Abstract
Adhesion properties of physically crosslinked hydrogels consisting of partially hydrated poly(sodium acrylate) (PSA) and poly(acrylic acid) (PAA) were investigated. The adhesion force and separation energy between the gels in swollen states were measured using a simple tack-evaluation technique by a point contact. As a result, the adhesion properties were significantly affected by the PSA/PAA ratio, which resulted from the fact that the physical and chemical properties of gels were changed through the replacement of PSA by PAA at gelation. The measurements of attenuated total reflectance Fourier transform infrared spectroscopy and the dynamic shear viscoelasticity suggested that the number of nonionized carboxyl groups increased and the stiffness increased with increasing the PAA ratio, respectively. In order to understand the adhesion properties further, the apparent contact area was evaluated by a stamp experiment using vermilion ink. The relationships between the adhesion properties and the physical and chemical features of gels are discussed in terms of the surface molecular interaction, the elastic and viscous properties of the bulk, and the apparent and true contact areas of the present system. From these results, the factors that determine the adhesion curve and the uniqueness and advantages of the present evaluation method are clarified.
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References
Gent AN, Kinloch AJ (1971) J Polym Sci 9:659
Gent AN (1982) Rubber Chem Technol 55:525
PSTC (2007) PSTC-6 tack rolling ball, adhesion test methods, test methods for pressure sensitive adhesive tapes, 15th edn. PSTC, Chicago
ASTM International (2008) ASTM D3121-06, standard test method for tack of pressure-sensitive adhesives by rolling ball. ASTM International, West Conshohocken
Barquins M, Maugis D (1981) J Adhes 13:53
Creton C, Leibler L (1996) J Polym Sci 34:545
Hertz H (1882) J Reine Angew Math 92:156
Johnson KL, Kendall K, Robert AD (1971) Proc R Soc London Ser A 324:301
Shull KR (2002) Mater Sci Eng R 36:1
Sato T, Goto M, Nakano K, Suzuki A (2005) Jpn J Appl Phys 44:8168
Bowden FP, Tabor D (1964) The friction and lubrication of solids, part 2. Oxford University Press, Oxford, p 413
Suzuki A, Sato T, Sakasegawa D, Sawada H, Goto M (2007) J Appl Polym Sci 105:3728
Sato H, Hirashima Y, Suzuki A, Goto M, Tokita M (2005) J Polym Sci Part B 43:753
Harada T, Hirashima Y, Suzuki A, Goto M, Kawamura N, Tokita M (2005) Eur Polym J 41:2189
Sato H, Hirashima Y, Suzuki A (2007) J Appl Polym Sci 105:3809
Hirashima Y, Sato H, Suzuki A (2005) Macromolecules 38:9280
Dong J, Ozaki Y, Nakashima K (1997) Macromolecules 30:1111
Nishinari K (2000) Rep Prog Polym Phys Jpn 43:163
Zozel A (1986) Adhesion 3:14
Tamagawa H, Nogata F, Umemoto S, Okui N, Popovic S, Taya M (2002) Bull Chem Soc Jpn 75:383
Bikermann JJ (1957) J Appl Phys 28:1484
Suzuki A, Yamazaki M, Kobiki Y, Suzuki H (1997) Macromolecules 30:2350
Archard JF (1957) Proc R Soc (Lond) A243:190
Sakasegawa D, Goto M, Suzuki A (2009) Prog Colloid Polym Sci 136: (in press)
Sakasegawa D, Suzuki A (2009) J Polym Sci B 47:1778
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Sakasegawa, D., Goto, M. & Suzuki, A. Adhesion properties of physically crosslinked elastic gels of poly(sodium acrylate)–poly(acrylic acid) mixtures evaluated by a point contact method. Colloid Polym Sci 287, 1281–1293 (2009). https://doi.org/10.1007/s00396-009-2090-4
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DOI: https://doi.org/10.1007/s00396-009-2090-4