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Composition of condensation products of bisphenol-A and epichlorohydrin

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Summary

Theoretical equations based on kinetic scheme were developed to predict the average oligomerization number of products of Bisphenol-A and epichlorohydrin condensation catalysed by a quaternary ammonium salt. Ratio of rate constants of the terminal groups formation and chain extension reaction was found. The reactivity ratio varies from 0.05 at 25° to 0.50 at 120°.

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Authors and Affiliations

  1. Polymer Department, Mendeleev University of Chemical Technology, 9 Miusskaya sq., Moscow 125190, Russia, , , , , , RU

    Djavat R. Medjitov, Lidija G. Shode & Genrich M. Tseitlin

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  1. Djavat R. Medjitov
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  2. Lidija G. Shode
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  3. Genrich M. Tseitlin
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Received: 6 December 1995/Revised version: 3 March 1998/Accepted: 5 March 1998

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Medjitov, D., Shode, L. & Tseitlin, G. Composition of condensation products of bisphenol-A and epichlorohydrin. Polymer Bulletin 40, 509–516 (1998). https://doi.org/10.1007/s002890050284

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  • DOI: https://doi.org/10.1007/s002890050284

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