Solid solutions of phosphate and vanadate calcium hydroxyapatites were synthesized and the catalytic activities for the oxidative dehydrogenation of propane to propylene on those catalysts were examined. Although the conversion of propane and the selectivity to propylene were 7.6 and 3.5% on calcium hydroxyapatite (CaHAp), the incorporation of vanadate to CaHAp by V/P=0.05 (atomic ratio) resulted in the enhancement of the conversion and the selectivity to 17.2 and 52.4%, respectively, corresponding to those on Mg2V2O7 under the same reaction conditions (14.0 and 50.9%, respectively).
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
S. Sugiyama E. Nitta H. Hayashi J.B. Moffat (2000) Appl. Catal. A Gen. 198 171 Occurrence Handle10.1016/S0926-860X(99)00521-9
S. Sugiyama T. Shono E. Nitta H. Hayashi (2001) Appl. Catal. A Gen. 211 123 Occurrence Handle10.1016/S0926-860X(00)00864-4
S. Sugiyama T. Shono D. Makino T. Moriga H. Hayashi (2003) J. Catal. 214 8 Occurrence Handle10.1016/S0021-9517(02)00101-X
S. Sugiyama T. Hashimoto N. Shigemoto H. Hayashi (2003) Catal. Lett. 89 229 Occurrence Handle10.1023/A:1025758614040
S. Sugiyama T. Hashimoto Y. Morishita N. Shigemoto H. Hayashi (2004) Appl. Catal. A Gen. 270 253 Occurrence Handle10.1016/j.apcata.2004.05.018
S. Sugiyama T. Hashimoto Y. Tanabe N. Shigemoto H. Hayashi (2005) J. Mol. Catal. A Chem. 277 255 Occurrence Handle10.1016/j.molcata.2004.10.046
C.B. Boechat J.G. Eon A.M. Rossi C.A.C. Perez R.A.S. San Gil (2000) Phys. Chem. Chem. Phys. 2 4225 Occurrence Handle10.1039/b004339g
C.B. Boechat J. Terra J.G. Eon D.E. Ellis A.M. Rossi (2003) Phys. Chem. Chem. Phys. 5 4290 Occurrence Handle10.1039/b306176k
T. Hattori, Shokubai Sekkei (ed. by Catal. Soc. Jpn.), Catalyst Design (Kodansya, Tokyo, 1989), pp. 163–166.
E.R. Kreidler F.A. Hummel (1970) Am. Miner. 55 170
K. Chen A. Khodakov J. Yang A.T. Bell E. Iglesia (1999) J. Catal. 186 325 Occurrence Handle10.1006/jcat.1999.2510
V.D. Makwana Y.-C. Son A.R. Howell S.L. Suib (2002) J. Catal. 210 46 Occurrence Handle10.1006/jcat.2002.3680
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sugiyama, S., Osaka, T., Hashimoto, T. et al. Oxidative Dehydrogenation of Propane on Calcium Hydroxyapatites Partially Substituted with Vanadate. Catal Lett 103, 121–123 (2005). https://doi.org/10.1007/s10562-005-6513-7
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10562-005-6513-7