Skip to main content
Log in

Multielemental Analysis of Migori (Southwest, Kenya) Artisanal Gold Mine Ores and Sediments by EDX-ray Fluorescence Technique: Implications of Occupational Exposure and Environmental Impact

  • Published:
Bulletin of Environmental Contamination and Toxicology Aims and scope Submit manuscript

Abstract

The results of heavy element profiling of the gold ores and sediments associated with the artisanal gold mining activities of the Migori gold belt of Southwestern Nyanza, Kenya, were reported in this paper. The analysis was made to assess the occupational exposure of the miners as well as to investigate the environmental impact of toxic heavy metals. Gold ores and sediments from the artisanal gold processing were sampled in four artisanal gold mining areas: Osiri A, Osiri B, Mikei and Macalder (Makalda) and analyzed for heavy elemental content using 109Cd radioisotope excited EDXRF spectrometry technique. Analysis consisted of direct irradiating of sample pellets. The concentrations of major elements detected were: titanium (711.41–10,766.67 mg/kg); cobalt (82.65–1,010.00 mg/kg); zinc (29.90–63,210 mg/kg); arsenic (29.30–8,246.59 mg/kg); gold (14.07–73.48 mg/kg); lead (16.31–14,999.40 mg/kg) and mercury (16.10–149.93 mg/kg). The average concentration of the heavy toxic metals i.e. arsenic, lead, titanium and zinc were found to be above 50 mg/Kg as recommended by World Health Organization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2

Similar content being viewed by others

References

  • Alpers N, Hunerlach MP, May JT, Hothem RL (2005) Mercury contamination from historical gold mining in California. US Geol Surv Fact Sheet 2005–3014:6

    Google Scholar 

  • Appleton JD, Williams TM, Orbea H, Carraso M (2001) Fluvial contamination associated with artisanal gold miming in the Ponce Enrĭquez, Portovelo- Zaruma and Nambija areas, Ecuador. Water Air Soil Poll 131:19–39

    Article  CAS  Google Scholar 

  • Ferreira da Silva E, Zhang C, Pinto LS, Patinha C, Reis P (2004) Hazard assessment on arsenic and lead in soils of Castromil gold mining area, Portugal. Appl Geochem 19:889–898

    Article  Google Scholar 

  • Getaneh W, Alemayehu T (2006) Metal contamination of the environment of placer and primary gold mining in the Adola region of Southern Ethiopia. Environ Geol 50:339–352

    Article  CAS  Google Scholar 

  • Ichangi DW, Maclean WH (1991) The Archean volcanic facies in the Migori segment, Nyanza greenstone belt, Kenya: stratigraphy, geochemistry and mineralization. J Afr Earth Sci 13:277–290

    Article  CAS  Google Scholar 

  • May TW, Wiedmeyer PH, Gober J, Larson S (2001) Influence of mining-related activities on concentration of metals in water and sediments from the streams of the Black Hills, South Dakota. Arch Environ Con Tox 40:1–9

    Article  CAS  Google Scholar 

  • Ogola JS, Mutulah WV, Omullo MA (2002) Impact of gold mining on the environment and human health: a case study in the Migori gold belt, Kenya. Environ Geochem Health 24:141–158

    Article  CAS  Google Scholar 

  • Pestina DMH, Formoso MLL, Teixeira EC (1997) Heavy metals in stream sediments from copper and gold mining areas in Southern Brazil. J Geochem Explor 58:133–143

    Article  Google Scholar 

  • Sanders LD (1964) Copper of Kenya, Geology survey of Kenya, Memoir No. 4 Nairobi: 51

  • Wennrich R, Mattusch J, Morgenstern P, Freyer K, Trentler H, Stärk H, Brüggemann L, Paschke A, Brigit D, Weiss H (2004) Characterization of sediments in an abandoned mining area; a case study of Mansfeld region, Germany. Environ Geol 45:818–833

    Article  CAS  Google Scholar 

  • Winde F, Sandham LA (2004) Uranium pollution of South African streams–An overview of the situation in gold mining areas of Witwatersrand. Geol J 61:131–149

    Google Scholar 

Download references

Acknowledgments

We thank the Department of Physics, University of Nairobi, for funding this research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to O. B. Odumo.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Odumo, O.B., Mustapha, A.O., Patel, J.P. et al. Multielemental Analysis of Migori (Southwest, Kenya) Artisanal Gold Mine Ores and Sediments by EDX-ray Fluorescence Technique: Implications of Occupational Exposure and Environmental Impact. Bull Environ Contam Toxicol 86, 484–489 (2011). https://doi.org/10.1007/s00128-011-0242-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00128-011-0242-y

Keywords

Navigation