Skip to main content
Log in

Multi-walled carbon nanotubes buckypaper/epoxy composites: effect of loading and pressure on tensile and electrical properties

  • Original Paper
  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Abstract

Carbon nanotubes (CNT) thin sheets known as buckypaper have been used as an alternative to particulate CNT filler in the fabrication of CNT/epoxy nanocomposites. The use of CNT buckypaper is on innovative process which converts the nanomaterials into an easy-to-handle form, making them ready to be incorporated into existing fabrication lines. The properties and qualities of the buckypapers produced are affected by the varieties in the fabrication methods implemented and the quality of the CNT. Very few studies have been recorded on the properties of CNT buckypaper with respect to the vacuum filter pressure together with filler loading. Hence, this research is aimed to investigate the combination effect of vacuum pressure and MWCNT loading during the vacuum filtration process. It was found that the vacuum pressure and MWCNT loading caused a significant effect on the porosity and surface roughness of buckypapers with low MWCNT loading. This subsequently influences the tensile properties and electrical conductivities of the epoxy-filled buckypaper composites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Li Y, Krӧger M (2012) A theoretical evaluation of the effects of carbon nanotube entanglement and bundling on the structural and mechanical properties of buckypaper. Carbon 50:1793–1806. https://doi.org/10.1016/j.carbon.2011.12.027

    Article  Google Scholar 

  2. Zhang J, Jiang D (2012) Influence of geometries of multi-walled carbon nanotubes on the pore structures of Buckypaper. Compos A 43:469–474. https://doi.org/10.1016/j.compositesa.2011.11.016

    Article  Google Scholar 

  3. Rigueur JL, Hasan SA, Mahajan SV, Dickerson JH (2010) Buckypaper fabrication by liberation of electrophoretically deposited carbon nanotubes. Carbon 48:4090–4099. https://doi.org/10.1016/j.carbon.2010.07.016

    Article  Google Scholar 

  4. Kim S-K, Kim JT, Kim H-C, Rhee K-Y, Kathi J (2012) Thermal and mechanical properties of epoxy/carbon fiber composites reinforced with multi-walled carbon nanotubes. J Macromol Sci Part B Phys 51:358–367. https://doi.org/10.1080/00222348.2011.596799

    Article  Google Scholar 

  5. Lopes PE, Hattum FV, Pereira CMC, Nóvoa PJRO, Forero S, Hepp F, Pambaguian L (2010) High CNT content composites with CNT buckypaper and epoxy resin matrix: impregnation behaviour composite production and characterization. Compos Struct 92:1291–1298. https://doi.org/10.1016/j.compstruct.2009.11.003

    Article  Google Scholar 

  6. Saeb MR, Bakhshandeh E, Khonakdar HA, Mäder E, Scheffler C, Heinrich G (2013) Cure kinetics of epoxy nanocomposites affected by MWCNTs functionalization: a review. Sci World J. https://doi.org/10.1155/2013/703708

    Google Scholar 

  7. Zou W, Z-j Du, Y-x Liu, Yang X, H-q Li, Zhang C (2008) Functionalization of MWNTs using polyacryloyl chloride and the properties of CNT–epoxy matrix nanocomposites. Compos Sci Technol 68:3259–3264. https://doi.org/10.1016/j.compscitech.2008.08.011

    Article  Google Scholar 

  8. Ma P-C, Kim J-K (2011) Carbon nanotubes for polymer reinforcement. Taylor & Francis, Boca Raton

    Google Scholar 

  9. Ma P-C, Siddiqui NA, Marom G, Kim J-K (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Compos A 41:1345–1367. https://doi.org/10.1016/j.compositesa.2010.07.003

    Article  Google Scholar 

  10. Chapartegui M, Barcena J, Irastorza X, Elizetxea C, Fernandez M, Santamaria A (2012) Analysis of the conditions to manufacture a MWCNT buckypaper/benzoxazine nanocomposite. Compos Sci Technol 72:489–497. https://doi.org/10.1016/j.compscitech.2011.12.001

    Article  Google Scholar 

  11. Whitby RLD, Fukuda T, Maekawa T, James SL, Mikhalovsky SV (2008) Geometric control and tuneable pore size distribution of buckypaper and buckydiscs. Carbon 46:949–956. https://doi.org/10.1016/j.carbon.2008.02.028

    Article  Google Scholar 

  12. Yee KF, Ong YT, Mohamed AR, Tan SH (2014) Novel MWCNT-buckypaper/polyvinyl alcohol asymmetric membrane for dehydration of etherification reaction mixture: fabrication, characterisation and application. J Membrane Sci 453:546–555. https://doi.org/10.1016/j.memsci.2013.11.040

    Article  Google Scholar 

  13. Ashrafi B, Guan J, Mirjalili V, Hubert P, Simard B, Johnston A (2010) Correlation between Young’s modulus and impregnation quality of epoxy-impregnated SWCNT buckypaper. Compos A 41(9):1184–1191. https://doi.org/10.1016/j.compositesa.2010.04.018

    Article  Google Scholar 

  14. Komarov FF, Milchanin OV, Munoz E, Rodionova VN, Karpovich VB, Krivosheev RM (2011) Attenuation of microwave electromagnetic radiation by means of buckypaper. Tech Phys 56:1679–1684. https://doi.org/10.1134/s1063784211110144

    Article  Google Scholar 

  15. Young JP (2009) Continuous buckypaper manufacturing process: process investigation and improvement. Florida State University College of Engineering, Tallahassee

    Google Scholar 

  16. Han J-H, Zhang H, Chu P-F, Imani A, Zhang Z (2015) Friction and wear of high electrical conductive carbon nanotube buckypaper/epoxy composites. Compos Sci Technol 114:1–10. https://doi.org/10.1016/j.compscitech.2015.03.012

    Article  Google Scholar 

  17. Wang Z, Liang Z, Wang B, Zhang C, Kramer L (2004) Processing and property investigation of single-walled carbon nanotube (SWNT) buckypaper/epoxy resin matrix nanocomposites. Compos A 35:1225–1232. https://doi.org/10.1016/j.compositesa.2003.09.029

    Article  Google Scholar 

  18. Ramón-Torregrosa PJ, Rodríguez-Valverde MA, Amirfazli A, Cabrerizo-Vílchez MA (2008) Factors affecting the measurement of roughness factor of surfaces and its implications for wetting studies. Colloids Surf A 323:83–93. https://doi.org/10.1016/j.colsurfa.2007.10.032

    Article  Google Scholar 

  19. Ansón-Casaos A, González-Domínguez JM, Terrado E, Martínez MT (2010) Surfactant-free assembling of functionalized single-walled carbon nanotube buckypapers. Carbon 48:1480–1488. https://doi.org/10.1016/j.carbon.2009.12.043

    Article  Google Scholar 

  20. Wan Dalina WAD (2017) Fabrication and properties of multi-walled carbon nanotubes filled woven glass fibre reinforced epoxy laminated hybrid composites. Universiti Sains Malaysia

  21. Han J-H, Zhang H, Chen M-J, Wang G-R, Zhang Z (2014) CNT buckypaper/thermoplastic polyurethane composites with enhanced stiffness, strength and toughness. Compos Sci Technol 103:63–71. https://doi.org/10.1016/j.compscitech.2014.08.015

    Article  Google Scholar 

  22. Fu S-Y, Feng X-Q, Lauke B, Mai Y-W (2008) Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites. Compos B 39:933–961. https://doi.org/10.1016/j.compositesb.2008.01.002

    Article  Google Scholar 

  23. Ghaleb ZA, Mariatti M, Ariff ZM (2014) Properties of graphene nanopowder and multi-walled carbon nanotube-filled epoxy thin-film nanocomposites for electronic applications: the effect of sonication time and filler loading. Compos A 58:77–83. https://doi.org/10.1016/j.compositesa.2013.12.002

    Article  Google Scholar 

Download references

Acknowledgements

We would like to express our gratitude to the Ministry of Higher Education (MOHE) and for Universiti Sains Malaysia supporting us through MyBrain15 (myPhD) program and Fundamental Research Grant (Grant No. 6071284), respectively, which made this study possible. Funding was provided by Fundamental Research Grant (Research Universiti Grant [Grant No. 814153]).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Mariatti.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wan Dalina, W.A.D., Mariatti, M. & Tan, S.H. Multi-walled carbon nanotubes buckypaper/epoxy composites: effect of loading and pressure on tensile and electrical properties. Polym. Bull. 76, 2801–2817 (2019). https://doi.org/10.1007/s00289-018-2530-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00289-018-2530-8

Keywords

Navigation