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Physico-chemical parameters and interaction forces associated with the clouding phenomenon of triton X-100 and ceftriaxone sodium mixture: an understanding of the impacts of potassium salts

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Abstract

Surfactants have the application in drug formulation purposes as common excipients. The use of surfactant in the incidence of additives improves the absorption and drug release phenomenon. Herein, the development of the clouding of non-ionic surfactants (NISs), triton X-100 (TX-100), and ceftriaxone sodium (CTS) drug mixture, in the appearance of potassium salts (KCl, K3PO4, KBrO3, K2SO4, and KI), has been studied by the way of cloud point (CP) measurement method. The CPs of the study system suffered a lessening as the quantities of KCl, K3PO4, KBrO3, and K2SO4 increased while the opposite result was observed for KI salt. Aggregation within the associated solution systems may lead to a decline in the corresponding CP. The standard free energy (\({\Delta G}_{\mathrm{c}}^{0}\)) values reveal the non-spontaneous cloudy formation of TX-100 + CTS mixture, and non-spontaneity go through a drop with the growing electrolyte concentration. The standard enthalpy (\({\Delta H}_{\mathrm{c}}^{0}\)) and standard entropy (\({\Delta S}_{\mathrm{c}}^{0}\)) values for phase partitioning of TX-100 + CTS reveal the exothermic interaction in the presence of KCl, K3PO4, KBrO3, and K2SO4 while mainly hydrophobic in the presence of KI salt. The intrinsic enthalpy (\({\Delta H}_{c}^{0,*}\)) values reveal that TX-100 + CTS mixture experiences the highest stability in K3PO4 salt media.

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The datasets generated during the study are available from the corresponding author on reasonable request.

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Acknowledgements

The authors would like to extend their gratitude to King Saud University, Riyadh, Saudi Arabia for funding this research through Researchers supporting Project number (RSP-2023-R406).

Funding

This study was funded by Researchers Supporting Project number (RSP-2023-R406), King Saud University, Riyadh, Saudi Arabia.

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Authors and Affiliations

  1. Department of Chemistry, Jahangirnagar University, Savar, Dhaka, 1342, Bangladesh

    Md. Nazrul Islam, Shahed Rana, Md. Anamul Hoque & Shariff E. Kabir

  2. Department of Biochemistry, College of Science, King Saud University, Riyadh, Kingdom of Saudi Arabia

    Mohamed H. Mahmoud

  3. Nuclear Safety, Security & Safeguards Division, Bangladesh Atomic Energy Regulatory Authority, Agargaon, Dhaka, 1207, Bangladesh

    Shamim Mahbub

  4. Department of Chemistry, Dhaka University of Engineering & Technology, Gazipur, 1707, Bangladesh

    Md. Rafikul Islam

  5. Laboratory for Chemical Computation and Modeling, Institute for Computational Science and Artificial Intelligence, Van Lang University, Ho Chi Minh City, Vietnam

    Dileep Kumar

  6. Faculty of Applied Technology, School of Technology, Van Lang University, Ho Chi Minh City, Vietnam

    Dileep Kumar

  7. Graduate Program in System Health Science and Engineering, Ewha Womans University, Seoul, 07984, Republic of Korea

    AbuZar Ansari

  8. Department of Chemistry, Jagannath University, Dhaka-1100, Bangladesh

    Shariff E. Kabir

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Contributions

M.N.I., M.H.M. and S.M. did the experiments. M.R.I., S.R. and A.A. interpreted the results. D.K., M.A.H. and S.E.K. supervised the work and wrote the manuscript. All authors reviewed the manuscript.

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Correspondence to Dileep Kumar.

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Islam, M.N., Mahmoud, M.H., Mahbub, S. et al. Physico-chemical parameters and interaction forces associated with the clouding phenomenon of triton X-100 and ceftriaxone sodium mixture: an understanding of the impacts of potassium salts. Colloid Polym Sci 302, 213–224 (2024). https://doi.org/10.1007/s00396-023-05188-w

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