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High-performance liquid chromatography with diamond ATR–FTIR detection for the determination of carbohydrates, alcohols and organic acids in red wine

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Abstract

A horizontal diamond attenuated total reflection (ATR) element has been incorporated in a flow-through cell with low dead volume and used for on-line mid-IR detection in high-performance liquid chromatography. The chemical inertness of the ATR element permitted the use of a strongly acidic mobile phase in the isocratic separation. The hyphenation was used for the analysis of organic acids, sugars and alcohols in red wine. In the case of co-eluting analytes multivariate curve resolution–alternating least squares (MCR–ALS) was successfully employed for quantitative analysis.

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Acknowledgement

Financial support from the Austrian Science Foundation within the project 13686 is acknowledged.

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Authors and Affiliations

  1. Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9/164-AC, 1060, Vienna, Austria

    Andrea Edelmann, Josef Diewok, Josefa Rodriguez Baena & Bernhard Lendl

Authors
  1. Andrea Edelmann
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  2. Josef Diewok
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  3. Josefa Rodriguez Baena
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  4. Bernhard Lendl
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Correspondence to Bernhard Lendl.

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www.iac.tuwien.ac.at/cavs

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Edelmann, A., Diewok, J., Baena, J.R. et al. High-performance liquid chromatography with diamond ATR–FTIR detection for the determination of carbohydrates, alcohols and organic acids in red wine. Anal Bioanal Chem 376, 92–97 (2003). https://doi.org/10.1007/s00216-003-1879-0

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