Skip to main content
SpringerLink
Log in

27Al NMR Study of the Structure and Dynamics of Natrolite

  • Published:
Applied Magnetic Resonance Aims and scope Submit manuscript

Abstract

The temperature dependences of nuclear magnetic resonance and magic angle spinning nuclear magnetic resonance spectra of 27Al nuclei in natrolite (Na2Al2Si3O10· 2H2O) have been studied. The influence of water molecules and sodium ions mobility on the shape of the 27Al NMR spectrum and framework dynamics have been discussed The temperature dependences of the spin–lattice relaxation times T1 of 27Al nuclei in natrolite have also been studied. It has been shown that the spin–lattice relaxation of the 27Al is governed by the electric quadrupole interaction with the crystal electric field gradients modulated by translational motion of H2O molecules in the natrolite pores. The dipolar interactions with paramagnetic impurities become significant as a relaxation mechanism of the 27Al nuclei only at low temperatures (<270 K).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. G. Engelhardt, D. Michel, High-Resolution Solid-State NMR of Silicates and Zeolites (Wiley, Chichester, 1987)

    Google Scholar 

  2. A. V. Sapiga, Thesis, Tavrida National University, Simferopol, 2003

  3. R.T. Thompson, R.R. Knispel, H.E. Petch, Can. J. Phys. 52, 2164 (1974)

    Google Scholar 

  4. A.V. Sapiga, N.A. Sergeev, Cryst. Res. Technol. 36, 8 (2001)

    Article  Google Scholar 

  5. M. Olszewski, N. A. Sergeev, A. V. Sapiga, Z. Naturforsch. 59a, 501–504 (2004)

  6. H.E. Petch, K.S. Pennington, J. Chem. Phys. 36, 1261 (1962)

    Article  Google Scholar 

  7. V. N. Szczerbakov, Thesis, Institute of Physics, Krasnojarsk, USSR, (1972)

  8. D. Freude, in Encyclopaedia of Analytical Chemistry, R.A. Meyers (ed.), p. 12188–12224 (2000)

  9. D. Massiot, F. Fayon, M. Capron, I. King, S. Le Calve, B. Alonso, J.-O. Durand, B. Bujoli, Z. Gan, G. Hoatson, Magn. Reson. Chem. 40, 70 (2002)

    Article  Google Scholar 

  10. F. Pechar, W. Schafer, G. Will, Z. Kristallog. 164, 19 (1983)

    Article  Google Scholar 

  11. J. Haase, H. Pfeifer, W. Oehme, J. Klinowski, Chem. Phys. Letters 150, 189 (1988)

    Article  ADS  Google Scholar 

  12. P.S. Hubbard, J. Chem. Phys. 53, 985 (1970)

    Article  ADS  Google Scholar 

  13. A. Abragam, The Principles of Nuclear Magnetism (Oxford U.P, London, 1961)

    Google Scholar 

  14. J. Haase, K.D. Park, K. Guo, H.K.C. Timken, E. Oldfield, J. Phys. Chem. 95, 6996 (1991)

    Article  Google Scholar 

  15. E.R. Andrew, D.P. Tunstall, Proc. Phys. Soc. London 78, 1 (1961)

    Article  ADS  Google Scholar 

  16. J. Seliger, R. Blinc, J. Phys.: Condens. Matter 5, 9401 (1993)

    ADS  Google Scholar 

  17. E. Fukushima, S.B.W. Roeder, Experimental Pulse NMR: A Nuts and Bolts Approach (Addison-Wesley, London, 1981)

    Google Scholar 

  18. T.T. Phua, B.J. Beadry, D.T. Peterson, D.R. Torgeson, R.G. Barnes, M. Belhoul, G.A. Styles, E.F.W. Seymour, Phys. Rev. B 28, 6227 (1983)

    Article  ADS  Google Scholar 

  19. A.L. Pigg, S.M. Day, Phys. Rev. B 11, 3219 (1975)

    Article  ADS  Google Scholar 

  20. A.M. Panich, N.A. Sergeev, Phys. B 405, 2034 (2010)

    Article  ADS  Google Scholar 

  21. A.M. Panich, A.I. Shames, N.A. Sergeev, Appl. Magn. Reson. 44, 107 (2013)

    Article  Google Scholar 

  22. N. Noginova, E. Arthur, T. Weaver, G.B. Loutts, V.A. Atsarkin, D.G. Gotovsev, Phys. Rev. B 69, 024406 (2004)

    Article  ADS  Google Scholar 

  23. V.M. Vinokurov, J.M. Gaite, G.R. Bulka, N.M. Khasanova, N.M. Nizamutdinov, A.A. Galeev, C. Rudowicz, J. Magn. Reson. 155, 57–63 (2002)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physics, University of Szczecin, 70-451, Szczecin, Poland

    M. Paczwa, M. Olszewski & N. A. Sergeev

  2. Faculty of Physics, Taurida National V.I.Vernadsky University, Simferopol, Crimea

    A. A. Sapiga & A. V. Sapiga

Authors
  1. M. Paczwa
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Sapiga
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Olszewski
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. A. Sergeev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Sapiga
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. A. Sergeev.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Paczwa, M., Sapiga, A.A., Olszewski, M. et al. 27Al NMR Study of the Structure and Dynamics of Natrolite. Appl Magn Reson 46, 583–592 (2015). https://doi.org/10.1007/s00723-015-0648-5

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00723-015-0648-5

Keywords

Search

Navigation