Abstract
Sample preparation is a constantly evolving step in the measurement process with a positive effect on its performance. Its evolution has been marked by an underlying environmental commitment, with simplification, miniaturization, and automation being three of its driving forces. This trends article deepens how the sample preparation can go sustainable through the efficient design of new sorptive materials, either liquid or solid. This objective can be achieved by using natural and/or biodegradable materials as precursors of the functional sorptive phases and by designing materials that simplify the procedures (thus reducing the energy or resources required). Although environmental performance is a crucial aspect of a new material, its applicability is what really defines its incorporation into the sample preparation toolbox. For this reason, their characteristics and more relevant applications will be briefly presented to conclude with the tendency of their use in the very near future.
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References
Azzouz A, Kailasa SK, LeeRascón SSJA, Ballesteros E, Zhang M, Kim K-H. Review of nanomaterials as sorbents in solid-phase extraction for environmental samples. TrAC, Trends Anal Chem. 2018;108:347–69. https://doi.org/10.1016/j.trac.2018.08.009.
Aguilera-Herrador E, Lucena R, Cárdenas S, Valcárcel M. The roles of ionic liquids in sorptive microextraction techniques. TrAC, Trends Anal Chem. 2010;29:602–16. https://doi.org/10.1016/j.trac.2009.11.009.
Kannouma RE, Hammad MA, Kamal AH, Mansour FR. Miniaturization of liquid-liquid extraction; the barriers and the enablers. Microchem J. 2022;182: 107863. https://doi.org/10.1016/j.microc.2022.107863.
Carasek E, Bernardi G, Morelli D, Merib J. Sustainable green solvents for microextraction techniques: recent developments and applications. J Chromatogr A. 2021;1640: 461944. https://doi.org/10.1016/j.chroma.2021.461944.
Abbott AP, Capper G, Davies DL, Rasheed RK, Tambyrajah V. Novel solvent properties of choline chloride/urea mixtures. Electronic supplementary information (ESI) available: spectroscopic data. 2003. See http://www.rsc.org/suppdata/cc/b2/b210714g/. Chem Commun. 2003; 1; 70–71. https://doi.org/10.1039/b210714g
Prabhune A, Dey R. Green and sustainable solvents of the future: deep eutectic solvents. J Mol Liq. 2023;379: 121676. https://doi.org/10.1016/j.molliq.2023.121676.
Choi YH, Van Spronsen J, Dai Y, Verberne M, Hollmann F, Arends IWCE, Witkamp G-J, Verpoorte R. Are natural deep eutectic solvents the missing link in understanding cellular metabolism and physiology? Plant Physiol. 2011;156:1701–5. https://doi.org/10.1104/pp.111.178426.
Andruch V, Kalyniukova A, Płotka-Wasylka J, Jatkowska N, Snigur D, Zaruba S, Płatkiewicz J, Zgoła-Grześkowiak A, Werner J. Application of deep eutectic solvents in analytical sample pretreatment (update 2017–2022). Part A: Liquid phase microextraction. Microchemical Journal. 2023;189:108509. https://doi.org/10.1016/j.microc.2023.108509
Werner J, Zgoła-Grześkowiak A, Płatkiewicz J, Płotka-Wasylka J, Jatkowska N, Kalyniukova A, Zaruba S, Andruch V. Deep eutectic solvents in analytical sample preconcentration Part B: solid-phase (micro)extraction. Microchem J. 2023;191: 108898. https://doi.org/10.1016/j.microc.2023.108898.
Ballesteros-Gómez A, Rubio S, Pérez-Bendito D. Potential of supramolecular solvents for the extraction of contaminants in liquid foods. J Chromatogr A. 2009;1216:530–9. https://doi.org/10.1016/j.chroma.2008.06.029.
Rubio S. Twenty years of supramolecular solvents in sample preparation for chromatography: achievements and challenges ahead. Anal Bioanal Chem. 2020;412:6037–58. https://doi.org/10.1007/s00216-020-02559-y.
Caballero-Casero N, Rubio S. Identification of bisphenols and derivatives in greenhouse dust as a potential source for human occupational exposure. Anal Bioanal Chem. 2022;414:5397–409. https://doi.org/10.1007/s00216-021-03863-x.
Romera-García E, Ballesteros-Gómez A, Rubio S. Supramolecular biosolvents made up of self-assembled rhamnolipids: synthesis and characterization. Green Chem. 2020;22:6115–26. https://doi.org/10.1039/D0GC02078H.
Jesús Dueñas-Mas M, Ballesteros-Gómez A, Rubio S. Characterization of a new sustainable supramolecular solvent and application to the determination of oxy-PAHs in meat, seafood and fish tissues. Food Chem. 2023;405: 134731. https://doi.org/10.1016/j.foodchem.2022.134731.
Cai Z-H, Wang J-D, Liu L, Ruan L-D, Gu Q, Yan X-Y, Fu L-N, Zhao P-Q, Zhang S, Fu Y-J. A green and designable natural deep eutectic solvent-based supramolecular solvents system: efficient extraction and enrichment for phytochemicals. Chem Eng J. 2023;457: 141333. https://doi.org/10.1016/j.cej.2023.141333.
Jalili V, Zendehdel R, Barkhordari A. Supramolecular solvent-based microextraction techniques for sampling and preconcentration of heavy metals: a review. Rev Anal Chem. 2021;40:93–107. https://doi.org/10.1515/revac-2021-0130.
Jessop PG, Phan L, Carrier A, Robinson S, Dürr CJ, Harjani JR. A solvent having switchable hydrophilicity. Green Chem. 2010;12:809. https://doi.org/10.1039/b926885e.
Jessop PG, Heldebrant DJ, Li X, Eckert CA, Liotta CL. Reversible nonpolar-to-polar solvent. Nature. 2005;436:1102–1102. https://doi.org/10.1038/4361102a.
Lasarte-Aragonés G, Lucena R, Cárdenas S, Valcárcel M. Use of switchable solvents in the microextraction context. Talanta. 2015;131:645–9. https://doi.org/10.1016/j.talanta.2014.08.031.
Bazel Y, Rečlo M, Chubirka Y. Switchable hydrophilicity solvents in analytical chemistry. Five years of achievements Microchemical Journal. 2020;157: 105115. https://doi.org/10.1016/j.microc.2020.105115.
Shishov A, Sviridov I, Timofeeva I, Chibisova N, Moskvin L, Bulatov A. An effervescence tablet-assisted switchable solvent-based microextraction: on-site preconcentration of steroid hormones in water samples followed by HPLC-UV determination. J Mol Liq. 2017;247:246–53. https://doi.org/10.1016/j.molliq.2017.09.120.
Pawliszyn J. Evolution of solid phase microextraction technology. Cambridge: Royal Society of Chemistry; 2023.
Płotka-Wasylka J, Jatkowska N, Paszkiewicz M, Caban M, Fares MY, Dogan A, Garrigues S, Manousi N, Kalogiouri N, Nowak PM, Samanidou VF, De La Guardia M. Miniaturized solid phase extraction techniques for different kind of pollutants analysis: state of the art and future perspectives – PART 1. TrAC, Trends Anal Chem. 2023;162: 117034. https://doi.org/10.1016/j.trac.2023.117034.
Płotka-Wasylka J, Jatkowska N, Paszkiewicz M, Caban M, Fares MY, Dogan A, Garrigues S, Manousi N, Kalogiouri N, Nowak PM, Samanidou VF, De La Guardia M. Miniaturized solid phase extraction techniques for different kind of pollutants analysis: state of the art and future perspectives – part 2. TrAC, Trends Anal Chem. 2023;165: 117140. https://doi.org/10.1016/j.trac.2023.117140.
Zhou W, Wieczorek MN, Javanmardi H, Pawliszyn J. Direct solid-phase microextraction-mass spectrometry facilitates rapid analysis and green analytical chemistry. TrAC, Trends Anal Chem. 2023;166: 117167. https://doi.org/10.1016/j.trac.2023.117167.
Mafra G, García-Valverde M, Millán-Santiago J, Carasek E, Lucena R, Cárdenas S. Returning to nature for the design of sorptive phases in solid-phase microextraction. Separations. 2019;7:2. https://doi.org/10.3390/separations7010002.
Godage NH, Gionfriddo E. Use of natural sorbents as alternative and green extractive materials: a critical review. Anal Chim Acta. 2020;1125:187–200. https://doi.org/10.1016/j.aca.2020.05.045.
Ma X, Wang L, He Q, Sun Q, Yin D, Zhang Y. A review on recent developments and applications of green sorbents-based solid phase extraction techniques. Advances in Sample Preparation. 2023;6: 100065. https://doi.org/10.1016/j.sampre.2023.100065.
Díaz-Liñán MC, Lucena R, Cárdenas S, López-Lorente AI. Unmodified cellulose filter paper, a sustainable and affordable sorbent for the isolation of biogenic amines from beer samples. J Chromatogr A. 2021;1651: 462297. https://doi.org/10.1016/j.chroma.2021.462297.
Allgaier-Díaz DW, Trujillo-Rodríguez MJ, Ayala JH, Díaz Díaz D, Pino V. Unmodified biopolymers as sustainable microextraction materials for the environmental monitoring of polycyclic aromatic hydrocarbons and personal care products. Microchem J. 2023;191: 108873. https://doi.org/10.1016/j.microc.2023.108873.
González-Bermúdez M, López-Lorente ÁI, Lucena R, Cárdenas S. Paper-based sorptive phases for a sustainable sample preparation. Advances in Sample Preparation. 2023;5: 100051. https://doi.org/10.1016/j.sampre.2023.100051.
Benedé JL, Chisvert A, Lucena R, Cárdenas S. Synergistic combination of polyamide-coated paper-based sorptive phase for the extraction of antibiotics in saliva. Anal Chim Acta. 2021;1164: 338512. https://doi.org/10.1016/j.aca.2021.338512.
Benedé JL, Chisvert A, Lucena R, Cárdenas S. A paper-based polystyrene/nylon Janus platform for the microextraction of UV filters in water samples as proof-of-concept. Microchim Acta. 2021;188:391. https://doi.org/10.1007/s00604-021-05047-x.
Díaz-Liñán MC, García-Valverde MT, Lucena R, Cárdenas S, López-Lorente AI. Paper-based sorptive phases for microextraction and sensing. Anal Methods. 2020;12:3074–91. https://doi.org/10.1039/D0AY00702A.
Hu B, Yao Z-P. Electrospray ionization mass spectrometry with wooden tips: a review. Anal Chim Acta. 2022;1209: 339136. https://doi.org/10.1016/j.aca.2021.339136.
Vejar-Vivar C, Millán-Santiago J, Mardones C, Lucena R, Cárdenas S. Polydopamine inner wall-coated hypodermic needle as microextraction device and electrospray emitter for the direct analysis of illicit drugs in oral fluid by ambient mass spectrometry. Talanta. 2022;249: 123693. https://doi.org/10.1016/j.talanta.2022.123693.
Millán-Santiago J, Lucena R, Cárdenas S. Nylon 6-cellulose composite hosted in a hypodermic needle: biofluid extraction and analysis by ambient mass spectrometry in a single device. Journal of Pharmaceutical Analysis. 2023;S2095177923001272. https://doi.org/10.1016/j.jpha.2023.06.015
Srivastava A, Mishra A. Food waste valorization for handling environmental problems: a review. Environmental Sustainability. 2022;5:401–21. https://doi.org/10.1007/s42398-022-00245-6.
Frezzini MA, Massimi L, Astolfi ML, Canepari S, Giuliano A. Food waste materials as low-cost adsorbents for the removal of volatile organic compounds from wastewater. Materials. 2019;12:4242. https://doi.org/10.3390/ma12244242.
Vassalini I, Litvinava M, Alessandri I. All food waste-based membranes for chromium(VI) removal. Environmental Sustainability. 2021;4:429–35. https://doi.org/10.1007/s42398-020-00132-y.
Cuccarese M, Brutti S, De Bonis A, Teghil R, Di Capua F, Mancini IM, Masi S, Caniani D. Sustainable adsorbent material prepared by soft alkaline activation of spent coffee grounds: characterisation and adsorption mechanism of methylene blue from aqueous solutions. Sustainability. 2023;15:2454. https://doi.org/10.3390/su15032454.
Płotka-Wasylka J. A new tool for the evaluation of the analytical procedure: green analytical procedure index. Talanta. 2018;181:204–9. https://doi.org/10.1016/j.talanta.2018.01.013.
Wojnowski W, Tobiszewski M, Pena-Pereira F, Psillakis E. AGREEprep – Analytical greenness metric for sample preparation. TrAC, Trends Anal Chem. 2022;149: 116553. https://doi.org/10.1016/j.trac.2022.116553.
Pena-Pereira F, Wojnowski W, Tobiszewski M. AGREE—analytical greenness metric approach and software. Anal Chem. 2020;92:10076–82. https://doi.org/10.1021/acs.analchem.0c01887.
González-Martín R, Gutiérrez-Serpa A, Pino V, Sajid M. A tool to assess analytical sample preparation procedures: sample preparation metric of sustainability. J Chromatogr A. 2023;1707: 464291. https://doi.org/10.1016/j.chroma.2023.464291.
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Financial support from PID2020-112862RB-I00 funded by MCIN/AEI/10.13039/50110 0 011033 (Feder “Una manera de hacer Europa”) is gratefully acknowledged.
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Soledad Cárdenas is an editor of Analytical and Bioanalytical Chemistry but was not involved in the peer review of this paper.
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Cárdenas, S. The role of sustainable materials in sample preparation. Anal Bioanal Chem 416, 2049–2056 (2024). https://doi.org/10.1007/s00216-023-05015-9
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DOI: https://doi.org/10.1007/s00216-023-05015-9