Abstract
This paper describes the development of a remediation approach based on the pre-oxidation using Fenton’s reagent and the subsequent removal of arsenic (As) through sand filtration from drinking water. The efficiency of the process was carried out including As(III) and As(V) with various concentration ratios up to 3,000 ppb. Efficient removal of As was observed within WHO guideline value of 10 ppb. The recoveries of samples were found to be 98 % ± 2.5 %. The process was applied to field samples, where results show considerable reduction in As concentrations. This process is cost effective for treatment of drinking water with high concentration of As.
Similar content being viewed by others
References
APHA, AWWA, WPCF (2005) Standard methods for examination of water and wastewater, 21st edn. Washington, D.C.
Balarama KMV, Chandrasekaran K, Karunasagar D, Arunachalam J (2001) A combined treatment approach using Fenton’s reagent and zero valent iron for the removal of arsenic from drinking water. J Hazard Mater B 84:229–240
Chen R, Pignatello JJ (1997) Role of quinone intermediates as electron shuttles in Fenton and photoassisted Fenton oxidations of aromatic compounds. Environ Sci Technol 31:2399–2406
Jaafarzadeh N, Amiri H, Ahmadi M (2012) Factorial experimental design application in modification of volcanic ash as a natural adsorbent with Fenton process for arsenic removal. Environ Technol 33:159–165
Jain CK, Ali I (2000) Arsenic: occurrence, toxicity and speciation techniques. Water Res 8:4304–4312
Joseph JM, Destaillats H, Hung HM, Hoffmann MR (2000) The sonochemical degradation of azobenzene and related azo dyes: rate enhancements via Fenton’s reactions. J Phys Chem A 104:301–307
Katsoyiannis IA, Zouboulis AI (2002) Removal of arsenic from contaminated water sources by sorption onto iron-oxide-coated polymeric materials. Water Res 36:5141–5155
Katsoyiannis IA, Ruettimann T, Hug SJ (2008) pH dependence of Fenton reagent generation and As(III) oxidation and removal by corrosion of zero valent iron in aerated water. Environ Sci Technol 42:7424–7430
Mohan D, Pittman CU, Bricka M, Smith F, Yancey B, Mohammad J, Steele PH, Alexandre-Franco MF, Gomez-Serrano V, Gong H (2007) Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production. J Colloid Interf Sci 310:57–73
Nordstrom DK (2002) Public health - Worldwide occurrences of arsenic in ground water. Science 296:2143–2145
Oliveros E, Legrini O, Hohl M, Muller T, Braun AM (1997) Large scale development of a light-enhanced Fenton reaction by optimal experimental design. Water Sci Technol 35:223–230
Pang S, Jiang J, Ma J (2009) New insight into the oxidation of arsenite by the reaction of zerovalent iron and oxygen. Comment on “pH dependence of Fenton reagent generation and As(III) oxidation and removal by corrosion of zero valent iron in aerated water”. Environ Sci Technol 43:3978–3979
Pesola GR, Parvez F, Chen Y, Ahmed A, Hasan R, Ahsan H (2012) Arsenic exposure from drinking water and dyspnoea risk in Araihazar, Bangladesh: a population-based study. Eur Respir J 39:1076–1083
Rasmussen L, Andersen K (2002) Environmental health and human exposure assessment. United Nations Synthesis Report on Arsenic in Drinking Water. WHO, chapter 2
Ravenscroft P, Brammer H, Richards KS (2009) Arsenic pollution: a global synthesis. Wiley-Blackwell, UK
Smedley PL, Kinniburgh G (2002) A review of the source, behaviour and distribution of arsenic in natural waters. Appl Geochem 17:517–568
Walling C, Cleary M (1977) Oxygen evaluation as a critical test of mechanism in the ferric-ion catalysed decomposition of hydrogen peroxide. Int J Chem Kinet 9:595–601
Wang SB (2008) A comparative study of Fenton and Fenton-like reaction kinetics in decolourisation of wastewater. Dye Pigment 76:714–720
Acknowledgments
The authors are thankful to the Director, National Environmental Engineering Research Institute (NEERI) for kind permission to publish the work. The authors are also thankful to the Instrumentation Division, NEERI, for extending the facilities.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jasudkar, D., Rakhunde, R., Deshpande, L. et al. Arsenic Remediation from Drinking Water Using Fenton’s Reagent with Slow Sand Filter. Bull Environ Contam Toxicol 89, 1231–1234 (2012). https://doi.org/10.1007/s00128-012-0852-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00128-012-0852-z