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3D printed graphene-based electrodes with high electrochemical performance

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Abstract

Three-dimensional (3D) printed graphene pyramids were fabricated through a dual-extrusion FDM-type 3D printer using a commercially available PLA-based conductive graphene. Compared with flat printed graphene, a substantial enhancement in the electrochemical performance was clearly observed for the case of 3D printed graphene pyramids with 5.0 mm height. Additionally, the charge transfer of Li+ across the graphene pyramids/electrolyte interface was easier enhancing its performance presenting a specific discharge capacity of 265 mAh g−1 with retention of 93% after 1000 cycles. The importance of thickness control towards the printing of an electrode with good stability and effective electrochemical behavior is highlighted.

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References

  1. K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, A.A. Firsov, Science 306, 666–669 (2004)

    Article  ADS  Google Scholar 

  2. D.W. Zhang, X.D. Li, H.B. Li, S. Chen, Z. Sun, X.J. Yin, S.M. Huang, Carbon 49, 5382–5388 (2011)

    Article  Google Scholar 

  3. M. Pumera, Chem. Rec. 9, 211–223 (2009)

    Article  Google Scholar 

  4. X. Wang, X. Lu, B. Liu, D. Chen, Y. Tong, G. Shen, Adv. Mater. 26, 4763–4782 (2014)

    Article  Google Scholar 

  5. X.H. Wang, C. Guan, L.M. Sun, R.A. Susantyoko, H.J. Fan, Q. Zhang, J. Mater. Chem. A 3, 15394–15398 (2015)

    Article  Google Scholar 

  6. X. Wang, L. Sun, R.A. Susantyoko, Q. Zhang, Carbon 98, 504–509 (2016)

    Article  Google Scholar 

  7. S. Pang, H.N. Tsao, X. Feng, K. Müllen, Adv. Mater. 21, 3488–3491 (2009)

    Article  Google Scholar 

  8. M. Xue, F. Li, J. Zhu, H. Song, M. Zhang, T. Cao, Adv. Funct. Mater. 22, 1284–1290 (2012)

    Article  Google Scholar 

  9. R.J. Stohr, R. Kolesov, K. Xia, J. Wrachtrup, ACS Nano 5, 5141–5150 (2011)

    Article  Google Scholar 

  10. J.H. Kim, W.S. Chang, D. Kim, J.R. Yang, J.T. Han, G.-W. Lee, J.T. Kim, S.K. Seol, Adv. Mater. 27, 157–161 (2015)

    Article  Google Scholar 

  11. J. Czyżewski, P. Burzyński, K. Gaweł, J. Meisner, J. Mater. Process. Technol. 209, 5281–5285 (2009)

    Article  Google Scholar 

  12. X. Wei, D. Li, W. Jiang, Z. Gu, X. Wang, Z. Zhang, Z. Sun, Sci. Rep. 5, 11181–11187 (2015)

    Article  ADS  Google Scholar 

  13. C. Zhu, T.Y.-J. Han, E.B. Duoss, A.M. Golobic, J.D. Kuntz, C.M. Spadaccini, M.A. Worsley, Nat. Commun. 6, 6962–6968 (2015)

    Article  Google Scholar 

  14. M.E. Snowden, P.H. King, J.A. Covington, J.V. Macpherson, P.R. Unwin, Anal. Chem. 82, 3124–3131 (2010)

    Article  Google Scholar 

  15. Y. Hu, X. Sun, J. Mater. Chem. A 2, 10712–10738 (2014)

    Article  Google Scholar 

  16. D. Wei, P. Andrew, H. Yang, Y. Jiang, F. Li, C. Shan, W. Ruan, D. Han, L. Niu, C. Bower, T. Ryhänen, M. Rouvala, G.A.J. Amaratunga, A. Ivaska, J. Mater. Chem. 21, 9762–9767 (2011)

    Article  Google Scholar 

  17. D. Louloudakis, D. Vernardou, E. Spanakis, N. Katsarakis, E. Koudoumas, Surf. Coat. Tech. 230, 186–189 (2013)

    Article  Google Scholar 

  18. D. Vernardou, A. Sapountzis, E. Spanakis, G. Kenanakis, E. Koudoumas, N. Katsarakis, J. Electrochem. Soc. 160, D6–D9 (2013)

    Article  Google Scholar 

  19. D. Vernardou, D. Louloudakis, E. Spanakis, N. Katsarakis, E. Koudoumas, New J. Chem. 38, 1959–1964 (2014)

    Article  Google Scholar 

  20. E.M. de Teixeira, A. de Campos, J.M. Marconcini, T.J. Bondancia, D. Wood, A. Klamczynski, L.H.C. Mattoso, G.M. Glenn, RSC Adv. 4, 6616–6623 (2014)

    Article  Google Scholar 

  21. R. Zhang, Y. Liu, L. Yu, Z. Li, S. Sun, Nanotechnology 24, 225601–225608 (2013)

    Article  ADS  Google Scholar 

  22. J.Y. Howe, C.J. Rawn, L.E. Jones, H. Ow, Powder Differ. 18, 150–154 (2003)

    Article  ADS  Google Scholar 

  23. A.C. Ferrari, Solid State Commun. 143, 47–57 (2007)

    Article  ADS  Google Scholar 

  24. A.C. Ferrari, J.C. Meyer, V. Scardaci, C. Casiraghi, M. Lazzeri, F. Mauri, S. Piscanec, D. Jiang, K.S. Novoselov, S. Roth, A.K. Geim, Phys. Rev. Lett. 97, 187401–187404 (2006)

    Article  ADS  Google Scholar 

  25. K. Vano-Herrera, A. Misiun, C. Vogt, J. Raman Spectrosc. 46, 273–279 (2015)

    Article  ADS  Google Scholar 

  26. Z. Chang, C. Li, Y. Wang, B. Chen, L. Fu, Y. Zhu, L. Zhang, Y. Wu, W. Huang, Sci. Rep. 6, 28421–28426 (2016)

    Article  ADS  Google Scholar 

  27. D. Vernardou, A. Kazas, M. Apostolopoulou, N. Katsarakis, E. Koudoumas, J. Electron. Mater. 46, 2232–2240 (2017)

    Article  ADS  Google Scholar 

  28. H. Wang, H. Yi, X. Chen, X. Wang, J. Mater. Chem. A 2, 1165–1173 (2014)

    Article  Google Scholar 

  29. Z. Jiao, X. Wei Sun, J. Wang, L. Ke, H. Volkan Demir, J. Phys. D Appl. Phys. 43, 285501–285506 (2010)

    Article  Google Scholar 

  30. A.W. Bott, W.R. Heineman, Chronocoulometry. Curr. Sep. 4, 121–126 (2004)

    Google Scholar 

  31. F.C. Anson, Anal. Chem. 38, 54–57 (1966)

    Article  Google Scholar 

  32. J. Qin, W. Lv, Z. Li, B. Li, F. Kang, Q.-H. Yang, Chem. Commun. 50, 13447–13450 (2014)

    Article  Google Scholar 

  33. Y. Wu, P. Zhu, X. Zhao, M.V. Reddy, S. Peng, B.V.R. Chowdari, S. Ramakrishna, J. Mater. Chem. A 1, 852–859 (2013)

    Article  Google Scholar 

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Acknowledgements

This work was supported by the European Research Council under ERC Advanced Grant No. 320081 (PHOTOMETA), while financial support by the EU-FET Graphene Flagship (Grant Agreement No: 604391) is also acknowledged.

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Correspondence to D. Vernardou or G. Kenanakis.

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Vernardou, D., Vasilopoulos, K.C. & Kenanakis, G. 3D printed graphene-based electrodes with high electrochemical performance. Appl. Phys. A 123, 623 (2017). https://doi.org/10.1007/s00339-017-1238-1

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  • DOI: https://doi.org/10.1007/s00339-017-1238-1

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