Skip to main content
SpringerLink
Log in

A novel PEO-based composite solid-state polymer electrolyte with methyl group-functionalized SBA-15 filler for rechargeable lithium batteries

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

Functionalized molecular sieve SBA-15 with trimethylchlorosilane was used as an inorganic filler in a poly(ethyleneoxide) (PEO) polymer matrix to synthesize a composite solid-state polymer electrolyte (CSPE) using LiClO4 as the doping salts, which is designated to be used for rechargeable lithium batteries. The methyl group-functionalized SBA-15 (fSBA-15) powder possesses more hydrophobic characters than SBA-15, which improves the miscibility between the fSBA-15 filler and the PEO matrix. The interaction between the fSBA-15 and PEO polymer matrix was investigated by scanning electron microscopy, X-ray diffraction, and differential scanning calorimetry. Linear sweep voltammetry and electrochemical impedance spectroscopy were employed to study the electrochemical stability windows, ionic conductivity, and interfacial stability of the CSPE. The temperature dependence of the change of the PEO polymer matrix in the CSPE from crystallization to amorphous phase was surveyed, for the first time, at different temperature by Fourier transform infrared emission spectroscopy. It has demonstrated that the addition of the fSBA-15 filler has improved significantly the electrochemical compatibility of the CSPE with a lithium metal electrode and enhanced effectively the ion conductivity of the CSPE.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Tarascon JM, Armand M (2001) Nature 414:359

    Article  CAS  Google Scholar 

  2. Fenton DE, Parker JM, Wright PV (1973) Polymer 14:589

    Article  CAS  Google Scholar 

  3. Wright PV (1975) Br Polym J 7:319

    Article  CAS  Google Scholar 

  4. Armand MB, Chabagno JM, Duclot JM (1979) In: Vashishta P, Shenoy JM, Shenoy GK (eds) Fast ion transport in solids. North Holland, New York, p 131

    Google Scholar 

  5. Gray FM (1991) Solid polymer electrolyte-fundamental and technological applications. VCH, New York

    Google Scholar 

  6. Croce F, Appetecchi GB, Persi L, Scrosati B (1998) Nature 394:456

    Article  CAS  Google Scholar 

  7. Croce F, Curini R, Martinello A, Persi L, Ronci F, Scrosati B, Caminiti R (1999) J Phys Chem 103:10632

    CAS  Google Scholar 

  8. Vaia RA, Vasudevan S, Krawiec W, Scanlon LG, Giannelis EP (1995) Adv Mater 7:154

    Article  CAS  Google Scholar 

  9. Sandi G, Carrado KA, Joachin H, Lu W, Prakash J (2003) J Power Sources 119:492

    Article  Google Scholar 

  10. Chen HW, Chiu CY, Wu HD, Shen IW, Chang FC (2002) Polymer 43:5011

    Article  CAS  Google Scholar 

  11. Krawiec W, Scanlon LGJ, Fellner JP, Vaia RA, Vasudevan S, Giannelis EP (1995) J Power Sources 54:310

    Article  CAS  Google Scholar 

  12. Xi JY, Miao SJ, Tang XZ (2004) Macromolecules 37:8592

    Article  CAS  Google Scholar 

  13. Xi JY, Ma XM, Cui MZ, Huang XB, Zheng Z, Tang XZ (2004) Chin Sci Bull 49:785

    Article  CAS  Google Scholar 

  14. Xi JY, Li J, Tang XZ (2004) Acta Chimi Sin 62:1755

    CAS  Google Scholar 

  15. Xi J, Qiu X, Ma X, Cui M, Yang J, Tang X, Zhu W, Chen L (2005) Solid State Ion 176:1249

    Article  CAS  Google Scholar 

  16. Kao HM, Tsai YY, Chao SW (2005) Solid State Ion 176:1261

    Article  CAS  Google Scholar 

  17. Wieczorek W, Zalewska A, Raducha D, Florjanczyk Z, Stevens JR (1998) Phys Chem B 102:352

    Article  CAS  Google Scholar 

  18. Choi B, Shin K (1996) Solid State Ion 86–88:303

    Article  Google Scholar 

  19. Capuano F, Croce F, Scrosati B (1991) J Electrochem Soc 139:1918

    Article  Google Scholar 

  20. Stevens JR, Wieczorek W (1996) Can J Chem 74:2106

    Article  CAS  Google Scholar 

  21. Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Science 279:548

    Article  CAS  Google Scholar 

  22. Jiang YX, Ding N, Sun SG (2004) J Electroanal Chem 563(1):15

    Article  CAS  Google Scholar 

  23. Yang CT, Huang MH (2005) J Phys Chem B 109:17842

    Article  CAS  Google Scholar 

  24. Appetecchi GB, Dautzenberg G, Scrosati B (1996) J Electrochem Soc 143:6

    Article  CAS  Google Scholar 

  25. Reddy MJ, Chu PP (2004) J Power Sources 135:1

    Article  CAS  Google Scholar 

  26. Nookala M, Kumar B, Rodrigues S (2002) J Power Sources 111:165

    Article  CAS  Google Scholar 

  27. Li X, Hsu SL (1984) J Polym Sci Polym Phys Ed 22:1331

    Article  CAS  Google Scholar 

  28. Bailey FE, Koleske JV Jr (1976) Poly (ethylene oxide). Academic, New York, p 115

    Google Scholar 

Download references

Acknowledgments

This work was supported by National Key Basic Research and Development Program (Grant no. 2002CB211804) and Natural Science Foundation of China (Grants no. 20433040 and 20573085).

Author information

Authors and Affiliations

  1. State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China

    Yan-Xia Jiang, Jin-Mei Xu, Quan-Chao Zhuang, Lan-Ying Jin & Shi-Gang Sun

Authors
  1. Yan-Xia Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jin-Mei Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Quan-Chao Zhuang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Lan-Ying Jin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Shi-Gang Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Yan-Xia Jiang or Shi-Gang Sun.

Additional information

Dedicated to Professor Oleg Petrii on the occasion of his 70th birthday on August 24th, 2007.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jiang, YX., Xu, JM., Zhuang, QC. et al. A novel PEO-based composite solid-state polymer electrolyte with methyl group-functionalized SBA-15 filler for rechargeable lithium batteries. J Solid State Electrochem 12, 353–361 (2008). https://doi.org/10.1007/s10008-007-0499-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-007-0499-6

Keywords

Search

Navigation