Abstract
The phase behavior of the mixed catanionic surfactants in aqueous solution, composed of the long-chain ionic liquid (IL) N-dodecyl-N-methylpyrrolidinium (C12MPB) and a divalent metal surfactant copper dodecyl sulfate (Cu(DS)2·4H2O), was investigated. The phase diagram of the catanionic system was mapped through visual observation and electrical conductivity measurement. The formation of vesicles was confirmed in the lamellar phase (Lα) through transmission electron microscopy (TEM). Rheological measurements were used to study the macroscopic properties of the birefringent Lα phase. Electrostatic and hydrophobic interactions are regarded as the main driving forces for the formation of vesicles. Furthermore, the vesicles were successfully used as the templates to prepare the leaflike CuO nanomaterials.
Similar content being viewed by others
References
Kaler EW, Murthy AK, Rodriguez BE, Zasadzinski JAN (1989) Science 245:1371–1374
Chevalier Y, Zemb T (1990) Rep Prog Phys 53:279–371
Guo X, Szoka FC (2003) Acc Chem Res 36:335–341
Antonietti M, Forster S (2003) Adv Mater 15:1323–1333
Sun CQ, Sano Y, Kashiwagi H, Ueno M (2002) Colloid Polym Sci 280:900–907
Medronho B, Fujii S, Richtering W, Miguel MG, Olsson U (2005) Colloid Polym Sci 284:317–321
Huang JB, Zhu BY, Mao M, He P, Wang J, He X (1999) Colloid Polym Sci 277:354–360
Sun WJ, Shen YW, Hao JC (2011) Langmuir 27:1675–1682
Aratono M, Onimaru N, Yoshikai Y, Shigehisa M, Koga I, Wongwailikhit K, Ohta A, Takiue T, Lhoussaine B, Strey R, Takata Y, Villeneuve M, Matsubara H (2007) J Phys Chem B 111:107–115
Svard M, Schurtenberger P, Fontell K, Jonsson B, Lindman B (1988) J Phys Chem 92:2261–2270
Kunieda H, Nakamura K, Olsson U, Lindman B (1993) J Phys Chem 97:9525–9531
Marques EF, Regev O, Khan A, Miguel MG, Lindman B (1998) J Phys Chem B 102:6746–6758
Bergström M, Pedersen JS, Schurtenberger P, Egelhaaf SU (1999) J Phys Chem B 103:9888–9897
Sohrabi B, Gharibi H, Tajik B, Javadian S, Hashemianzadeh MJ (2008) J Phys Chem B 112:14869–14876
Dong RH, Weng RY, Dou Y, Zhang L, Hao JC (2010) J Phys Chem B 114:2131–2139
Kennedy MT, Korgel BA, Monbouquette HG, Zasadzinski JA (1998) Chem Mater 10:2116–2119
Djojoputro H, Zhou XF, Qiao SZ, Wang LZ, Yu CZ, Lu GQ (2006) J Am Chem Soc 128:6320–6321
Li RX (2004) Green solvent: synthesis and application of ionic liquids. Chemistry Technology, Beijing
Mcewen AB, Ngo HL, Lecompte K, Goldman JL (1999) J Electrochem Soc 146:1687–1695
Welton T (1999) Chem Rev 99:2071–2084
Blanchard LA, Hancu A, Bechman EJ, Brennecke JF (1999) Nature 399:28–29
Anthony JL, Maginn EJ, Brennecke JF (2002) J Phys Chem B 106:7315–7320
Hao JC, Song AX, Wang JZ, Chen X, Zhuang WC, Shi F, Zhou F, Liu WM (2005) Chem Eur J 11:3936–3940
Singh K, Marangoni DG, Quinn JG, Singer RD (2009) J Colloid Interface Sci 335:105–111
Baker GA, Pandey S, Pandey S, Baker SN (2004) Analyst 129:890–892
Karukstis KK, McDonough JR (2005) Langmuir 21:5716–5721
Kunze M, Jeong S, Paillard E, Winter M, Passerini S (2010) J Phys Chem C 114:12364–12369
Zhao MW, Zheng LQ (2011) Phys Chem Chem Phys 13:1332–1337
Law G, Watson PR (2001) Langmuir 17:6138–6141
Dong B, Li N, Zheng LQ, Yu L, Inoue T (2007) Langmuir 23:4178–4182
Dattelbaum AM, Baker SN, Baker GA (2005) Chem Commun 7:939–941
Teng MM, Song AX, Liu LP, Hao JC (2008) J Phys Chem B 112:1671–1675
Teng MM, Song AX, Hao JC (2009) J Colloid Interface Sci 338:537–541
Goossens K, Lava K, Nockemann P, Hecke KV, Meervelt LV, Driesen K, Görller-Walrand C, Binnemans K, Cardinaels T (2009) Chem Eur J 15:656–674
Moroi Y, Motomura K, Matuura R (1974) J Colloid Interface Sci 46:111–117
Miyamoto S (1960) Bull Chem Soc Jpn 33:371–375
Miyamoto S (1960) Bull Chem Soc Jpn 33:375–379
Li X, Dong SL, Jia XF, Song AX, Hao JC (2007) Chem Eur J 13:9495–9502
Yuan J, Bai XT, Zhao MW, Zheng LQ (2010) Langmuir 26:11726–11731
Hyun YH, Lim ST, Choi HJ, Jhon MS (2001) Macromolecules 34:8084–8093
Wang JZ, Song AX, Jia XF, Hao JC, Liu WM, Hoffmann H (2005) J Phys Chem B 109:11126–11134
Song AX, Jia XF, Teng MM, Hao JC (2007) Chem Eur J 13:496–501
Song AX, Hao JC (2009) Curr Opin Colloid Interface Sci 14:94–102
Zhong Z, Ng V, Luo J, Teh SP, Teo J, Gedanken A (2007) Langmuir 23:5971–5977
Kratohvil S, Matijevic EJ (1991) J Mater Res 6:766–777
Fujita W, Awaga K (1996) Inorg Chem 35:1915–1917
Fujita W, Awaga K, Yokoyama T (1997) Inorg Chem 36:196–199
Wang HH, Shen Q, Li XP, Liu FL (2009) Langmuir 25:3152–3158
Lin S, Li M, Dujardin E, Girard C, Mann S (2005) Adv Mater 17:2553–2559
Liu B, Zeng HC (2005) J Am Chem Soc 127:18262–18268
Cho KS, Talapin DV, Gaschler WG, Murray CB (2005) J Am Chem Soc 126:7140–7147
Liu JP, Huang XT, Li YY, Sulieman KM, He X, Sun FL (2006) Cryst Growth Des 6:1690–1696
Acknowledgments
The authors are grateful for funding from the National Natural Science Foundation of China (No. 50972080) and the National Basic Research Program (2009CB930101).
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
ESM 1
(DOC 252 kb)
Rights and permissions
About this article
Cite this article
Zhao, M., Yuan, J. & Zheng, L. The formation of vesicles by N-dodecyl-N-methylpyrrolidinium bromide ionic liquid/copper dodecyl sulfate and application in the synthesis of leaflike CuO nanosheets. Colloid Polym Sci 290, 1361–1369 (2012). https://doi.org/10.1007/s00396-012-2664-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-012-2664-4