article  CAS  Google Scholar 

  54. Zhu Y, Liu S, Jaenicke S, Chuah G (2004) Catal Today 97:249

    Article  CAS  Google Scholar 

  55. Zhu Y, Chuah GK, Jaenicke S (2006) J Catal 241:25

    Article  CAS  Google Scholar 

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Acknowledgment

The first author would like to thank the Defence Research and Development Organization (DRDO), New Delhi, for providing financial support under Grant No. ERIP/ER/0300231/M/01.

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  1. National Centre for Catalysis Research, Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600 036, India

    G. Ranga Rao & T. Rajkumar

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  1. G. Ranga Rao
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  2. T. Rajkumar
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Correspondence to G. Ranga Rao.

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Ranga Rao, G., Rajkumar, T. Investigation of 12-Tungstophosphoric Acid Supported on Ce0.5Zr0.5O2 Solid Solution. Catal Lett 120, 261–273 (2008). https://doi.org/10.1007/s10562-007-9279-2

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  • DOI: https://doi.org/10.1007/s10562-007-9279-2

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