Abstract
LiCoPO4 nanoparticles were synthesized by standard and glucose-assisted sol–gel methods for use as cathodes in lithium-ion batteries. The effect of glucose on the characteristics of the formed LiCoPO4 nanoparticles was investigated by TGA, XRD, and FESEM. The TGA results indicated gradual decomposition of glucose in the temperature range 400–700 °C. The XRD results showed olivine phases in addition to small traces of Co3O4 for samples calcined at 400 °C while pure olivine phases were confirmed for the 700 °C calcined samples. The addition of glucose strongly suggests promotion of LiCoPO4 crystallization, as revealed by FESEM studies. The electrochemical measurements pertaining to LiCoPO4 samples calcined at 400 °C suggested an enhancement of initial discharge capacity from 103.3 to 144.6 mAh/g for the standard and glucose-based electrodes, respectively. Further, the effects of conductive additive and excess lithium on the electrochemical performance of LiCoPO4 have also been investigated.
Similar content being viewed by others
References
Bramnik NN, Bramnik KG, Buhrmester T, Baehtz C, Ehrenberg H, Fuess H (2004) J Solid State Electrochem 8:558–564
Wolfenstine J, Read J, Allen JL (2007) J Power Sources 163:1070–1073
Lloris JM, Pérez VC, Tirado JL (2002) Electrochem Solid-State Lett 5:A234–A237
Morgan D, Van der VA, Ceder G (2004) Electrochem Solid-State Lett 7:A30–A32
Zaghib K, Mauger A, Goodenough JB (2007) Chem Mater 19:3740–3747
Amine K, Yasuda H, Yamachib M (2000) Electrochem Solid-State Lett 3:178–179
Kim DH, Im JS, Kang JW, Kim EJ, Ahn HY, Kim J (2007) J Nanosci Nanotechnol 7:3949–3953
Kim TR, Kim DH, Ryu HW, Kim J (2007) J Phys Chem Solids 68:1203–1206
Yamada A, Hosoya M, Chung SC, Kudo Y, Hinokuma K, Liu KY, Nishi Y (2003) J Power Sources 119–121:232–238
Yang S, Zavalij PY, Whittingham MS (2001) Electrochem Commun 3:505–508
Prosini PP, Zanc D, Pasquali M (2001) Electrochim Acta 46:3517–3523
Chen Z, Dahn JR (2002) J Electrochem Soc 149:A1184–A1189
Jin B, Gu HB, Kim KW (2008) J Solid State Electrochem 12:105–111
Liu H, Li C, Cao Q, Wu YP, Holze R (2008) J Solid State Electrochem 12:1017–1020
Sheng YC, Bo G, Ling HS, Chang HM, Xiao GZ (2009) J Solid State Electrochem 13:1361–1366
Fey GTK, Lu TL (2008) J Power Sources 178:807–814
Guoxiu W, Hao L, Jian L, Shizhang Q, Gaoqing ML, Paul M, Hyojun A (2010) Adv Mater 22:4944–4948
Idalia B, Andreas H, Igor D, Petr N, Markus N (2009) J Mater Chem 19:5125–5128
Jin B, Jin EM, Park KH, Gu HB (2008) Electrochem Commun 10:1537–1540
Murugan AV, Muraliganth T, Manthiram A (2008) J Phys Chem C 112:14665–14671
Lai CY, Xu QJ, Ge HH, Zhou GD, Xie JY (2008) Solid State Ionics 179:1736–1739
Murugan AV, Muraliganth T, Ferreira PJ, Manthiram A (2009) Inorg Chem 48:946–952
Han DW, Kang YM, Yin RZ, Song MS, Kwon HS (2009) Electrochem Commun 11:137–140
Gwon H, Seo DH, Kim SW, Kim J, Kang K (2009) Adv Funct Mater 19:3285–3292
Drezen T, Kwon NH, Bowen P, Teerlinck I, Isono M, Exnar I (2007) J Power Sources 174:949–953
Zhihua L, Duanming Z, Fengxia Y (2009) J Mater Sci 44:2435–2443
Jang IC, Lim HH, Lee SB, Karthikeyan K, Aravindan V, Kang KS, Yoon WS, Cho WI, Lee YS (2010) J Alloys Compd 497:321–324
Wang F, Yang J, Li YN, Wang J (2010) J Power Sources 195:6884–6887
Shui JL, Yan Y, Chen CH (2006) Electrochem Commun 8:1087–1091
Acknowledgments
This work was supported by the Korea Research Foundation Grant funded by the Korean Government (MOEHRD; KRF-2007-412-J02003).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kim, E.J., Xu, H.Y., Lim, J.S. et al. Impact of glucose on the electrochemical performance of nano-LiCoPO4 cathode for Li-ion batteries. J Solid State Electrochem 16, 149–155 (2012). https://doi.org/10.1007/s10008-011-1291-1
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-011-1291-1