Abstract
Various electrode materials commonly used in electroanalysis were tested in preparation of respective bismuth film electrodes and compared in simultaneous electrochemical detection of heavy metals, simulating dissolved quantum dots used as labels of antibodies in quantum dot-linked immunosorbent assays. According to results obtained during voltammetric measurements, it can be concluded that selected commercial screen-printed electrodes showed many significant drawbacks which are described in detail. Contrary to the gold disk electrode, conventional glassy carbon electrode coated with thin bismuth film was applicable up to −1.5 V without the need to use very high content of bismuth in supporting electrolyte. Moreover, significant interactions among present metals were observed during their electrochemical stripping analysis, especially in presence of copper and silver.
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References
Alivisatos AP (1996) Science 271:933
Ekimov AI, Onushchenko AA (1981) JETP Lett 34:345
Tang R, Xue J, Xu B, Shen D, Sudlow GP, Achilefu S (2015) ACS Nano 9:220
Narayanaswamy A, Feiner LF, Zaag PJ (2008) J Phys Chem C 112:6775
Li XM, Shen HB, Li S, Niu JZ (2010) J Mater Chem 20:923
Vasudevan D, Gaddam RR, Trinchi A, Cole I (2015) J Alloys Compd 636:395
Moina C, Ybarra G (2012) Fundamentals and Applications of Immunosensors. In: Chiu NHL, Christopoulos TK (eds) Advances in immunoassay technology. InTech, Shanghai, p 65
Čadková M, Metelka R, Holubová L, Horák D, Dvořáková V, Bílková Z, Korecká L (2015) Anal Biochem 484:4
Hnatowich DJ, Layne WW, Childs RL, Lanteigne D, Davis MA, Griffin TW, Doherty PW (1983) Science 220:613
Sun B, Xie W, Yi G, Chen D, Zhou Y, Cheng J (2001) J Immunol Methods 249:85
Čadková M, Dvořáková V, Metelka R, Bílková Z, Korecká L (2016) Monatsh Chem 147:69
Švancara I, Prior Ch, Hočevar SB, Wang J (2010) Electroanalysis 22:1405
Jacob F, Meier M, Caduff R, Goldstein D, Pochechueva T, Hacker N, Fink D, Heinzelmann-Schwarz V (2011) Gynecol Oncol 121:487
Anandhakumar S, Mathiyarasu J, Phani KLN (2013) Analyst 138:5674
Charalambous A, Economou A (2005) Anal Chim Acta 547:53
Wang J, Lu J, Hočevar SB, Farias PAM (2000) Anal Chem 72:3218
Sochr J, Machková M, Machyňák L, Čacho F, Švorc L (2016) Acta Chim Slovaca 9:28
Copeland TR, Osteryoung RA, Skogerboe RK (1974) Anal Chem 46:2093
Yang D, Wang L, Chen Z, Megharaj M, Naidu R (2013) Electroanalysis 25:2637
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The supports received from the Czech Science Foundation (Project No. 15-16549S) and the Faculty of Chemical Technology, University of Pardubice (Project No. SGS-2016-001) are gratefully acknowledged.
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Sýs, M., Metelka, R., Korecká, L. et al. Comparison of various bismuth film electrodes in simultaneous electrochemical detection of heavy metals for application in quantum dot-linked immunoassays. Monatsh Chem 148, 505–510 (2017). https://doi.org/10.1007/s00706-016-1901-9
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DOI: https://doi.org/10.1007/s00706-016-1901-9