Abstract
Three-dimensional (3D) printed graphene pyramids were fabricated through a dual-extrusion FDM-type 3D printer using a commercially available PLA-based conductive graphene. Compared with flat printed graphene, a substantial enhancement in the electrochemical performance was clearly observed for the case of 3D printed graphene pyramids with 5.0 mm height. Additionally, the charge transfer of Li+ across the graphene pyramids/electrolyte interface was easier enhancing its performance presenting a specific discharge capacity of 265 mAh g−1 with retention of 93% after 1000 cycles. The importance of thickness control towards the printing of an electrode with good stability and effective electrochemical behavior is highlighted.
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Acknowledgements
This work was supported by the European Research Council under ERC Advanced Grant No. 320081 (PHOTOMETA), while financial support by the EU-FET Graphene Flagship (Grant Agreement No: 604391) is also acknowledged.
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Vernardou, D., Vasilopoulos, K.C. & Kenanakis, G. 3D printed graphene-based electrodes with high electrochemical performance. Appl. Phys. A 123, 623 (2017). https://doi.org/10.1007/s00339-017-1238-1
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DOI: https://doi.org/10.1007/s00339-017-1238-1