Abstract
To assess the compatibility of blends of synthetic poly(propylene carbonate) (PPC), with a natural bacterial poly(3-hydroxybutyrate) (PHB), a simple casting procedure of blend was used. poly(3-hydroxybutyrate)/poly(propylene carbonate) blends are found to be incompatible according to DSC and DMA analysis. In order to improve the compatibility and mechanical properties of PHB/PPC blends, poly(vinyl acetate) (PVAc) was added as a compatibilizer. The effects of PVAc on the thermal behavior, morphology, and mechanical properties of 70PHB/30PPC blend were investigated. The results show that the melting point and the crystallization temperature of PHB in blends decrease with the increase of PVAc content in blends, the loss factor changes from two separate peaks of 70PHB/30PPC blend to one peak of 70PHB/30PPC/12PVAc blend. It is also found that adding PVAc into 70PHB/30PPC blend can decrease the size of dispersed phase from morphology analysis. The result of tensile properties shows that PVAc can increase the tensile strength and Young’s modulus of 70PHB/30PPC blend, and both the elongation at break and the tensile toughness increase significantly with PVAc added into 70PHB/30PPC.
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References
Doi Y (1990) Microbial polyesters.VCH, New York
Grassie N, Murray EJ, Holmes PA (1984) Polym Degrad Stabil 6:47
Grassie N, Murray EJ, Holmes PA (1984) Polym Degrad Stabil 6:95
Grassie N, Murray EJ, Holmes PA (1984) Polym Degrad Stabil 6:127
De koning GJM, Lemstra PJ (1993) Polymer 34:4089
Matsusaki H, Abe H, Doi Y (2000) Biomacromolecules 1:17
Doi Y, Kunnioka M, Nakamura Y, Soga K (1987) Macromolecules 20:2988
Hiramitsu M, Doi Y (1993) Polymer 34:4782
Shimamura E, Scandola M, Doi Y (1994) Macromolecules 27:4429
Cao A, Kasuya K, Abe H, Doi Y, Inoue Y (1998) Polymer 39:4801
Saito Y, Nakamura S, Hiramitsu M, Doi Y (1996) Polym Int 39:169
Nakamura K, Yoshie N, Sakurai M, Inoue Y (1994) Polymer 35:193
Spyros A, Ashby RD, Gross RA (1995) Macromolecules 28:6108
Avella M, Martuseelli E (1988) Polymer 29:1781
Avella M, Martuseelli E, Greco P (1991) Polymer 32:1647
Shafee EE (2001) Eur Polym J 37:451
An YX, Dong LS, Li L et al (1999) Eur Polym J 35:365
An YX, Li L, Dong LS et al (1999) J Polym Sci Part B Polym Phys 37:443
Iriondo P, Iruin JJ, Fernandez-Berridi MJ (1995) Polymer 36:3225
Xing PX, Dong LS, An YX et al (1997) Macromolecules 30:2726
Paglia ED, Beltrame PL, Canetti M et al (1993) Polymer 34:996
Sadocco P, Canet M, Seves A, Martucelli E (1993) Polymer 34:3368
Marand H, and Collins M (1990) Acs Polym Prep 31:552
Chiu HJ, Chen HL, Lin JS (2001) Polymer 42:5749
An YX, Dong LS, Li G et al (2000) J Polym Sci Part B Polym Phys 38:1860
Xing PX, An YX, Dong LS et al (1998) Macromolecules 31:6898
Kumagai Y, Doi Y (1992) Polym Degrad Stabil 36:241
Blumn E, Owen AJ (1995) Polymer 36:4077
Avella M, Martuscelli E, Orsello G et al (1997) Polymer 38:6135
Greco P, Martuscelli E (1989) Polymer 30:1475
Abate M, Martuscelli E, Ragosto G et al (1991) J Mater Sci 26:1119
Inoue S, Koinuma H, Tsuruta TJ (1969) Polym Sci Polym Lett Ed 7:287
Zhou M, Takayanagi M, Yoshida Y, Ishii S, Noguchi H (1999) Polym Bull 42:419
Udipi K, Gillham JK (1974) J Polym Sci 18:1575
Huang Y, Wang J, Liao B, Chen L, Cong GJ (1997) Appl Polym Sci 64:2457
Peng SW, An YX, Chen C et al (2003) Polym Degrad Stabil 80:141
Olibisi O, Roberson LM, Shaw MT (1979) Polymer—polymer miscibility. Academic, San Diego
Yoon JS, Lee WS, Kim KS et al (2000) Eur Polym J 36:435
Abe H, Doi Y, Kumagai Y (1994) Macromolecules 27:6012
Hlavata D, Horak Z, Lednicky F et al (2001) J Polym Sci Part B Polym Phys 39:931
Batham PJ, Keller A, Otun EL, Holmes PA (1984) J Mater Sci 19:2781
Legros A, Carreau PJ, Favis BD, Michel A (1984) Polymer 35:758
Oshinski AJ, Keskkula H, Paul DR (1992) Polymer 33:284
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Wang, X., Peng, S. & Dong, L. Effect of poly(vinyl acetate) (PVAc) on thermal behavior and mechanical properties of poly(3-hydroxybutyrate)/poly(propylene carbonate) (PHB/PPC) blends. Colloid Polym Sci 284, 167–174 (2005). https://doi.org/10.1007/s00396-005-1353-y
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DOI: https://doi.org/10.1007/s00396-005-1353-y