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Study of Cu, Cu-Ni and Rh-modified Cu porous layers as electrode materials for the electroanalysis of nitrate and nitrite ions

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Abstract

Three porous materials (Cu, a Cu-Ni alloy with 70 at.% Cu and Rh-modified Cu) have been tested as electrodes for the electroanalysis of nitrate and nitrite ions, in either neutral or basic media, using mainly a flow injection technique. Porous Cu and Cu-Ni were prepared by electrodeposition at high current density, exploiting the transient template action of hydrogen bubbles. Rh-modified Cu electrodes were obtained from porous Cu, through a galvanic displacement reaction. All materials had a linear response for both nitrates and nitrites, at concentrations up to 10−3 M, at least. Sensitivities, detection limits and stability were determined. Compared with Cu, used as a benchmark, (i) Rh-modified Cu had higher sensitivity for nitrates, comparable sensitivity for nitrites, lower or comparable detection limits and overall better stability; (ii) Cu-Ni had lower sensitivity, but exhibited lower detection limits and more stable performance for most analyte/medium combinations.

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Authors and Affiliations

  1. IENI CNR, Corso Stati Uniti 4, 35127, Padua, Italy

    Nicola Comisso, Sandro Cattarin, Paolo Guerriero, Luca Mattarozzi, Marco Musiani, Lourdes Vázquez-Gómez & Enrico Verlato

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  1. Nicola Comisso
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  2. Sandro Cattarin
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  3. Paolo Guerriero
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  4. Luca Mattarozzi
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  5. Marco Musiani
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  6. Lourdes Vázquez-Gómez
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  7. Enrico Verlato
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Correspondence to Marco Musiani.

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Comisso, N., Cattarin, S., Guerriero, P. et al. Study of Cu, Cu-Ni and Rh-modified Cu porous layers as electrode materials for the electroanalysis of nitrate and nitrite ions. J Solid State Electrochem 20, 1139–1148 (2016). https://doi.org/10.1007/s10008-015-2915-7

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  • DOI: https://doi.org/10.1007/s10008-015-2915-7

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