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Hydrogen, trace, and ultra-trace element distribution in natural olivines

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Abstract

We investigate the coupling between H, minor, trace, and ultra-trace element incorporations in 17 olivines from ten different locations covering various petrological origins: magmatic, hydrothermal, and mantle-derived context. Concentrations in major element are determined by micro X-ray fluorescence. Minor, trace, and ultra-trace elements are determined by laser ablation inductively coupled plasma mass spectrometry. Hydrogen concentrations are quantified using unpolarized and polarized Fourier transform infrared spectroscopy (FTIR). Forsterite contents (83.2–94.1%) reflect the petrogenetic diversity. Hydrogen concentrations range from 0 to 54 ppm H2O wt. Minor element concentrations (Ni + Mn) range from 3072 to 4333 ppm, and impurities are dominated by Ni, Mn, Ca or B. Total trace element concentrations range from 8.2 to 1473 ppm. Total rare Earth and extended ultra-trace elements concentrations are very low (< 0.5 ppm). Magmatic and hydrothermal olivines show the most and least amount of impurities, respectively, and mantle-derived olivines have concentrations between these two extremes. Combined with minor, trace, and ultra-trace element concentrations, the hydrogen concentrations, and FTIR OH bands reflect the point defect diversity imposed by different geological settings. Hydrogen concentrations are inversely correlated with divalent impurities, indicating their competition for vacancies. However, a broad positive correlation is also found between OH bands at 3575 and 3525 cm−1 and Ti, confirming the existence of Ti-clinohumite-like point defect in mantle olivines. Nonetheless, Ti does not exclusively control hydrogen incorporation in olivine due to the co-existence with other mechanisms, and its effect appears diluted. Our results confirm that hydrogen behaves as a peculiar incompatible element, and furthermore as an opportunistic impurity in olivine.

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Acknowledgements

CNRS supported this study through INSU Tellus program 2019 awarded to S. Demouchy and a Future Fellowship (FT150100115) from Australian Research Council awarded to O. Alard. The authors thank Dr. D. Mainprice and Dr. A. Ishikawa for the re-use of selected olivine crystals. S.D. thanks J.-A. Padròn-Navarta and C. Thoraval for constructive discussions, Dr. T.D. Murphy and Dr. Y. Gréau at Macquarie University for their help and precious time on the Bruker M4 Tornado and L. Gorojovsky who improved the spelling and grammar of this manuscript. Dr. D. Maurin and he IR-Raman technological Platform of University of Montpellier are acknowledged for vibrational spectroscopy experiments. This is contribution 1567 from the ARC Centre of Excellence for Core to Crust Fluid Systems (http://www.ccfs.mq.edu.au) and 1430 in the GEMOC Key Centre (http://www.gemoc.mq.edu.au).

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  1. Géosciences Montpellier, Université de Montpellier and CNRS, 34095, Montpellier, France

    Sylvie Demouchy & Olivier Alard

  2. Department of Earth and Planetary Science, Macquarie University, Sydney, NSW, 2109, Australia

    Olivier Alard

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Demouchy, S., Alard, O. Hydrogen, trace, and ultra-trace element distribution in natural olivines. Contrib Mineral Petrol 176, 26 (2021). https://doi.org/10.1007/s00410-021-01778-5

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