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Mesoporous silica xerogel modified with bridged ionic silsesquioxane used to immobilize copper tetrasulfonated phthalocyanine applied to electrochemical determination of dopamine

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Abstract

Silica xerogel was modified with an ionic silsesquioxane containing the cationic 1,4-diazoniabicyclo[2.2.2]octane bridged group and it was used as matrix for immobilization of copper tetrasulfonated phthalocyanine, resulting in Si/Db/CuTsPc material. This material was characterized by ultraviolet-visible and infrared spectroscopy, elemental and thermogravimetric analyses, nitrogen adsorption-desorption isotherms, and scanning electron microscopy. The Si/Db/CuTsPc material was used to develop a carbon paste electrode for dopamine determination. The electrochemical behavior of dopamine was evaluated by cyclic voltammetry and chronoamperometry. The optimal experimental conditions were determined (pH = 4.5 and oxygen atmosphere) using a 0.1 mol L−1 phosphate buffer solution. The carbon paste electrode modified with the Si/Db/CuTsPc material shows a linear response for current intensity with the dopamine concentration in the range of 0.010 to 0.107 mmol L−1. The detection limit was 0.42 μmol L−1, and the sensitivity was 7.15 μA (mmol L−1)−1, making the system promising to be applied as electrochemical sensor for dopamine.

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Acknowledgments

The authors are grateful to CNPQ (Conselho Nacional de Desenvolvimento Científico e Tecnológico), FAPERGS (Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul), and CAPES (Coordenação de Aperfeiçoamento Pessoal de Nível Superior) for financial support and fellowships.

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Authors and Affiliations

  1. LSS – Instituto de Química, UFRGS, CP 15003, CEP 91501-970, Porto Alegre, RS, Brazil

    Monique Deon, Elisangela Muncinelli Caldas, Danielle Santos da Rosa, Eliana Weber de Menezes, Silvio Luis Pereira Dias, Tania Maria Haas Costa, Leliz Ticona Arenas & Edilson Valmir Benvenutti

  2. LLO – Instituto de Física, UFRGS, CP 15015, CEP 91501-970, Porto Alegre, RS, Brazil

    Marcelo Barbalho Pereira

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  1. Monique Deon
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  2. Elisangela Muncinelli Caldas
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  3. Danielle Santos da Rosa
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Correspondence to Edilson Valmir Benvenutti.

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Deon, M., Caldas, E.M., da Rosa, D.S. et al. Mesoporous silica xerogel modified with bridged ionic silsesquioxane used to immobilize copper tetrasulfonated phthalocyanine applied to electrochemical determination of dopamine. J Solid State Electrochem 19, 2095–2105 (2015). https://doi.org/10.1007/s10008-014-2687-5

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